青海德尔尼铜(锌钴)矿床硫化物Cu同位素组成及矿床成因探讨

青海德尔尼铜(锌钴)矿床产出在北西或北西西向超镁铁质岩带中,对其矿床成因长期以来一直存在争议。文中对德尔尼矿床主矿体不同类型硫化物矿石的Cu同位素组成进行了分析,通过与现代海底正在形成的赋存在超镁铁质岩(蛇纹石化橄榄岩)中的块状硫化物矿床进行类比,从构造背景和矿床地质角度探讨了矿床成因,得出以下主要认识:(1)阿尼玛卿构造带可能存在大型拆离断层,超镁铁质岩体和硫化物矿体的产出均与北西向发育的长期活动拆离断层有关;(2)德尔尼矿床属古代海相火山成因块状硫化物矿床,为赋存在超镁铁质岩体中的一个特殊类型(或称为"德尔尼型");(3)硫化物原生矿石Cu同位素组成均为负值,呈富轻Cu同位素特征,表明矿床经历了广泛的后期热液叠加过程。德尔尼矿床控矿构造、岩体特征和后期叠加成矿过程的深入研究不仅对矿床成因认识和找矿具有重要意义,而且为现代海底慢速-超慢速扩张洋中脊超镁铁质岩热液系统成矿研究提供了参考。     

萃取分离—石墨炉原子吸收光谱法测定铅锌矿中的铟

样品经硝酸、氢氟酸分解除硅,加热硫酸冒烟除尽硝酸、氢氟酸,利用铟与氢溴酸能生成稳定的络合物并被乙酸丁酯萃取的性质,将铟与其它干扰离子分离并富集.使用MOLAARM6（Thermo Electron Corporation）石墨炉原子吸收分光光度计,以钒为机体改进剂,测定铅锌矿中的铟.方法检出限为LD=0.012ug/ml.实验结果令人满意.     

四酸溶矿——电感偶合等离子体发射光谱法测定钼矿中的钼

为了适应地质找矿和地质大普查工作对矿样测定速度和正确度的要求,对钼矿样品中的钼的测定方法进行试验,探讨在敞开体系中用盐酸+硝酸+氢氟酸+高氯酸的四酸溶矿体系消解钼矿样品,使用电感耦合等离子发射光谱仪(ICP-AES)测定钼的方法。     

磨抛光合成新材料在岩矿制片中的应用

作者利用所研制出来的磨抛光合成新材料与传统磨抛光工艺进行了对比试验。通过对多种最常使用的矿物或岩石的反复试验,结果表明合成新材料不仅大大提高了工作效率,还具有抛光速度快(所需时间仅为传统工艺的1/3~1/2),而且抛光效果极佳(基本无糙面或麻点),经久耐用,耗材极低和基本无巴盘打片现象。     

Surface characterization of maize-straw-derived biochars and their sorption performance for MTBE and benzene

Biochars generated at various temperatures might show significant differences in sorption for organic contaminants. In this study, a series of biochars, generated from pyrolyzing maize straws at different temperatures, were systematically characterized. The characterization results showed that with increasing pyrolysis temperature, the surface areas, micropore areas and aromaticity of biochars were enhanced. Batch experiments were conducted to study methyl tert-butyl ether (MTBE) and benzene sorption to biochars. The results indicated that the sorption capacity of benzene to biochars was higher than that of MTBE. The higher pyrolyzed temperature of biochars resulted in a stronger sorption affinity for target compounds, and the dominant sorption mechanisms varied for biochars pyrolyzed at different temperatures. The sorption to biochars pyrolyzed at 700 and 800 °C performed a high adsorption capacity, which indicated that they might be a promising sorbent to remove MTBE and benzene from water. Biochar pyrolyzed at 400 °C showed transitional sorption mechanisms from partition to adsorption for MTBE and benzene. Pore-filling was a possible sorption mechanism to biochars pyrolyzed at high temperature.     

Assessment of the Excavation-Damaged Zone in a Tall Rock Slope Using Acoustic Testing Method

During slope excavation, high stresses can become concentrated in the rock mass because of stress redistribution. Failure of the rock mass creates an excavation-damaged zone (EDZ) in the slope. The damage reduces the acoustic wave velocity in the rock mass. Results of field tests measuring acoustic wave velocity at the Jinping I Hydropower Station are used here to study the EDZ in a tall rock slope. Two acoustic testing methods were adopted in the field tests: single-hole acoustic testing (SAT) and cross-hole acoustic testing (CAT). The acoustic wave velocity was lower in the EDZ, and the depth of the EDZ increased with decreasing slope elevation. Statistical analysis shows that the acoustic wave velocity obtained by the SAT method is larger than that obtained by the CAT method, and the relative difference between the SAT- and CAT-derived velocities is lower for a high quality rock mass than for a low quality rock mass. The integrity ratio and severity of damage can also be determined by acoustic wave velocity test results, revealing that the integrity ratio and elastic modulus of a rock mass are reduced in the EDZ.     

阿尔泰南缘可可托海地区二厂房岩体LA-ICP-MS锆石U-Pb年代学、岩石成因及其地质意义

对出露于阿尔泰造山带南缘可可托海地区二厂房岩体中的黑云母花岗闪长岩进行了LA-ICP-MS锆石U-Pb定年和岩石地球化学分析。结果显示,锆石的²⁰⁶Pb/²³⁸U年龄加权平均值为398.0±3.5 Ma（MSWD=1.3）,表明该岩体形成于早中泥盆世。岩体的SiO₂含量介于65.40%～69.31%之间,里特曼指数值为1.27～1.65,A/CNK值为0.92～1.02,属中钾、钙碱性、准铝质岩石。具有富集Cs、Rb、Th、U等大离子亲石元素和轻稀土元素,相对亏损重稀土元素和Nb、Ta、Zr、Hf等高场强元素,负Eu异常明显（δEu=0.48～0.65）的岛弧岩浆岩特征。结合区域地质资料,认为二厂房岩体形成于陆缘弧构造环境,是在古亚洲洋俯冲过程中,幔源的基性岩浆底侵下地壳后使之熔融并发生了岩浆混合作用的产物。     

Genesis study of high abundant 17a（H）-diahopanes in Lower Cretaceous lacustrine source rocks of the Lishu Fault Depression,Songliao Basin,Northeast China

Relatively abundant 17α（H）-diahopanes have been detected in the lower cretaceous lacustrine source rocks from the Lishu Fault Depression in the Songliao Basin Northeast China. Rich long chain tricyclic terpanes （carbon number up to C35） and gammacerane have been observed in those source rocks with relatively abundant 17α（H）-diahopanes, which is rarely seen in previous reports. In this paper, the formation of 17α（H）-diahopanes has been discussed from three aspects including maturity, oxidation-reduction nature of depositional environment and parent material composition by the GC/MS analyses. The results reveal that maturity and oxidation-reduction nature of depositional environment have little effect on the formation of 1 7α（H）-diahopanes in the investigated area. How- ever, the positive correlation between long-chain tricyclic terpanes and 17α（H）-diahopanes argues strongly for a common origin, and the origin is related to the algaes in saline water environment. The algaes in saline water envi- ronment may be a kind of origin of 1 7α（H）-diahopanes.     

新型旋转减冲装置对桩基局部冲刷防护试验研究

为减轻海上风电单桩基础周围局部冲刷对其结构安全的影响,提出了一种新型旋转减冲装置。在波流水槽中开展物理模型试验,改变波流条件、装置安装高度、安装距离,记录桩周冲刷发展历时,运用激光地形仪扫描冲刷坑形态,分析各工况下冲刷坑形态差异,验证装置不同安装距离、安装高度下的冲刷防护效果,提出了不同安装位置下的防护效率公式。结果表明：新型旋转减冲装置具有较好的冲刷防护效果,本试验工况下,桩周最大冲刷深度可减小44%左右。装置安装距离对冲刷防护效果影响较小,波流作用下的冲刷防护效果受装置安装高度影响显著,冲刷防护效果随装置安装高度的增加而减弱。     

区域土地利用影响地表CO2浓度异质性特征的动力学机制

本文综合应用高斯方程和拉姆齐模型,针对京津冀地区2000年以来10 km×10 km栅格尺度的地表CO₂浓度开展研究,分析了区域土地利用影响地表CO₂浓度异质性特征的动力学机制。研究发现：① 地表CO₂浓度与土地利用类型密切相关。2000—2018年京津冀地区CO₂浓度的高值区主要集中于经济较发达的快速城镇化地区;② 土地利用强度及土地利用效率上的时空分异为地表CO₂扩散提供了潜在的势能。京津冀地区地表CO₂排放及扩散存在明显的空间异质性,距离CO₂排放高值区越近,其相应的CO₂浓度越高并随时间推移及空间拓展呈逐步减小的态势;③ 京津冀地区在土地利用结构调整、格局优化及效率提升后,CO₂排放强度增幅明显减弱,其区域间的增幅差异也逐渐缩小。产业转型发展、土地利用格局优化、土地利用效率提高有效地抑制了京津冀地区地表CO₂排放强度的提升并促进了该区域的内涵式增长与高质量发展。