Alteration and mineralization styles of the orogenic disseminated Zhenyuan gold deposit,southeastern Tibet: Contrast with carlin gold deposit

Orogenic disseminated and Carlin gold deposits share much similarity in alteration and mineralization.The disseminated orogenic Zhenyuan Au deposit along the Ailaoshan shear zone,southeastern Tibet,was selected to clarify their difference.The alteration and mineralization from the different lithologies,including meta-quartz sandstone,carbonaceous slate,meta-(ultra)mafic rock,quartz porphyry and lamprophyre were researched.According to the mineral assemblage and replacement relationship in all types of host rocks,two reactions show general control on gold deposition:(1)replacement of earlier magnetite by pyrite and carbonaceous material;(2)alteration of biotite and phlogopite phenocrysts in quartz porphyry and lamprophyre into dolomite/ankerite and sericite.Despite the lamprophyre is volumetrically minor and much less fractured than other host rocks,it contains a large portion of Au reserve,indicating that the chemically active lithology has played a more important role in gold precipitation compared to structure.LA-ICP-MS analysis shows that Au mainly occurs as invisible gold in fine-grained pyrite disseminated in the host rocks,with Au content reaching to 258.95 ppm.The diagenetic core of pyrite in meta-quartz sandstone enriched in Co,Ni,Mo,Ag and Hg is wrapped by hydrothermal pyrite enriched in Cu,As,Sb,Au,Tl,Pb and Bi.Different host rock lithology has much impact on the alteration and mineralization features.Carbonate and sericite in altered lamprophyre show they have higher Mg than those developed in other of host rocks denoting that the carbonate and sericite incorporated Mg from phlogopite phenocrysts in the primary lamprophyre during alteration.The ore fluid activated the diagenetic pyrite in meta-quartz sandstone leading the hydrothermal pyrite enriched in Cu,Mo,Ag,Sb,Te,Hg,Tl,Pb and Bi,but the hydrothermal pyrite in meta-(ultra)mafic rock is enriched in Co and Ni as the meta-(ultra)mafic rock host rock contain high content of Co and Ni.However,Au and As shear similar range in both types of host rocks indicating that these two elements most likely come from the deep source fluid rather than the host rocks.It was shown in the disseminated orogenic gold deposit that similar hydrothermal alteration with mineral assemblage of carbonate(mainly dolomite and ankerite),sericite,pyrite and arsenopyrite develops in all types of host rocks.This is different from the Nevada Carlin type,in which alteration is mainly dissolution and silicification of carbonate host rock.On the other hand,Au mainly occur as invisible gold in both disseminated orogenic and Carlin gold deposits.     

Element mobility during continental collision: insights from polymineralic metamorphic vein within UHP eclogite in the Dabie orogen

Metamorphic dehydration and partial melting are two important processes during continental collision. They have significant bearing on element transport at the slab interface under subduction‐zone P–T conditions. Petrological and geochemical insights into the two processes are provided by a comprehensive study of leucocratic veins in ultrahigh‐pressure (UHP) metamorphic rocks. This is exemplified by this study of a polymineralic vein within phengite‐bearing UHP eclogite in the Dabie orogen. The vein is primarily composed of quartz, kyanite, epidote and phengite, with minor accessory minerals such as garnet, rutile and zircon. Primary multiphase solid inclusions occur in garnet and epidote from the both vein and host eclogite. They are composed of quartz ± K‐feldspar ± plagioclase ± K‐bearing glass and exhibit irregular to negative crystal shapes that are surrounded by weak radial cracks. This suggests their precipitation from solute‐rich metamorphic fluid/melt that involved the reaction of phengite breakdown. Zircon U–Pb dating for the vein gave two groups of concordant ages at 217 ± 2 and 210 ± 2 Ma, indicating two episodes of zircon growth in the Late Triassic. The same minerals from the two rocks give consistent δ¹⁸O and δD values, suggesting that the vein‐forming fluid was directly derived from the host UHP eclogite. The vein is much richer in phengite and epidote than the host eclogite, suggesting that the fluid is associated with remarkable concentration of such water‐soluble elements as LILE and LREE migration. Garnet and rutile in the vein exhibit much higher contents of HREE (2.2–5.7 times) and Nb–Ta (1.8–2.0 times) than those in the eclogite, indicating that these normally water‐insoluble elements became mobile and then were sunken in the vein minerals. Thus, the vein‐forming agent would be primarily composed of the UHP aqueous fluid with minor amounts of the hydrous melt, which may even become a supercritical fluid to have a capacity to transport not only LILE and LREE but also HREE and HFSE at subduction‐zone metamorphic conditions. Taken together, significant amounts of trace elements were transported by the vein‐forming fluid due to the phengite breakdown inside the UHP eclogite during exhumation of the deeply subducted continental crust.     

Hydrous and anhydrous alterations of chondrules in Kaba and Mokoia CV chondrites

Abstract— Chondrules in the Bali-like CV chondrite Kaba and the Allende-like portion of the Mokoia breccia have been studied to explore the relationship between hydrous alteration to form phyllosilicates and anhydrous alteration resulting in secondary olivine zonation, replacement of enstatite by ferroan olivine and formation of feldspathoids (nepheline and sodalite). All Kaba chondrules experienced extensive hydrous alteration; whereas, anhydrous alteration was minor and resulted only in the olivine zonation. On the other hand, all of the Mokoia chondrules experienced both extensive anhydrous and hydrous alteration. Bronzite rims formed between relic enstatite grains and phyllosilicates in both Kaba and Mokoia during the hydrous alteration. Petrographic observations indicate that phyllosilicates in Mokoia postdate formation of the secondary ferroan olivine and feldspathoids. We conclude that anhydrous alteration in Kaba and Mokoia predated hydrous alteration and took place before accretion of chondrules into the CV parent asteroid.     

A note on the deflection of a baroclinic current by a continental shelf

The deflection, at a step-shelf fronted coast, of a constant potential vorticity current in a reduced-gravity, inviscid model ocean is studied theoretically. The step shelf, with a depth smaller than the reservoir depth, forces the uplifting of the approaching current and causes water column foreshortening, leading to relative vorticity generation that enhances current deflection to the right (facing the coast). As a consequence, in comparison to the case of a vertical wall coast, the proportion of the transport to the right is increased. For normal incidence for a shelf-depth/reservoir-depth ratio of 0.3 and shelf width to deformation radius ratio of 1.5, more than 90% of the approaching current transport goes to the right and less than 10% to the left. In addition, the (barotropic) dynamic pressure at the coast is low to the right and high to the left (with the highest pressure at the stagnation point). In the vertical wall case, the wall pressures on the flank are equal. For oblique incidence from the left, the deflection to the left is drastically reduced. In fact, there is practically no steady-state flow diverted to the left (less than 2%) when the approach angle is greater than 60° to the left of normal. In the vertical wall case, the same angle would have to be 90° for the flow to the left to vanish, namely only when the approach current is parallel to the coast to the right.     

桂林岩溶洼地和洞穴发生、发展的构造控制剖析

通过对桂林地质构造和岩溶建造的研究,并对岩溶洼地、洞穴发育特征进行分析,认为它们在发生、发展上具有成生的内在联系,从而反映在时空方面具有特定的关系。 这些关系集中表现在岩溶洼地、洞穴是岩溶水沿断裂、裂隙溶蚀、侵蚀扩大、改造、堆积、再改造的结果。其规律性主要反映在方向性、等距性、继承性、成层性及形态关系等几个方面。 实践表明,研究岩溶发育规律,要对构造控制因素进行分析,必须从构造形迹鉴别入手,分析其成生联系、体系归属,了解地质构造的发生。发展阶段和序次,并以此和岩溶岩系(建造)为依据,联系成岩环境(特征)和水文地质条件进行综合分析,才能客观反映构造的控制规律。      

Numerical reconstruction of trajectory of small-size surface drifter in the Mediterranean sea

In this study, we addressed the effects of wind-induced drift on Lagrangian trajectories of surface sea objects using high-resolution ocean forecast and atmospheric data. Application of stochastic Leeway model for prediction of trajectories drift was considered for the numerical reconstruction of the Elba accident that occurred during the period 21.06.2009–22.06.2009: a person on an inflatable raft was lost in the vicinity of the Elba Island coast; from the initial position, the person on a raft drifted southwards in the open sea and later he was found on a partially deflated raft during rescue operation. For geophysical forcing, we used high-resolution currents from the Mediterranean Forecasting System and atmospheric wind from the European Centre for Medium-Range Weather Forecasts. To investigate the effect of wind on trajectory behavior, numerical simulations were performed using different categories of drifter-like particles similar to a person on an inflatable raft. An algorithm of spatial clustering was used to differentiate the most probable search areas with a high density of particles. Our results showed that the simulation scenarios using particles with characteristics of draft-limited sea drifters provided better prediction of an observed trajectory in terms of the probability density of particles.     

军曹鱼不同组织5种同工酶的研究

采用聚丙烯酰胺垂直凝胶电泳法对军曹鱼的几种组织 (脑、心肌、肾、肌肉、性腺、肝、血液、胰、脾 )的 5种同工酶 (LDH、MDH、ME、POD和EST)进行了分析 ,结果表明 :5种同工酶在军曹鱼中都具有明显的组织特异性 ,这些特异性与其组织特定生理功能相关。与其他硬骨鱼类相比 ,军曹鱼的酶谱简单得多 ,这可能与其种属多样性相关。     

Biogeochemistry of nitrous oxide in groundwater in a forested ecosystem elucidated by nitrous oxide isotopomer measurements

The biological and physical controls on microbial processes that produce and consume N₂O in soils are highly complex. Isotopomer ratios of N₂O, with abundance of ¹⁴N¹⁵N¹⁶O, ¹⁵N¹⁴N¹⁶O, and ¹⁴N¹⁴N¹⁸O relative to ¹⁴N¹⁴N¹⁶O, are promising for elucidation of N₂O biogeochemistry in an intact ecosystem. Site preference, the nitrogen isotope ratio of the central nitrogen atom minus that of the terminal nitrogen atom, is useful to distinguish between N₂O via hydroxylamine oxidation and N₂O via nitrite reduction.We applied this isotopomer analysis to a groundwater system in a temperate coniferous-forested ecosystem. Results of a previous study at this location showed that the N₂O concentration in groundwater varied greatly according to groundwater chemistry, i.e. NO₃⁻, DOC, and DO, although apportionment of N₂O production to nitrification or denitrification was ambiguous. Our isotopic analysis (δ¹⁵N and δ¹⁸O) of NO₃⁻ and N₂O implies that denitrification is the dominant production process of N₂O, but definitive information is not derived from δ¹⁵N and δ¹⁸O analysis because of large variations in isotopic fractionations during production and consumption of N₂O. However, the N₂O site preference and the difference in δ¹⁵N between NO₃⁻ and N₂O indicate that nitrification contributes to total N₂O production and that most measured N₂O has been subjected to further N₂O reduction to N₂. The implications of N₂O biogeochemistry derived from isotope and isotopomer data differ entirely from those derived from conventional concentration data of DO, NO₃⁻, and N₂O. That difference underscores the need to reconsider our understanding of the N cycle in the oxic-anoxic interface.     

Linear and nonlinear vibration of non-uniform beams on two-parameter foundations using p-elements

A hierarchical finite element is presented for the geometrically nonlinear free and forced vibration of a non-uniform Timoshenko beam resting on a two-parameter foundation. Legendre orthogonal polynomials are used as enriching shape functions to avoid the shear-locking problem. With the enriching degrees of freedom, the accuracy of the computed results and the computational efficiency are greatly improved. The arc-length iterative method is used to solve the nonlinear eigenvalue equation. The computed results of linear and nonlinear vibration analyses show that the convergence of the proposed element is very fast with respect to the number of Legendre orthogonal polynomials used. Since the elastic foundation and the axial load applied at both ends of the beam affect the ratios of linear frequencies associated with the internal resonance, they influence the nonlinear vibration characteristics of the beam. The axial tensile stress of the beam in nonlinear vibration is investigated in this paper, and attention should be paid to the geometrically nonlinear vibration resulting in considerably large axial tensile stress in the beam.     

Strontium isotopic and chemical variations of the granitic rocks in the Tsukuba district,Japan

Initial ⁸⁷Sr/⁸⁶Sr ratios, major and trace element compositions have been determined for the Paleogene granitic rocks in the Tsukuba district, Japan. Isotopic ages strongly suggest that the granitic rocks (seven units) were continuously emplaced and solidified during a short time interval. Initial ⁸⁷Sr/⁸⁶Sr ratios for seven granitic units vary from 0.7082 to 0.7132, while sedimentary and metasedimentary country rocks have ratios at the time of granitic magma emplacement ranging from 0.7149 to 0.7298. Continuous linear arrays for the granitic rocks in the diagrams of initial ⁸⁷Sr/⁸⁶Sr ratios versus some chemical parameters can be explained by either of following two processes. One is the assimilation — fractional crystallization (AFC) process between the parental magma (SiO₂ of 68% and initial ratio of 0.7078) and sedimentary country rocks, and the other is magma mixing process between above parental magma and sediment derived acidic magma (melt) (SiO₂ of 75%). The high initial ratios (0.7078–0.7098) for basic rocks such as gabbro or diorite in the Tsukuba district and the similar characteristics observed in the rocks of Ryoke belt (SW Japan) suggest that the parental magma had the same source region as the basic rocks, probably the lower crustal source.