Delayed geochemical hazard: Concept, digital model and case study

Delayed Geochemical Hazard (DGH briefly) presents the whole process of a kind of serious ecological and environmental hazard caused by sudden reactivation and sharp release of long-term accumulated pollutant from stable species to active ones in soil or sediment system due to the change of physical-chemical conditions (such as temperature, pH, Eh, moisture, the concentrations of organic matters, etc.) or the decrease of environment capacity. The characteristics of DGH are discussed. The process of a typical DGH can be expressed as a nonlinear polynomial. The points where the derivative functions of the first and second orders of the polynomial reach zero, minimum and maximum are keys for risk assessment and harzard pridication.The process and mechanism of the hazard is due to the transform of pollutant among different species principally. The concepts of "total releasable content of pollutant", TRCP, and "total concentration of active specie", TCAS, are necessarily defined to describe the mechanism of DGH. The possibility of the temporal and spatial propagation is discussed. Case study shows that there exists a transform mechanism of "gradual release" and "chain reaction" among the species of the exchangeable and the bounds to carbonate, iron and manganese oxides and organic matter, thus causing the delayed geochemical hazard.     

Chemical forms of heavy metal contaminants in sediments of Miyun reservoir

The chemical forms, spatial distribution and sources of As, Hg, Cd, Pb and Zn in sediments of the Miyun reservoir were studied. The results of sequential extraction demonstrate that most of As, Pb and Zn were bound to the residual fraction, Hg was associated with the sulfide fraction while Cd was associated with the carbonate fraction and the residual fraction. On the vertical profiles the concentrations of the heavy metals in total and each fractions mostly decreased with increasing depths in sediments, suggesting that the heavy metals input from the upstream watershed increases yearly. Summation of the residual fraction, the sulfide fraction and the carbonate fraction accounts for 60.03%―85.60% of the total heavy metal contents in the sediments, which represent the geochemical background values of the elements and relate closely to soil erosion. Results of the main factor analysis show that most sediments of the reservoir come from the upstream soil erosion, the point source pollution and domestic waste. Moreover, the microbial activities taking place on the sediment-water interface are also one of the major factors to cause the increasing content of the organic matter fraction and the iron-manganese oxide fraction. Environmental change of the reservoir water could make the removability of the heavy metals increase, leading to the increase of their concentrations in pore water in sediments, and imperiling water quality of the reservoir.     

近1800年以来内蒙古达里湖浮游植物群落演变及驱动因素

湖泊是地质历史上区域生态环境演变的重要载体,其沉积物中包含了丰富的环境演变信息。达里湖是典型的草原内陆封闭型湖泊,位于东亚夏季风的北部边缘,地理位置关键。本研究基于在达里湖采集的约238 cm沉积物岩芯 (GDL-1),通过²¹⁰Pb和¹³⁷Cs (岩芯上部20 cm)、AMS¹⁴C测年,以及沉积物样品中甾醇等生物标志物含量分析,重建了近1800年以来达里湖硅藻、蓝藻等典型藻类含量的演化历史,并结合总氮(TN)、总磷(TP)、盐度(Sr/Ba)和温度(T)等环境代用指标,分析藻类群落的主要影响因素。结果显示达里湖典型藻类总量平均为2.03 ng/g(最高6.69 ng/g,最小0.53 ng/g),其中蓝藻占比平均为60%,绿藻和硅藻占比平均为20%;环境因子对硅藻、蓝藻和典型藻类生物量的解释率分别为47.7%、55.20%和48.10%,T、TN和Sr/Ba是影响浮游植物群落的主要影响因素;硅藻占比与温度呈显著负相关,小冰期硅藻占比最高,中世纪暖期占比最低;在达里湖的高盐环境下,湖泊营养盐浓度对藻类的影响受到限制,成为藻类等生长的限制因素;Sr/Ba小于0.9时,硅藻含量与典型藻类总量随着Sr/Ba值的升高而增加,Sr/Ba大于0.9时,典型藻类总量与Sr/Ba值呈负相关关系,而硅藻则表现出对盐度具有一定的耐受性;整体上,近1800年以来,区域或全球性气候事件通过改变达里湖盐度、营养元素浓度和温度来影响典型藻类群落结构。在暖期阶段,蒸发作用增强等导致的湖泊盐度增加成为达里湖典型藻类群落结构演变的主要影响因素;在冷期,营养元素浓度和温度的降低成为湖泊水体浮游植物生物量的主要影响因素。     

太湖表层沉积物多环芳烃的空间分布、来源及其风险

随着太湖流域社会与经济的发展,多环芳烃(PAHs)在各种环境介质中逐渐累积,污染日益严重,可能对太湖生态环境及周边人体健康构成威胁。为探究太湖沉积物PAHs的来源及生态风险,于2021年12月在太湖采集30个表层沉积物样品,利用气相色谱-质谱联用仪(GC-MS)检测样品中16种PAHs含量;利用受体模型和苯并[a]芘(BaP)毒性当量法进行来源解析及生态风险评估,并将各来源贡献与毒性当量浓度相结合,量化源风险。结果表明,太湖表层沉积物中16种PAHs总含量介于124~592 ng/g之间,平均值为294 ng/g,中值为279 ng/g;高环多环芳烃(HMW PAHs)为主要组分,占∑PAHs的67%。高含量区域位于竺山湾、梅梁湾、贡湖湾和西太湖,与国内外其他湖泊沉积物相比,太湖沉积物PAHs含量处于较低水平。源解析的结果表明,太湖表层沉积物中PAHs交通排放源贡献率为29.1%、煤炭燃烧源贡献率为26.7%、生物质燃烧源贡献率为28.7%、石油源贡献率为15.6%。生态风险评价结果表明,交通排放源、生物质燃烧源、煤炭燃烧源和石油源的BaP毒性当量含量(TEQ_BaP)均值分别为19.34、17.81、16.33和9.1 ng/g,均小于70 ng/g,几乎处于无风险水平。西太湖、贡湖湾和梅梁湾的部分区域ΣTEQ_BaP大于70 ng/g属于潜在风险区,具有一定潜在毒性。在后续的污染治理中应重点关注太湖西北部地区污染物的排放。本研究可为沉积物中PAHs污染的研究提供数据支撑,为地方政府精准、高效地管控PAHs污染提供理论依据。     

桥梁气象专题研究与服务

根据实际开展的桥梁气象专题研究，分析桥梁气象研究与服务如何面对国内大型桥梁建设发展趋势所带来的机遇和挑战，提出开展桥梁气象研究与服务的必要性，并从桥位气候背景、桥位气象参数取值、桥梁气象研究方法以及桥梁施工及营运期气象服务与保障等方面介绍桥梁气象专题研究及服务应开展的主要内容，同时，给出一个已投入实际使用的桥梁施工期气象环境监测与预警系统的建设思路。     

甘青地区新石器-青铜时代居民颅面部形态变异及其在人群形成上的意义

通过对考古遗址出土古代居民遗骸的研究来探寻人群形成、适应、迁徙、融合历史是生物人类学研究的重要内容。甘青地区地处我国西北,位于新疆与中原之间,是人群迁徙与交流的关键地区。以往研究发现该地区新石器-青铜时代居民具有的一些独特的头面部特征,如具有偏狭的中颅型、高颅结合狭颅、中等偏狭的面宽、高而狭的面型、中等的面部扁平度、中眶型、狭鼻型和正颌型。一些学者就来自周边地区人群迁徙或基因交流对甘青地区古代人群形成的影响做过探讨。由于迄今开展的相关研究及掌握的数据资料有限,学术界对甘青地区古代人群内部的变异情况、时代变化及其与周边地区人群的差异程度还缺乏深入的了解,对新石器时代以来甘青地区人群的形成过程以及与东、西方人群的关系还不是很清楚。本文通过对243例甘青地区新石器-青铜时代人群颅骨测量数据的统计和分析,结合相关考古学和古环境学资料,对该地区古代居民颅面部形态特征的总体表现特点、时代变化、内部变异及与周边地区人群的关系进行了探讨,发现：1）从整体颅面部特征上看,甘青地区新石器-青铜时代人群介于典型西方人群与中原人群之间,但与中原人群更为接近;2）甘青地区新石器-青铜时代人群颅骨测量特征呈现一定的时代变化。从新石器时代到青铜时代,颅型趋向圆颅和阔颅化、面型趋狭、鼻型趋狭、眶型趋高;齿槽部的突颌水平变小;3）甘青地区古代人群颅面部测量特征的内部变异程度介于新疆与中原人群之间。从新石器时代到青铜时代,甘青地区人群颅面部测量特征的内部变异呈减小趋势;4）从新石器时代到青铜时代,甘青地区古代人群部分颅面部测量特征呈现出与西方人群接近的趋势。基于本文的分析,认为气候环境、生业方式以及人群之间的基因交流共同造成了甘青地区古代人群颅面部形态特征的变化,甘青地区古代人群形成以受到中原人群影响为主。

     

关于辽宁地区b值方法定量预测的研究

本文利用地震学分析预报方法程式指南和“八五”攻关成果中提出的地震b值定量预测方法,对辽宁及邻区1969年以来发生的8次地震震例作了回顾性检验研究。在此基础上,根据震前b值的变化特征,总结出了可能适用于辽宁地区半年左右尺度的b值预测方法的异常羊别指标及预报规则。     

Heavy metal pollution in sediments of a typical mariculture zone in South China

The heavy metal inventory and the ecological risk of the estuarine sediments in Hailing Bay, an important maricultural zone along the southern coast of China, were investigated. Results show that the surface sediments were mainly polluted by As (2.17-20.34 mg/kg), Ni (1.37-42.50mg/kg), Cu (1.21-58.84 mg/kg) and Zn (11.69-219.22 mg/kg). Furthermore, the aquafarming zone was significantly more polluted than the non-aquafarming zone, and cluster analysis suggested additional sources of heavy metal input in the aquafarming zone. As, Cr, Cu, Ni, Pb and Zn were mainly present in the non-bioavailable residual form in the surface sediments, whereas Cd was predominantly in the highly mobile acid soluble and reducible fractions. The ecological risk of the polluted sediments stemmed mainly from Cd, and from As, Cu and Pb to less degrees. The highest potential risks occurred near the aquaculture base, indicating the need to control heavy metal inputs from aquafarming activities.     

峰局五矿下组煤带压开采的可行性与建议

峰局五矿是多年开采的老矿。近些年，随着开采深度的不断增加和开采层次的逐渐下移，来自底部岩溶高承压水的威胁日趋严重，实际生产能力逐年下降。下组煤能否开采是关系到矿井生存与发展的大问题。作者根据多年的研究成果和工作实践，就下组煤带压开采的可行性，谈一些看法和建议。