An algorithm for determination of aerosol opticalthickness from AVHRR imagery over oceans

Summary The uncertainty in aerosol size distributions is a main source of errors in aerosol optical thickness determined from satellite measurements. To reduce the errors resulting from the uncertainty in aerosol size distributions, we have performed sensitivity analyses. It is found the errors resulting from the uncertainty in aerosol size distribution can be considerably reduced by using the Junge power law to approximate the aerosol size distribution in an actual atmosphere, if the exponent value is determined at the same time. An iterative algorithm is then developed for the simultaneous determination of aerosol optical thickness and the exponent of the Junge power law over ocean areas from the upwelling radiances measured in AVHRR visible and near infrared channels. A number of numerical experiments are carried out to investigate the validity of the Junge power law approximation by assuming the aerosol size distributions in an actual atmosphere are bimodal with different mode parameters, and by using the actual aerosol size distributions determined at several places by Kaufman et al. (1994). The results show that the errors in determined aerosol optical thickness resulting from the Junge power law approach are significantly reduced. The iterative algorithm is investigated further by comparing the aerosol optical thickness deduced from satellite measurement with that observed by a sun photometer. Received October 10, 2001 Revised December 28, 2001     

In Situ Determination of Au and Cu in Natural Pyrite by Near‐Infrared Femtosecond Laser Ablation‐Inductively Coupled Plasma‐Quadrupole Mass Spectrometry: No Evidence for Matrix Effects

Gold and copper concentrations were determined in natural pyrite by near‐infrared femtosecond LA‐ICP‐QMS, using both sulfide reference materials (pyrrhotite Po‐726 and in‐house natural chalcopyrite Cpy‐RM) and NIST SRM 610 as external calibrators. Firstly, using NIST SRM 610 as the external calibrator, we calculated the Au concentration in Po‐726 and the Cu concentration in Cpy‐RM. The calculated concentration averages for Au and Cu were similar to the values published for Po‐726 and Cpy‐RM, respectively. Secondly, we calculated Au and Cu concentrations taking NIST SRM 610 as an unknown sample and using Po‐726 and Cpy‐RM as external calibrators. Again, the average values obtained closely reflected the preferred concentrations for NIST SRM 610. Finally, we calculated Au and Cu concentrations in natural pyrite using sulfide and silicate reference materials as external calibrators. In both cases, calculated concentrations were very similar, independent of the external calibrator used. The aforementioned data, plus the fact that we obtained very small differences in relative sensitivity values (percentage differences are between 5% and 17% for ⁵⁷Fe, ⁶³Cu and ¹⁹⁷Au) on analyses of silicate and sulfide RMs, indicate that there were no matrix effects related to the differences in material composition. Thus, it is possible to determine Au and Cu in natural sulfides using NIST silicate glasses as an external calibrator.     

Effects of bottom sediments on the survival of Enterobacter aerogenes in seawater

The survival of the coliform bacterium Enterobacter aerogenes in seawater was greatly affected by the underlying bottom sediments. The presence of sediments which contained higher concentrations of organic nutrients than the overlaying seawater prolonged the survival and even enabled growth of the bacterial cells. Results obtained from chemical analysis indicated that sediments of fine-grained, silt-clay type contained highest amounts of organic nutrients as compared with sediments with larger particle sizes such as silt and sand grains. Thus, nutrient contents of the sediments were found to be inversely proportional to sediment particle size. The degree of prolonged survival of E. aerogenes was also found to be inversely proportional to the size of the sediment particles presented. Release of the bound nutrients which became available to cells of E. aerogenes from sediments by action of waves and human activities can explain, at least in part, why high counts of coliform bacteria are obtained in coastal and beach waters.     

Toxicities of antifouling biocide Irgarol 1051 and its major degraded product to marine primary producers

Irgarol 1051 (2-methythiol-4-tert-butylamino-6-cyclopropylamino-s-triazine) is an algaecide commonly used in antifouling paints. It undergoes photodegradation which yields M1 (2-methylthio-4-tert-butylamino-6-amino-s-triazine) as its major and most stable degradant. Elevated levels of both Irgarol and M1 have been detected in coastal waters worldwide; however, ecotoxicity effects of M1 to various marine autotrophs such as cyanobacteria are still largely unknown. This study firstly examined and compared the 96 h toxicities of Irgarol and M1 to the cyanobacterium Chroococcus minor and two marine diatom species, Skeletonema costatum and Thalassiosira pseudonana. Our results suggested that Irgarol was consistently more toxic to all of the three species than M1 (96 h EC50 values: C. minor, 7.71 microug L(-1) Irgarol vs. > 200 microg L(-1) M1; S. costatum, 0.29 microg L(-1) Irgarol vs. 11.32 microg L(-1)M1; and T. pseudonana, 0.41 microg L(-1) Irgarol vs. 16.50 microg L(-1)M1). Secondly, we conducted a meta-analysis of currently available data on toxicities of Irgarol and M1 to both freshwater and marine primary producers based on species sensitivity distributions (SSDs). Interestingly, freshwater autotrophs are more sensitive to Irgarol than their marine counterparts. For marine autotrophs, microalgae are generally more sensitive to Irgarol than macroalgae and cyanobacteria. With very limited available data on M1 (i.e. five species), M1 might be less toxic than Irgarol; nonetheless this finding warrants further confirmation with additional data on other autotrophic species.     

A hypothesis of the Senoumi submarine megaslide in Suruga Bay in Japan—based on the undrained dynamic-loading ring shear tests and computer simulation

The distinctive bathymetric feature exists in the Suruga Bay, Japan. It has been called as Senoumi (Stone flower sea) from old times. Senoumi is a 30?km wide and 20?km long concave feature. Its origin has not been explained yet; however, the feature might be a combined consequence of intensive tectonic activity in the plate border, landslides, and a submarine flow coming from the Oi River. If the Senoumi was caused by a landslide, the latter would be larger than any on-land landslide in Japan. The downshelf “exit” from this feature is much narrower than its central part. This is not usual shape of landslides, but it is similar to the liquefied landslides such as those in quick clays which mobilize great strength reduction after failure. To study Senoumi as a landslide, the shear behaviors of the following three soil samples were investigated by the cyclic and seismic undrained stress control ring shear tests. One sample is volcanic ash taken from the base of landslide deposits (mass transport deposits), from 130 to 190?m deep layer below the submarine floor which was drilled and cored by the Integrated Ocean Drilling Program Expedition 333. Another two samples are the Neogene silty–sand and silt taken from the Omaezaki hill adjacent to the Senoumi, because the shear zone might have been formed in Neogene layers extending from on-land to the continental shelf. The largest strength reduction from peak to steady-state shear resistance in the undrained cyclic loading test was found in volcanic ash. The strength reduction in Neogene silty–sand was smaller than volcanic ash, while the Neogene silt mobilized the least post-failure strength reduction. An integrated model simulating the initiation and motion of earthquake-induced rapid landslides (landslide simulation (LS)-RAPID, Sassa et al. Landslides 7–3:219–236, 2010) was applied to this study. The steady-state shear resistance and other geotechnical parameters measured by the undrained ring shear tests and the greatest strong motion record in the 2011 off-the-Pacific Coast of Tohoku earthquake (M _w 9.0), also known as “2011 Tohoku Earthquake” at the observation point MYG004 (2,933?gal) were input to this model. As the result, it was found that landslides would be triggered by 0.30–1.0 times of MYG004 in volcanic ash, 0.4–1.0 times of MYG004 in Neogene silty–sand and Neogene silt, though the depth and area of triggered landslides were different in soils and intensity of shaking. Feature, created by LS-RAPID using the parameters of volcanic ash, was most similar to the Senoumi in depth and extent. The result obtained from this study includes a hypothesis to be proved, but presents the strong need to investigate the risk of the large-scale submarine landslides which could enhance tsunami wave and possibly enlarge the submarine landslide retrogressively into the adjacent coastal plain by the upcoming mega earthquake in the Nankai Trough.     

Rocky desertification and its causes in karst areas: a case study in Yongshun County,Hunan Province,China

Rocky desertification, a process of land degradation characterized by soil erosion and bedrock exposure, is one of the most serious land degradation problems in karst areas, and is regarded as an obstacle to local sustainable development. It is well known that human activities can accelerate rocky desertification; however, the effects of climate change on rocky desertification in karst areas are still unclear. This study focused on the effects of temperature and precipitation changes and human activities on rocky desertification in karst areas to determine the impacts of climate change and human disturbances on rocky desertification. Areas of different level of rocky desertification were obtained from Landsat TM (1987) and Landsat ETM+ (2000) images. The results show that, although the total desertification area increased by only 1.27% between 1987 and 2000, 17.73% of the slightly desertified land had degraded to a moderate or intense level, 2.01 and 15.71%, respectively. Meanwhile, between 1987 and 2000, the air temperature increased by 0.7°C, and precipitation increased by 170 mm. Statistical results indicate that the increase in precipitation was caused by heavy rainfall. In addition, under the interactive influences of heavy rainfall and temperature, the average karst dissolution rate was about 87 m³ km⁻² a⁻¹ during the 14 years in the study area. Further analysis indicated that rocky desertification was positively related with the increase in temperature and precipitation and especially with the heavy rainfall events. Climate change accelerated rocky desertification in the karst areas. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.