Cs and Cl NMR spectroscopy and molecular dynamics modeling of Cs and Cl complexation with natural organic matter

Interaction of dissolved aqueous species with natural organic matter (NOM) is thought to be important in sequestering some species and enhancing the transport of others, but little is known about these interactions on a molecular scale. This paper describes a combined experimental ¹³³Cs and ³⁵Cl nuclear magnetic resonance (NMR) and computational molecular dynamics (MD) modeling study of the interaction of Cs⁺ and Cl⁻ with Suwannee River NOM. The results provide a detailed picture of the molecular-scale structure and dynamics of these interactions. Individual NOM molecules are typically hundreds to thousands of Daltons in weight, and on the molecular scale their interaction with small dissolved species can be investigated in ways similar to those used to study the interaction of dissolved aqueous species with mineral surfaces. As for such surface interactions, understanding both the structural environments and the dynamics over a wide range of frequencies is essential. The NMR results show that Cs⁺ is associated with NOM at pH values from 3.4 ± 0.5 (unbuffered Suwannee River NOM solution) to 9.0 ± 0.5. The extent of interaction increases with decreasing CsCl concentration at constant pH. It also decreases with increasing pH at constant CsCl concentration due to pH-dependent negative structural charge development on the NOM caused by progressive deprotonation of carboxylic and phenolic groups. The presence of NOM has little effect on the ¹³³Cs chemical shifts, demonstrating that its local coordination environment does not change significantly due to interaction with the NOM. Narrow, solution-like line widths indicate rapid exchange of Cs⁺ between the NOM and bulk solution at frequencies of >10² Hz. The MD simulations support these results and show that Cs⁺ is associated with the NOM principally as outer sphere complexes and that this interaction does not reduce the Cs⁺ diffusion coefficient sufficiently to cause NMR line broadening. The ³⁵Cl NMR data and the MD results are consistent in demonstrating that there is no significant complexation between Cl⁻ and NOM in the pH range investigated, consistent with negative structural charge on the NOM.     

四川林农复合经营持续发展对策探讨

分析了四川林农复合经营的主要类型、效益与障碍，并探讨了其持续发展的原则、有利条件与对策．     

舟山港台风风暴潮的分析及预报

利用 1 956～ 2 0 0 0年舟山市定海验潮站潮位观测资料 ,对历年影响舟山的台风风暴潮灾进行了全面的统计分析。将台风按路径分型 ,分析了不同路径台风风暴潮的特点 ,并用基于PRESS准则的逐步回归方法 ,建立了不同路径风暴潮的预报模型。     

西北地区水资源环境与城市化系统耦合的时空分异——以西陇海兰新经济带甘肃段为例

水资源是城市化与生态环境协调发展的重要限制因子,研究西北地区水资源环境与城市化系统耦合的时空分异规律,对于区域水资源、生态环境和社会经济系统可持续发展具有重要的现实意义。采用GRA方法,以西陇海兰新经济带甘肃段为例,从时空角度定量揭示了甘肃段水资源环境与城市化系统耦合的时空分异规律,结果表明:(1)时间序列上整体呈波动下降趋势,表现为类似组合"S"型特征;空间上随人口城市化水平的提高,耦合度亦表现出与时间序列类似特征;时空耦合度相互印证,说明系统符合"各态遍历假说;"(2)不同阶段甘肃段各城市耦合度表现出较大差异,具有复杂的空间结构:以兰州市为中心向外耦合度"先升高后减小",表明水资源环境与城市化系统耦合度的高低不仅取决于城市自身发展等内部因素,而且与城市之间的区域差异、区域联系等外部因素有关。基于以上认知,在解决区域水资源环境与城市化关系问题时,除有效提高城市水资源环境适应及调控能力之外,还要协调好区域之间的关系,构建区域利益共同体以达到"双赢"的目的,这为落后地区解决发展中的资源环境问题提供了新的思路。     

淮北地区一次强风暴的弓形回波分析

2005年7月16日淮北地区发生了一次强风暴天气过程。主要使用新建成的阜阳CINRAD-SA多普勒天气雷达观测资料,辅以天气图、本站高空观测、地面观测资料,对此过程进行了综合分析。结果表明：这是一次以灾害性大风为主、有雨暴相伴随、局部还有冰雹发生的强对流天气过程。影响系统是一条中-β尺度的弓形飑线回波带。弓形回波带是由更早些时间出现的弧形的阵风锋触发而成的。中层干冷空气的侵入加强了对流云体中的下沉气流和低层出流,形成阵风锋。在如何综合应用如此丰富的雷达产品做好临近预报方面作了初步的尝试。     

Climatic regime shift and decadal anomalous events in China

Climatic time series from historical documents and instrumental records from China showed temporal and regional patterns in the last two to three centuries, including two multidecadal oscillations at quasi-20-year and quasi-70-year timescales revealed by signal analysis from wavelet transform. Climatic anomalous events on the decadal timescale were identified based on the two oscillations when their positive (or negative) phases coincide with each other to amplify amplitude. The coldest event occurred in the decade of 1965–1975 in eastern China, while the periods of 1920–1930, 1940–1950, and 1988–2000 appeared to be warmer in most parts of China. For the precipitation series in northern China, the dry anomalous event was found in the late 1920s, while the wet anomalous event occurred in the 1950s. A severe drought in 1927–1929 in northern China coincided with the anomalous warm and dry decade, caused large-scale famine in nine provinces over northern China. Climatic anomalous events with a warm-dry or cold-wet association in the physical climate system would potentially cause severe negative impacts on natural ecosystem in the key vulnerable region over northern China. The spatial pattern of summer rainfall anomalies in the eastern China monsoon region showed an opposite variations in phase between the Yellow River Valley (North China) and the mid-low Yangtze River Valley as well as accompanied the shift of the northernmost monsoon boundary. Climatic regime shifts for different time points in the last 200 years were identified. In North China, transitions from dry to wet periods occurred around 1800, 1875, and 1940 while the transitions from wet to dry periods appeared around 1840, 1910, and the late 1970s. The reversal transition in these time points can also be found in the lower Yangtze River. Climatic regime shifts in China were linked to the interaction of mid- and low latitude atmospheric circulations (the westerly flow and the monsoon flow) when they cross the Tibetan Plateau in East Asia.     

大海马游泳行为及游泳能力测定与分析

利用自制的鱼类游泳能力测定装置,观察了大海马垂直和水平方向的最大临界游速,描述了大海马的游泳行为,并评估其游泳能力。结果表明:水温25.5℃±1.0℃条件下,体长6 cm个体水平方向的临界游速达到峰值为4.23 cm/s±0.23 cm/s;随体长的增加和减少,临界游速都有所下降,体长至约10 cm时临界游速为2.86 cm/s±0.02 cm/s。该物种在水平游泳时,游泳速度与尾部的倾斜角度有关,倾角越大,速度越大,当倾角达到55°时,速度达到最大值,而大于该角度,身体就失去平衡不能进行逆水流游动。大海马体长在6 cm时达到垂直方向的临界游速峰值,为0.372 cm/s±0.014 cm/s,此时的绝对临界速度为0.085 BL/s±0.010 BL/s。至体长增长到13 cm时,基本趋于稳定,与水平方向游速变化趋势相似。     

新时代地热行业发展特点及几点思考

当前,中国特色社会主义进入了新时代,社会各项建设取得重大成就,地热产业也发展壮大。在大力倡导生态文明建设、推进绿色发展、提升环境保护、推进资源的节约和循环利用的社会发展形势下,一些重要规划和政策的实施、一批重点区域和重大项目的建设、大量地热能开发利用新技术的推广,又给地热产业带来了新的发展契机。不同形式、不同利用方式的地热能都将迎来更广阔的市场、更高的产业增长态势。为顺应新时代行业发展,地热产业应抓住机遇,迎接挑战,创新突破,成就未来。本文将从上位决策、项目建设、技术创新、管理等方面,分析当下地热行业发展的形势、特点和存在的问题,提出相关建议,以共同探讨,相互借鉴。