The Zoulang Nanshan Caledonian Subduct ion Complex in the Northern Qilian Mountains and Its Dynamics

The front of the Zoulang Nanshan Caledonian volcanic island arc zone in the northern Qilian Mountains is a forearc accretionary terrane, composed of multiple accretionary volcanic island arcs, flysch accretionary wedges,high-pressure metamorphosed detachment zones and remnants of ophiolites. It resulted from the northeastward subduction of the Early Palaeozoic Qilan oceanic crust beneath the Alxa block. High-pressure metamorphism, which occurred during the subduction, progressed through three stages: the initial stage of medium T-high P,the main stage of temperature decrease and pressure increase, and the lag stage of pressure decrease and temperature increase. Finally the paper presents a retrotrench subduction dynamic model indicative of northward subduction of the central Qilian block and southward accretion of the Alxa block during the period of 450-500 Ma.     

离子色谱法测定矿物包裹体中阴离子

本文介绍了用离子色谱法同时测定矿物包裹体中F~-、Cl~-、PO_4~(3-)、Br~-、NO_3~-、SO_4~(2-)6种阴离子的新方法。研究了流动相浓度对保留时间的影响以及消除负峰干扰的方法。     

全球前寒武—寒武系含油气盆地石油地质特征及成藏主控因素

前寒武—寒武系油气作为我国中西部含油气盆地未来油气勘探的重要接替领域,近年来受到广泛关注。本文以阿曼和东西伯利亚盆地为例,阐述全球典型前寒武—寒武系古老含油气盆地石油地质特征及成藏主控因素,为国内前寒武—寒武系油气勘探取得进一步突破提供参考。阿曼和东西伯利亚盆地烃源岩主要发育在盆地初始裂陷作用区,受埋深及地温梯度控制,在志留纪或泥盆纪之前就已大量生油;储集层岩性以砂岩为主,分布面积广,受表生风化淋滤、胶结物溶蚀及构造裂缝改造等后期作用影响,可形成优质区域性储层;优质的区域性盖层是前寒武—寒武系古老油气藏得以保存的关键性因素,盆地膏盐岩累计厚度都超过1 000m。塔里木盆地寒武系盐下深层含油气层系,同国外古老含油气盆地相比,同样具有多套高丰度优质烃源岩生烃、厚层区域性膏盐岩封堵及长距离运移、多层系成藏特征,具有良好的油气勘探潜力。     

柴达木盆地三湖地区第四系沉积相与生物气成藏

柴达木盆地三湖地区第四系蕴藏着巨大的生物气资源,目前已探明加控制天然气储量接近3×1011m3。更新世时期,柴达木盆地的湖相沉积主要分布在三湖(吉乃尔湖、涩聂湖和达布逊湖)地区,自山前至盆地中心依次发育了冲积扇、河流三角洲和湖相沉积,其中湖相沉积分布最为广泛。早更新世湖相沉积开始形成,中更新世湖相沉积扩张并且达到鼎盛,晚更新世湖相沉积开始萎缩并形成盐湖沉积。中、早更新世冰川的出现和青藏高原的崛起使柴达木盆地的古气候变得干旱寒冷,沉积水体温度较低,盐度较高。本区第四纪独特的沉积环境是形成大型生物气藏最重要的地质条件。高盐度的水体环境减缓了有机质的降解速度,长期的低温条件抑制了甲烷菌的活动,避免了沉积有机质在沉积浅埋阶段的过量消耗,推迟了生物产气的高峰期。而三湖地区巨厚的第四系暗色泥岩和频繁发育的砂岩提供了充足的气源条件和构成了良好的生储盖组合。     

In situ infiltration test using a reclaimed abandoned river bed: managed aquifer recharge in Shijiazhuang City,China

Managed aquifer recharge (MAR) is necessary for water resources management in arid and semiarid regions. Infiltration rate is often a decisive limiting factor in site selection for MAR. In order to avoid scale effects in the application of infiltration rate parameters, the largest in situ infiltration test in China was undertaken between August 19 and August 30, 2009 to measure the infiltration rate of the field selected for MAR in Shijiazhuang City, China. The in situ test lasted for 10 days, and about 1.82 × 10⁷ m³ of water was introduced into the infiltration field. Groundwater level variations were monitored during the test. Monitoring showed that the infiltration rate of surface water was 1.5 m/day, which means that about 10–15 × 10⁸ m³/a of water could be injected into the target aquifer. Also, groundwater level variations showed that the northern part of the infiltration field had a higher infiltration rate, as predicted, and the test result supplied a sound foundation for validation of the groundwater numerical simulation, which will be of benefit for future predictions of the response of the groundwater level to artificial recharge engineering. Finally, an artificial recharge plan was proposed based on the infiltration test results and the water source conditions, which would be useful for the development of MAR programs and management of local water resources.     

右江盆地含油气成矿流体性质及其成藏-成矿作用

右江盆地含油气成矿流体是一种多组分、多相态的不混溶体系,成藏流体具低温(多为90～160℃)和低盐度(多小于6wt%NaCl)的特征,其主要组分是有机质、CO2和H2O;金矿成矿流体以中低温(多集中于150～250℃)和低盐度(0.4～6.7wt%NaCl)为特征,其主要组分为H2O和CO2,次为烃类有机组分。盆地内古油藏与金矿床在空间上密切共存,在成藏和成矿流体活动时限上基本一致,在成因上一脉相承,表明两者均为盆地有机成矿流体演化的产物。加里东晚期至印支中期,"盆-台相间"的沉积构造格局为成矿和成藏奠定了物质基础,盆地有机成矿流体的活动使油气和金属分别聚集形成油气藏和金属矿床。印支晚期至燕山早期,伴随褶皱造山作用的盆地流体活动使油气的原始分布格局发生改变,并造成了油气和金属矿床的空间分带。燕山中晚期强烈的构造抬升剥蚀,使油气藏和金属矿床遭受强烈的破坏与改造。     

Os, Pb, and Nd isotope geochemistry of the Permian Emeishan continental flood basalts: Insights into the source of a large igneous province

The nature of the source of continental flood basalts (CFB) is a highly debated topic. Proposed mantle sources for CFBs, including both high- and low-Ti basalts, include subcontinental lithospheric mantle (SCLM), asthenospheric mantle, and deep, plume-related mantle. Re-Os isotope systematics can offer important constraints on the sources of both ocean island basalts (OIB) and CFB, and may be applied to distinguish different possible melt sources. This paper reports the first Re-Os isotope data for the Late Permian Emeishan large igneous province (LIP) in Southwest China. Twenty one CFB samples including both low- and high-Ti basalts from five representative sites within the Emeishan LIP have been analyzed for Os, Nd, and Pb isotopic compositions. The obtained Os data demonstrate that crustal assimilation affected Os isotopic compositions of some Emeishan basalt samples with low Os concentrations but not all of the samples, and the Emeishan basalts with high Os contents likely experienced the least crustal contamination. The low and high-Ti basalts yield distinct Os signatures in terms of ¹⁸⁷Os/¹⁸⁸Os and Os content. The low-Ti basalt with the highest Os concentration (400 ppt) has a radiogenic Os isotopic composition (γOs(t), +6.5), similar to that of plume-derived OIB. Because the Os isotopic composition of basalts with relatively high Os concentrations (typically >50 ppt) likely represents that of their mantle source, this result implies a plume-derived origin for the low-Ti basalts. On the other hand, the high-Ti basalts with high Os concentration (over 50 ppt) have unradiogenic Os isotopic signatures (γOs(t) values range from −0.8 to −1.4), suggesting that a subcontinental lithosphere mantle (SCLM) component most likely contributed to the generation of these magmas. Combining Pb and Nd isotopic tracers with the Os data, we demonstrate that the low-Ti basaltic magmas in the Emeishan CFB were mainly sourced from a mantle plume reservoir, whereas the high-Ti basaltic magmas were most likely derived from a SCLM reservoir or were contaminated by a significant amount of lithospheric mantle material during plume-related magma ascent through the SCLM.     

冈底斯明则-程巴斑岩-夕卡岩型Mo-Cu矿床成矿时代与含矿岩石成因

冈底斯东南缘克鲁-冲木达矿带以发育渐新世斑岩-夕卡岩型Mo-W-Cu成矿作用而有别于冈底斯中新世斑岩-夕卡岩型Cu-Mo-Au矿带,但是对渐新世成矿岩石类型及成因以及渐新世与中新世斑岩成矿作用存在差异的原因尚不清楚,严重制约了该带矿产资源潜力评价.为此,本文选择矿带内程巴斑岩型Mo矿床及明则夕卡岩型Cu矿床开展了成岩与成矿年代学及含矿岩石成因研究.明则矿区与夕卡岩矿化有关的二长岩的结晶年龄为30.4±0.6Ma,表明夕卡岩矿化时代约30Ma,这与程巴斑岩型Mo矿床矿石中辉钼矿Re-Os同位素分析所揭示的约30Ma矿化时代一致.明则二长岩的SiO2含量为55％ ～57％,K2O含量为2.7％ ～5.0％,属于钾玄岩,具有较高的MgO含量(3.5％～6.9％)、Mg#值(57.6～67.2)以及相容元素含量(Cr =34×10-6 ～379×10-6;Ni为48×10-6～116×10-6).而程巴花岗闪长岩的SiO2含量为65％ ～ 67％,K2O含量为3.2％～4.1％,属于高钾钙碱性岩,具有较低的MgO含量(1.7％～2.1％)、Mg#值(49.5～51.1)以及相容元素含量(Cr =20×10-6～39×10-6;Ni为16×10-6 ～25×10-6).二长岩和花岗闪长岩均显示富集轻稀土元素与大离子亲石元素,亏损高场强元素,具有弱的Eu负异常,但二长岩的REE含量明显高于花岗闪长岩,且具有较低的Sr/Y比值(24 ～49),后者Sr/Y比值为54～68.两种岩石均具有类似的Hf同位素组成,二长岩的εHf(t)值为+2.8～+6.8,花岗闪长岩εHf(t)值为+4.2～ +6.1.综合分析表明,二长岩是受大洋板片流体交代的富集岩石圈地幔部分熔融的产物,而花岗闪长岩是增厚的新生下地壳部分熔融的产物,二者在形成过程中可能发生了幔源镁铁质岩浆与壳源长英质岩浆的混合作用,这种壳幔相互作用导致区域斑岩-夕卡岩型Cu-Mo矿化,但由于该区隆升剥蚀强烈,上部的斑岩型Cu矿体基本被剥蚀而没有保存下来,因此现今表现为斑岩型Mo矿床.     

The significance and relationships among substitutive climatic proxies in the Holocene at the middle Loess Plateau in China

The substitutive climatic proxies contain climate data, including temperature, rainfall, monsoon, and so on. However, the environmental significance and relationships among climatic proxies remain uncertain. In this research, soil samples from three soil profiles in the Holocene at the middle Chinese Loess Plateau were studied to analyze the change of seven substitutive climatic proxies. The rescaled range analysis method and Pearson correlation coefficient were employed to determine the significance and relationships among these proxies. The results indicated that the magnetic susceptibility of soil, total ferrum content, and pH can reflect changes in both temperature and rainfall during soil formation. In addition, calcium carbonate content and total organic carbon were mainly affected by the rainfall and temperature, respectively. Particle size composition (clay fraction <0.005 mm and coarse silt 0.01–0.05 mm) is an effective means by which to describe the effects of the East Asian winter monsoon. The results of this study provide theoretical basis and scientific reference for further paleoclimate evolution research.     

中国南方离子吸附型稀土矿床成矿类型及其母岩控矿因素探讨

传统认为中国南方的离子吸附型稀土矿床可划分为以“足洞式”为代表的重稀土型和以“河岭式”(或“花山式”)为代表的轻稀土型两种矿化类型。然而，近年来发现的许多矿床(如清溪、寨背和馒头山等)的赋矿风化壳中出现了轻稀土矿与重稀土矿并存现象，表现出特殊的“上轻下重”双层矿体结构。这指示了除重稀土型和轻稀土型之外，还存在着轻重稀土共生型的过渡类型。本研究通过对三种不同成矿类型的若干典型矿床系统对比，指出成矿类型的多样性与母岩性质密切相关，尤其是母岩的稀土元素地球化学和稀土载体矿物属性是制约成矿类型变化的关键因素。统计数据表明，从重稀土型→轻重稀土共生型→轻稀土型，成矿母岩的全岩稀土总量变化不大(ΣREY: 200×10-6~450×10-6→200×10-6~500×10-6→200×10-6~800×10-6)，但轻重稀土配分值出现较显著的区间性差异(ΣLREE/ΣHREY: 02~1→1~5→2~10)。与之同时，母岩中能为离子相稀土提供物源且具有重稀土配分属性的稀土副矿物类型和数量明显减少，这与全岩稀土元素地球化学特征中重稀土分量占比的降低趋势也互相匹配。该结果指示，以往认为重稀土配分母岩形成重稀土矿床、轻稀土配分母岩形成轻稀土矿床的传统观点需要外延，即一部分具有低度轻稀土配分属性(1＜ΣLREE/ΣHREY＜5)且含有丰富易风化稀土副矿物的母岩还可能形成轻重稀土共生型矿床，该认识可为今后离子吸附型稀土矿床勘查工作提供新的找矿依据。