Decoloration of acidic scarlet GR by pyrolusite is studied in this paper. The effects of pH in solution, dosage and granularity of pyrolusite, reaction temperature, and vibration speed on decoloration efficiency are discussed. According to experiment results, the decoloration efficiency may exceed 95% for 40 mg/L GR solution by pyrolusite. pH is most important among all factors which impact the decoloration of acidic scarlet GR. Dosage and granularity of pyrolusite, reaction temperature, and vibration speed have a little benitfit on decoloration. The high decoloration efficiency and low removal efficiency of COD as well as FT-IR spectra of products between pyrolusite and acidic scarlet GR indicate that acidic scarlet GR undergoes the redox reaction on the interface of mineral and its chromophore is oxidated and decolored, but it is not removed thoroughly by oxidation. 相似文献
Rigid columns penetrating a firm underlying stratum have often been used to enhance the stability and improve the settlement of embankments over soft ground. Furthermore, an inclined underlying stratum is commonly encountered in engineering practice. This investigation experimentally and numerically studies the performance of embankments over soft ground reinforced by rigid columns with various embedment depths. In centrifuge tests, a tilting failure occurs for columns with an embedment depth Le of 2D (D is the diameter of columns), whereas the embankments remain stable for Le of 7D. This result indicates that the inclined underlying stratum weakens the restraint effect at the column base and that a greater embedment depth is required to ensure the stability of embankments. Parametric studies numerically reveal that there exists a critical embedment depth, which represents a shift in the failure mechanism. The optimum column layout is determined based on the contributions of columns in different locations beneath an embankment. Finally, the influence of the embedment depth on the distribution of the bending moment of the columns and the soil reaction are discussed.