Dissolution mechanisms of water in depolymerized silicate melts: Constraints from H and Si NMR spectroscopy and ab initio calculations

Dissolution of water in magmas significantly affects phase relations and physical properties. To shed new light on the this issue, we have applied ¹H and ²⁹Si nuclear magnetic resonance (NMR) spectroscopic techniques to hydrous silicate glasses (quenched melts) in the CaO-MgO-SiO₂ (CMS), Na₂O-SiO₂, Na₂O-CaO-SiO₂ and Li₂O-SiO₂ systems. We have also carried out ab initio molecular orbital calculations on representative clusters to gain insight into the experimental results.The most prominent result is the identification of a major peak at ∼1.1 to 1.7 ppm in the ¹H MAS NMR spectra for all the hydrous CMS glasses. On the basis of experimental NMR data for crystalline phases and ab initio calculation results, this peak can be unambiguously attributed to (Ca,Mg)OH groups. Such OH groups, like free oxygens, are only linked to metal cations, but not part of the silicate network, and are thus referred to as free hydroxyls in the paper. This represents the first direct evidence for a substantial proportion (∼13∼29%) of the dissolved water as free hydroxyl groups in quenched hydrous silicate melts. We have found that free hydroxyls are favored by (1) more depolymerized melts and (2) network-modifying cations of higher field strength (Z/R²: Z: charge, R: cation-oxygen bond length) in the order Mg > Ca > Na. Their formation is expected to cause an increase in the melt polymerization, contrary to the effect of SiOH formation. The ²⁹Si MAS NMR results are consistent with such an interpretation. This water dissolution mechanism could be particularly important for ultramafic and mafic magmas.The ¹H MAS NMR spectra for glasses of all the studied compositions contain peaks in the 4 to 17 ppm region, attributable to SiOH of a range of strength of hydrogen bonding and molecular H₂O. The relative population of SiOH with strong hydrogen bonding grows with decreasing field strength of the network-modifying cations. Ab initio calculations confirmed that this trend largely reflects hydrogen bonding with nonbridging oxygens.     

金坛市开发区的数字影像测图

为完善数字化测图功能，通过全数字摄影测量系统(VirtuoZo)的数字影像测图模块(IGS)在金坛市开发区1：500测区中的应用，总结提高测图精度和速度的体会。     

基于GIS的油气储层综合评价方法研究

通过对现有的商用地理信息系统的分析，剖析了传统的储层综合评价方法及存在的问题。充分利用GIS工具，建立油气储层评价空间数据库，整合各种与储层相关的多学科油田图形信息及其相关属性信息，利用GIS与储层评价模型集成解决油气储层评价问题，扩展了GIS的空间分析功能，实现了油气储层评价的科学性和完备性，并以西部某油田为例进行了实例分析。     

常州市数字化测绘工程及GIS建库概述

数字化地形图和地籍图是城市规划、建设和管理及国土资源管理的重要基础资料．也是开展数字城市和信息化建设的最基础平台。通过对系统总体结构的设计和应用成果介绍，分析了目前基础地理数据生产、管理和应用的现状，介绍了基于GIS的常州市数字化地形图、地籍图测绘工程总体目标及基础地理信息系统总体设计．并概述了整个数字化测绘工程的实施过程和特点。     

矢量地形图拓扑等问题的研究与实践

对矢量地图生产过程中常见的图形拓扑、数据冗余问题进行分析和研究；在此基础上结合生产实践，提出了相应的解决办法。研制了基于AutoCAD2000平台的相关程序。     

Geographical distribution of ecological footprint and sustainability analysis for Liaoning Province

This paper presents the detailed results and analyses on the ecological footprints and bio-capacities of the individual cities and the province as a whole for the year 2001, providing a clear picture of sustainability for the province. Results show that the ecological footprints of most cities in Liaoning exceeded their respective bio-capacities, incurring high ecological deficits. The ecological deficit of the province as a whole was 1.31 ha/cap. Those cities with resources extraction and/or primary material-making as their major industries constitute the "ecologically black band", whose ecological deficits ranged from 2.45 to 5.23 ha/cap, the highest of all cities in the province. Fossil energy consumption was the major source of footprint amounting to 1.63 ha/cap at the provincial level, taking up 67.3% of the total. For cropland, modest ecological surpluses occurred in Jinzhou, Tieling, Huludao, and Panjin while modest ecological deficits in Dalian, Benxi, Fushun, and Dandong, resulting in an overall surplus for the province. Liaoning had a certain level of surplus in fishing ground (water area), mainly distributed in the coastal cities of Dalian, Panjin, Huludao, Yingkou, Jinzhou, and Dandong. Most cities had a small ecological deficit in pasture and all had a small ecological surplus in forest. The eco-efficiency, expressed as GDP value per hectare of footprint, exhibits high variations among the cities, with the highest (Shenyang) more than 10 times the lowest (Fuxin). Cities with manufacture, high-tech, and better developed service industries had high eco-efficiency, while those with resources extraction, primary material-making, and less developed service industries had low eco-efficiency. Based on the components and geographical distribution of ecological footprint, strategic policy implications are outlined for Liaoning's development toward a sustainable future.     

2004年齐河县小麦全生育期气象条件分析

通过对2003-2004年齐河县冬小麦全生育期的气象条件分析,发现有利的气象条件和合理灌溉、科学施肥是小麦高产的主要因素,评价了气象条件对小麦生长和产量的影响.     

西安市冬季冷暖的历史演变对采暖的影响

本文针对CAPPS2.0系统在业务化自动运行过程中的一些问题,提供了一套具体可行的解决方案,实现了CAPPS系统的全自动运行,具有很高的实用价值。     

侯马市酸雨概况及其气象条件分析

通过对侯马近14a酸雨观测资料分析,发现侯马出现酸雨的概率较大,强度较强,时间变化特征明显,与气象条件关系密切。     

Chemical forms of heavy metal contaminants in sediments of Miyun reservoir

The chemical forms, spatial distribution and sources of As, Hg, Cd, Pb and Zn in sediments of the Miyun reservoir were studied. The results of sequential extraction demonstrate that most of As, Pb and Zn were bound to the residual fraction, Hg was associated with the sulfide fraction while Cd was associated with the carbonate fraction and the residual fraction. On the vertical profiles the concentrations of the heavy metals in total and each fractions mostly decreased with increasing depths in sediments, suggesting that the heavy metals input from the upstream watershed increases yearly. Summation of the residual fraction, the sulfide fraction and the carbonate fraction accounts for 60.03%―85.60% of the total heavy metal contents in the sediments, which represent the geochemical background values of the elements and relate closely to soil erosion. Results of the main factor analysis show that most sediments of the reservoir come from the upstream soil erosion, the point source pollution and domestic waste. Moreover, the microbial activities taking place on the sediment-water interface are also one of the major factors to cause the increasing content of the organic matter fraction and the iron-manganese oxide fraction. Environmental change of the reservoir water could make the removability of the heavy metals increase, leading to the increase of their concentrations in pore water in sediments, and imperiling water quality of the reservoir.