The mechanisms of paragenesis and separation of silver, lead and zinc in hydrothermal solutions

On the basis of an experimental study and thermodynamic calculation, the mechanisms of paragenesis and separation of silver, lead and zinc in the hydrothermal system have been studied. At acidic to nearly neutral pH, their chloride complexes are stable, and among them the chloride complexes of zinc are most stable. And the sulfide complexes are the dominant species at nearly neutral to alkaline pH,while the sulfide complexes of silver are most stable. With decreasing temperature, [ Cl^-] ,fO2, and increasing pH, the solubilities of silver, lead and zinc will decrease, leading to their deposition and separation. For sulfide complexes, the concentrations of reduced sulfur and pH are two important factors affecting their stabilities. Complexes of different forms and stabilities respond to the variation of conditions to different extents, which gave rise to the paragenesis and separation of silver, lead and zinc in the whole ore-forming process of dissolution, transport and deposition.     

Dissolved organic matter in surface runoff in the Loess Plateau of China: The role of rainfall events and land-use

Exploring the chemical characterization of dissolved organic matter (DOM) is important for understanding the fate of laterally transported organic matter in watersheds. We hypothesized that differences in water-extractable organic matter (WEOM) in soils of varying land uses and rainfall events may significantly affect the quality and the quantity of stream DOM. To test our hypotheses, characteristics of rainfall-runoff DOM and WEOM of source materials (topsoil from different land uses and gullies, as well as typical vegetation) were investigated at two adjacent catchments in the Loess Plateau of China, using ultraviolet–visible absorbance and excitation emission matrix fluorescence with parallel factor analysis (PARAFAC). Results indicated that land-use types may significantly affect the chemical composition of soil WEOM, including its aromaticity, molecular weight, and degree of humification. The PARAFAC analysis demonstrated that the soils and stream water were dominated by terrestrial/allochthonous humic-like substances and microbial transformable humic-like fluorophores. Shifts in the fluorescence properties of stream DOM suggested a pronounced change in the relative proportion of allochthonous versus autochthonous material under different rainfall patterns and land uses. For example, high proportions of forestland could provide more allochthonous DOM input. This study highlights the relevance of soils and hydrological dynamics on the composition and fluxes of DOM issuing from watersheds. The composition of DOM in soils was influenced by land-use type. Precipitation patterns influenced the proportion of terrestrial versus microbial origins of DOM in surface runoff. Contributions of allochthonous, terrestrially derived DOM inputs were highest from forested landscapes.     

移动测量系统宽幅影像的几何拼接与量测

研究了移动测量系统宽幅影像的拼接与量测算法。通过建立三幅影像柱面全景投影的几何关系,能够直接拼接完成宽幅影像。利用宽幅影像和原始影像间反投影变换关系以及三幅原始影像的同、异步立体像对,可建立宽幅影像与物方空间坐标间一一对应关系,从而实现宽幅影像目标的量测算法。宽幅影像的投影拼接和量测实验表明,利用柱面全景投影拼接得到宽幅影像的方法可应用于移动测量平台宽幅影像序列的拼接;在原始影像具备同步立体像对的条件下,宽幅影像量测的绝对精度可达1 m以内,相对精度可达0.2 m以内,满足城市环境实景目标量测的精度需求。     

自适应高程分级的城区DSM晕渲方法

在对传统的分层设色晕渲理论应用于城区DSM的可视化技术进行充分研究的基础上,提出了一种基于高程直方图的自适应高程分级方法。该方法通过高程直方图研究城区地形、地物的高程分布及变化特征,自适应建立高程带分级模型。实验表明,提出的晕渲图制作方法兼顾了地貌形态和地物特征的表达,成果色彩过渡自然,层次清晰,地形、地物区分明显,有较强的艺术性和实用价值。     

Thermal equation of state of natural tourmaline at high pressure and temperature

Synchrotron-based in situ angle-dispersive X-ray diffraction experiments were conducted on a natural uvite-dominated tourmaline sample by using an external-heating diamond anvil cell at simultaneously high pressures and temperatures up to 18 GPa and 723 K, respectively. The angle-dispersive X-ray diffraction data reveal no indication of a structural phase transition over the P–T range of the current experiment in this study. The pressure–volume–temperature data were fitted by the high-temperature Birch–Murnaghan equation of state. Isothermal bulk modulus of K ₀ = 96.6 (9) GPa, pressure derivative of the bulk modulus of \(K_{0}^{\prime } = 12.5 \;(4)\), thermal expansion coefficient of α ₀ = 4.39 (27) × 10^?5 K^?1 and temperature derivative of the bulk modulus (?K/?T) _P  = ?0.009 (6) GPa K^?1 were obtained. The axial thermoelastic properties were also obtained with K _a0 = 139 (2) GPa, \(K_{a0}^{\prime }\) = 11.5 (7) and α _a0 = 1.00 (11) × 10^?5 K^?1 for the a-axis, and K _c0 = 59 (1) GPa, \(K_{c0}^{\prime }\) = 11.4 (5) and α _c0 = 2.41 (24) × 10^?5 K^?1 for the c-axis. Both of axial compression and thermal expansion exhibit large anisotropic behavior. Thermoelastic parameters of tourmaline in this study were also compared with that of the other two ring silicates of beryl and cordierite.     

天山南麓雷暴日短期预报研究

利用阿克苏及邻近地区12个气象站1980—2013年雷暴资料,以及同期高空资料,统计了各站年均雷暴日数,对发生区域雷暴天气的环流形势进行分类,归纳出各型的入型指标。通过逐步回归法,建立阿克苏及邻近地区区域雷暴概率回归预报模型,并对2013年进行试预报。结果表明:(1)阿克苏及邻近地区区域雷暴的影响系统主要分为4类:巴湖低槽型、急流型、西北气流型和温度槽型。(2)对2002—2012年5—9月(共1683 d)历史资料进行判别,满足入型条件的样本数为876 d,消空率为48%;对2013年5—9月(共153 d)历史资料进行判别,入型样本数为80 d,消空率为48%。(3)对2002—2012年5—9月所有入型样本进行回代检验,平均准确率为72.0%(平均TS评分为30.1%);对2013年5—9月所有入型样本进行试预报,平均准确率为63.2%(平均TS评分为28.2%)。     

强度尺度分解方法在气候温度场检验中的应用

本文首次将Casati等提出的强度尺度分解方法应用到气候地表温度场的检验中,探讨此方法用于评估气候模拟场误差的详细空间信息的适用性。以新一代气候系统模式模拟的月平均地表温度为例,传统的统计分析方法（较为常用的是空间相关系数和均方根误差、EOF分析等）不能完全反映模拟场误差的空间信息;强度尺度分解方法可计算不同阈值和空间尺度上的均方误差和模拟技巧,评估对应的模拟能力,定量给出模拟场主要误差的空间信息（误差范围即温度阈值及对应的空间尺度）,例如,亚洲东部地区1月单年及多年平均的模拟场在230 K阈值1600 km模拟技巧非常低。本研究表明强度尺度分解方法适用于气候温度场的检验评估,能定量给出误差的空间信息。     

一种数字地图新产品--PDF地图

针对目前数字地图产品的使用现状和需求,提出了PDF地图产品。首先给出了PDF地图的定义与特征,其次详细描述了PDF地图的数据模型及生成方法,最后总结了PDF地图的两种基本应用模式,并验证了其可行性和有效性。