The effects of soil sand contents on characteristics of humic acids along soil profiles

It is generally accepted that the compositions and properties of soil organic matter (SOM) are influenced by many factors. In order to reveal the effects of soil texture on characteristics and dynamics of SOM and its sub-fraction, humic acid (HA), along two soil profiles, a yellow soil profile and a purplish soil profile, under the same climate and vegetation conditions were determined. Results indicate that the decomposition and humification degrees of SOM and HA of the purplish soils are higher than those of the corresponding yellow soils indicated by A/O–A ratios of HAs, TOCs and HA yields of bulk soil samples, nevertheless, the development degree of the purplish soil is lower than that of the yellow soil. The variations of E₄/E₆ ratios of HAs along the soil profiles indicate the overall molecular sizes of HAs decreased downward along the soil profiles. A/O–A ratios of HAs decreased downward along both the soil profiles indicate that humification processes decrease downward along both the soil profiles. Leaching of SOM shows significant effects on the distribution and characteristics of HAs in the yellow soil profile but the purplish soil profile, which is consistent with the higher hydrophobicity of HAs in purplish soils, shows that the distribution characteristics of SOM along the soil profiles are a complex result of the combination of soil texture and characteristics of SOM itself. The remarkably different sand contents are concluded tentatively as one of reasons to the different distributions and dynamics of HAs along the soil profiles, however, to profoundly understand the evolution and transport of SOM along soil profiles needs more researches.     

X2检验假设分布有效性的岩体工程应用

在工程地质问题中许多现象是不确定、且具有随机分布的特性，而这种随机分布特性往往可以采用某种形式的密度函数来描述。采用Ｘ２检验假设分布有效性是一个重要的方法，采用该法可以获得观测数据最佳拟合的概率模型，通过自编程序可以同时检验多种概率密度函数并选取最佳模型。本文将介绍这一方法，并通过一个实例加以说明。     

Garnet-bearing tonalitic porphyry from East Kunlun,Northeast Tibetan Plateau: implications for adakite and magmas from the MASH Zone

A garnet-bearing tonalitic porphyry from the Achiq Kol area, northeast Tibetan Plateau has been dated by SHRIMP U-Pb zircon techniques and gives a Late Triassic age of 213 ± 3 Ma. The porphyry contains phenocrysts of Ca-rich, Mn-poor garnet (CaO > 5 wt%; MnO < 3 wt%), Al-rich hornblende (Al₂O₃ ~ 15.9 wt%), plagioclase and quartz, and pressure estimates for hornblende enclosing the garnet phenocrysts yield values of 8–10 kbar, indicating a minimum pressure for the garnet. The rock has SiO₂ of 60–63 wt%, low MgO (<2.0 wt%), K₂O (<1.3 wt%), but high Al₂O₃ (>17 wt%) contents, and is metaluminous to slightly peraluminous (ACNK = 0.89–1.05). The rock samples are enriched in LILE and LREE but depleted in Nb and Ti, showing typical features of subduction-related magmas. The relatively high Sr/Y (~38) ratios and low HREE (Yb < 0.8 ppm) contents suggest that garnet is a residual phase, while suppressed crystallization of plagioclase and lack of negative Eu anomalies indicate a high water fugacity in the magma. Nd–Sr isotope compositions of the rock (εNd_T = −1.38 to −2.33; ⁸⁷Sr/⁸⁶Sr_i = 0.7065–0.7067) suggest that both mantle- and crust-derived materials were involved in the petrogenesis, which is consistent with the reverse compositional zoning of plagioclase, interpreted to indicate magma mixing. Both garnet phenocrysts and their ilmenite inclusions contain low MgO contents which, in combination with the oxygen isotope composition of garnet separates (+6.23‰), suggests that these minerals formed in a lower crust-derived felsic melt probably in the MASH zone. Although the rock samples are similar to adakitic rocks in many aspects, their moderate Sr contents (<260 ppm) and La/Yb ratios (mostly 16–21) are significantly lower than those of adakitic rocks. Because of high partition coefficients for Sr and LREE, fractionation of apatite at an early stage in the evolution of the magma may have effectively decreased both Sr and LREE in the residual melt. It is suggested that extensive crystallization of apatite as an early phase may prevent some arc magmas from evolving into adakitic rocks even under high water fugacity.     

秦岭若干重要类型金矿床成矿地质条件研究新进展

通过秦岭金矿区域成矿地质条件研究取得的进展 :八卦庙矿区发育有条带状的热水沉积岩 ,金矿床类型属于热水沉积韧性剪切带改造型 ,矿化类型为细脉浸染型 ;马鞍桥金矿的成矿大地构造环境属于华北板块南缘 ,含矿岩系为早古生代的深水斜坡浊积岩相 ,矿区的“浅色岩相”系变质成因 ;煎茶岭金矿属构造蚀变岩型金矿 ,而非超基性岩浆热液型金矿。以上研究为秦岭地区金矿找矿指出了新方向和新类型     

松辽盆地北部泉三、四段储层物性影响因素分析

发育于泉头组三、四段的扶余油层和杨大城子油层是松辽盆地的主力油层之一,该油层低孔特低渗的物性特征制约了扶杨油层的勘探开发.为了研究松辽盆地北部泉三、四段储层物性的影响因素和低渗透储层的成因,本文以12 062组实测孔隙度和渗透率数据为基础,讨论了泉三、四段的物性影响因素.结果表明,总体上影响泉三、四段储层物性的主要因素...     

陕西凤太地区唐藏—黄柏塬构造带内各时代火山岩对比研究

唐藏一黄柏塬构造带是商丹结合带的向西延伸,有两套不同时代火山岩系相依分布,其中新元古代丹凤岩群火山岩系主要为玄武岩—安山岩—流纹岩,早古生代罗汉寺岩群火山岩系为苦橄岩—安山玄武岩—安山岩—流效岩,通过岩石常量元素和稀土、微量元素地球化学特征研究,证明丹凤岩群火山岩系形成千岛弧构造环境,罗汉寺岩群火山岩系形成于陆壳增厚的活动陆线构造环境。     

Ree geochemistry characteristics of stratigraphic samples in the abalieke region,Western Kunlun北大核心

The Abalieke region locats in the central section of the western Kunlun polymetallic (Pb, Zn, Cu, etc) ore belt, an area with major potential for further base metal deposit discoveries. This paper reports REE data for 82 samples from 8 stratigraphic sections for Huoshilafu formation in the Abalieke region. To attempt to solve the origin of ore-forming materials using REE geochemistry. Although total REE contents are quite variable ( Σ REE = 7. 52 × 10-6-220. 70 × 10-6, ΣLREE = 5. 82 × 10-6-198. 46 × 10-6, ΣHREE = 1. 49 × 10-6- 32. 74 × 10-6 and Y = 4. 77 × 10-6-91. 30 × 10-6) , chondrite-normalized REE patterns of the majority of samples are uniformly LREE-enriched (averaging ΣLREE/ΣHREE = 6. 57), with remarkably fractionation of LREE and HREE [averaging (La/Yb)N = 8. 20], slightly negative Eu anomalies (averaging δEu = 0. 77) and insignificant Ce anomalies (averaging δCe = 0. 88). The results demonstrate that REE characteristics of stratigraphic samples from Abalieke region are similar to those of rock and ore samples from other representative deposits (Tiekelike, Tamu, Kalangu, Tuokuziate) in the western Kunlun polymetallic ore belt, which indicate a close genetic relationship between the ore-forming materials and the host strata for the majority of deposits in this belt.     

Geochemistry and tectonic environment of amphiholites of the Zanhuang metamorphic complex北大核心

Amphibolites, one of the kinds of Precambrian basement rocks, are exposed in the south-middle Zanhuang Metamorphic Complex, central-south segment of the Trans-North China Orogen. These metamorphic rocks were carefully studied through field investigations and petrographical and geochemical analyses. It was found that protoliths of the Zanhuang amphibolites are calc-alkaline and tholeiitic rocks with a large range of ΣREE (41.38 × 10-6 -232.55 × 10-5 ) and weak LREE enrichment. The multi-element variation results showed that K, Rb and Ba were relatively concentrated, Nb and Ta were of evident depletion while Ti was of weak depletion. Geochemical characteristics and various relevant geochemical discrimination diagrams showed that the Zanhuang amphibolites were formed in volcanic arcs of continental margin similar to the current continental margin, which was resulted from the subduction between the Western Block and the Eastern Block.