Greenland surface mass balance simulated by a regional climate model and comparison with satellite-derived data in 1990–1991

The 1990 and 1991 ablation seasons over Greenland are simulated with a coupled atmosphere-snow regional climate model with a 25-km horizontal resolution. The simulated snow water content allows a direct comparison with the satellite-derived melt signal. The model is forced with 6-hourly ERA-40 reanalysis at its boundaries. An evaluation of the simulated precipitation and a comparison of the modelled melt zone and the surface albedo with remote sensing observations are presented. Both the distribution and quantity of the simulated precipitation agree with observations from coastal weather stations, estimates from other models and the ERA-40 reanalysis. There are overestimations along the steep eastern coast, which are most likely due to the “topographic barrier effect”. The simulated extent and time evolution of the wet snow zone compare generally well with satellite-derived data, except during rainfall events on the ice sheet and because of a bias in the passive microwave retrieved melt signal. Although satellite-based surface albedo retrieval is only valid in the case of clear sky, the interpolation and the correction of these data enable us to validate the simulated albedo on the scale of the whole Greenland. These two comparisons highlight a large sensitivity of the remote sensing observations to weather conditions. Our high-resolution climate model was used to improve the retrieval algorithms by taking more fully into account the atmosphere variability. Finally, the good agreement of the simulated melting surface with the improved satellite signal allows a detailed estimation of the melting volume from the simulation.     

Age constraints on felsic intrusions, metamorphism and gold mineralisation in the Palaeoproterozoic Rio Itapicuru greenstone belt, NE Bahia State, Brazil

U–Pb sensitive high resolution ion microprobe mass spectrometer (SHRIMP) ages of zircon, monazite and xenotime crystals from felsic intrusive rocks from the Rio Itapicuru greenstone belt show two development stages between 2,152 and 2,130 Ma, and between 2,130 and 2,080 Ma. The older intrusions yielded ages of 2,152±6 Ma in monazite crystals and 2,155±9 Ma in zircon crystals derived from the Trilhado granodiorite, and ages of 2,130±7 Ma and 2,128±8 Ma in zircon crystals derived from the Teofilândia tonalite. The emplacement age of the syntectonic Ambrósio dome as indicated by a 2,080±2-Ma xenotime age for a granite dyke probably marks the end of the felsic magmatism. This age shows good agreement with the Ar–Ar plateau age of 2,080±5 Ma obtained in hornblendes from an amphibolite and with a U–Pb SHRIMP age of 2,076±10 Ma in detrital zircon crystals from a quartzite, interpreted as the age of the peak of the metamorphism. The predominance of inherited zircons in the syntectonic Ambrósio dome suggests that the basement of the supracrustal rocks was composed of Archaean continental crust with components of 2,937±16, 3,111±13 and 3,162±13 Ma. Ar–Ar plateau ages of 2,050±4 Ma and 2,054±2 Ma on hydrothermal muscovite samples from the Fazenda Brasileiro gold deposit are interpreted as minimum ages for gold mineralisation and close to the true age of gold deposition. The Ar–Ar data indicate that the mineralisation must have occurred less than 30 million years after the peak of the metamorphism, or episodically between 2,080 Ma and 2,050 Ma, during uplift and exhumation of the orogen.Electronic supplementary material Supplementary material is available for this article at     

Contributions respectives des courants et de la houle dans la mobilité sédimentaire d'une plate-forme interne estuarienne. Exemple : le seuil interinsulaire,au large du pertuis d'Antioche,France

This paper investigates the relative influence of waves, wind-induced current and tidal current on the sediment mobility of a macro-tidal environment belonging to the inner shelf seaward of the ‘pertuis Charentais’ (France). This study, mainly based on three-week hydrodynamic in-situ measurements, shows that, for a water depth of 23 m, the swell (rather than wind waves) orbital velocity is large enough to initiate the motion of medium sands that are then transported by currents. Estimations show that medium sand of 0.2 mm is transported during 92% of the measurements, whereas coarse sand and gravel move sporadically, during storm, synchronously with spring tides. Further more, bedload fluxes appear strongly larger when waves are taken into account (370 times larger for 0.2-mm sands). To cite this article: D. Idier et al., C. R. Geoscience 338 (2006).     

Effective dispersion in a chemically heterogeneous medium under temporally fluctuating flow conditions

We investigate effective solute transport in a chemically heterogeneous medium subject to temporal fluctuations of the flow conditions. Focusing on spatial variations in the equilibrium adsorption properties, the corresponding fluctuating retardation factor is modeled as a stationary random space function. The temporal variability of the flow is represented by a stationary temporal random process. Solute spreading is quantified by effective dispersion coefficients, which are derived from the ensemble average of the second centered moments of the normalized solute distribution in a single disorder realization. Using first-order expansions in the variances of the respective random fields, we derive explicit compact expressions for the time behavior of the disorder induced contributions to the effective dispersion coefficients. Focusing on the contributions due to chemical heterogeneity and temporal fluctuations, we find enhanced transverse spreading characterized by a transverse effective dispersion coefficient that, in contrast to transport in steady flow fields, evolves to a disorder-induced macroscopic value (i.e., independent of local dispersion). At the same time, the asymptotic longitudinal dispersion coefficient can decrease. Under certain conditions the contribution to the longitudinal effective dispersion coefficient shows superdiffusive behavior, similar to that observed for transport in s stratified porous medium, before it decreases to its asymptotic value. The presented compact and easy to use expressions for the longitudinal and transverse effective dispersion coefficients can be used for the quantification of effective spreading and mixing in the context of the groundwater remediation based on hydraulic manipulation and for the effective modeling of reactive transport in heterogeneous media in general.     

Limited Consequences of Seagrass Decline on Benthic Macrofauna and Associated Biotic Indicators

Marine phanerogams are ecosystem engineers, as their presence induces major environmental changes that impact on the benthic fauna. Consequently, modifications to the structure of benthic communities would be expected to be associated with seagrass decline. Since 2005, Zostera noltii seagrass beds in Arcachon Bay (France), the largest in Europe, have undergone a severe decline. Twelve stations distributed throughout the lagoon were sampled in 2002, and all were found to be densely planted at that time. Subsequently, the same stations were revisited in 2010 and seagrass cover had drastically decreased by that time. Based on benthic macrofauna, multidimensional scaling (MDS) analysis identified four groups. Years were separated. In 2002, two groups were distinct in relation to the water body, since in 2010 separation between the two other groups was related to seagrass occurrence. When looking at community structure and dominant species there were moderate differences within and between years, independent of seagrass decline. Seagrass loss did not drastically modify the species composition as they were preserved in the remaining seagrass patches. However, there was a drop in macrofauna abundance in unvegetated muddy compared with abundance in the remaining seagrass areas. Epifauna was particularly affected by seagrass decline. Among biotic indicators based on macrofauna, multivariate indicator MISS (Macrobenthic Index in Sheltered Systems) was in agreement with the similarity of macrofauna structure among groups, while other tested indicators performed badly in relation to seagrass occurrence. However, no index detected seagrass loss, highlighting the necessity of maintaining a separate survey on seagrass cover.     

Aqueous–solid solution thermodynamic model of U(VI) uptake in C–S–H phases

Reliable thermodynamic models assessing the interaction of radionuclides with cementitious materials are important in connection with long-term predictions of the safe disposal of radioactive waste in cement-based repositories. In this study, a geochemical model of U(VI) interaction with calcium silicate hydrates (C–S–H phases), the main component of hardened cement paste (HCP), has been developed. Uranium(VI) sorption isotherms on C–S–H phases of different Ca:Si ratios (C:S) and structural data from spectroscopic studies provided the indispensable set of experimental data required for the model development. This information suggested that U(VI) is neither adsorbed nor incorporated in the Ca–O octahedral layers of the C–S–H structure, but rather is located in the interlayer, similar to Ca²⁺ and other cations. With a view to the high recrystallisation rates and the cryptocrystalline ‘gel-like’ structure of the C–S–H phases, these observations indicated a U(VI) uptake driven by the formation of a solid solution.     

Iron Distribution in Size‐Resolved Aerosols Generated by UV‐Femtosecond Laser Ablation: Influence of Cell Geometry and Implications for In Situ Isotopic Determination by LA‐MC‐ICP‐MS

The influence of ablation cell geometry (Frames single‐ and HelEx two‐volume cells) and laser wavelength (198 and 266 nm) on aerosols produced by femtosecond laser ablation (fs‐LA) were evaluated. Morphologies, iron mass distribution (IMD) and ⁵⁶Fe/⁵⁴Fe ratios of particles generated from magnetite, pyrite, haematite and siderite were studied. The following two morphologies were identified: spherules (10–200 nm) and agglomerates (5–10 nm). Similarity in IMD and ablation rate at 198 and 266 nm indicates similar ablation mechanisms. ⁵⁶Fe/⁵⁴Fe ratios increased with aerodynamic particle size as a result of kinetic fractionation during laser plasma plume expansion, cooling and aerosol condensation. The HelEx cell produces smaller particles with a larger range of ⁵⁶Fe/⁵⁴Fe ratios (1.85‰) than particles from the Frames cell (1.16‰), but the bulk aerosol matches the bulk substrate for both cells, demonstrating stoichiometric fs‐LA sampling. IMD differences are the result of faster wash out of the HelEx cell allowing less time for agglomeration of small, low‐δ ⁵⁶Fe particles with larger, high‐δ ⁵⁶Fe particles in the cell. Even with a shorter ablation time, half the total Fe ion intensity, and half the ablation volume, the HelEx cell produced Fe isotope determinations for magnetite that were as precise as the Frames cell, even when the latter included an aerosol‐homogenising mixing chamber. The HelEx cell delivered a more constant stream of small particles to the ICP, producing a more stable Fe ion signal (0.7% vs. 1.5% RSE for ⁵⁶Fe in a forty‐cycle single analysis), constant instrumental mass bias and thus a more precise measurement.     

Simulation of the lately injected dykes in an Iranian porphyry copper deposit using the plurigaussian model

Ore deposits are usually composed of rock units or facies with different grade distributions and complex spatial structures. Being able to simulate the spatial layout of these facies are essential to have a comprehensive mining plan and an accurate resources and reserves evaluation. Modelers are faced with a set of challenges when creating the facies model such as: reproducing the facies proportions and spatial continuity as well as the topological contacts between facies, capturing post depositional overprinting, and honoring the data obtained from drill holes. Plurigaussian simulation (PGS) is a geostatistical approach that allows covering these challenges. This study addresses the application of PGS to Sungun porphyry copper deposit (Iran), in order to simulate the layout of three facies: mineralized porphyry and skarn and non-mineralized dykes. The aim of this study is to construct numerical models in which the dyke structures reflect the evolution observed in the geology.     

Characterization and provenance of the slabs of the Puigseslloses Megalith,Barcelona, Spain

The Puigseslloses megalith tomb (Barcelona, Spain) is located on the summit of a hill in the Vic Plain where the sedimentary rocks that were used in its construction do not crop out. A sedimentological and petrological characterization of the monument's slabs and a multidisciplinary analysis of the outcropping materials in nearby areas has allowed the identification of three possible source areas associated with the Paleogene Banyoles Marls Formation and the Folgueroles Sandstone Formation and allows us to propose possible routes by which the slabs were transported from the catchment site to the place where the monument was built. In addition, the lithology and position of different slabs within the megalith denote the intention to separate the chamber from the corridor by using different types of slab. The position of the monument also reveals that tomb location was more of a priority than proximity to the slab sources. © 2010 Wiley Periodicals, Inc.     

Co-simulating Total and Soluble Copper Grades in an Oxide Ore Deposit

In oxide copper deposits, the acid soluble copper represents the fraction of total copper recoverable by heap leaching. Two difficulties often complicate the joint modeling and simulation of total and soluble copper grades: the inequality constraint linking both grade variables and the sampling design for soluble copper grade, which may be preferential and cause biases in sample statistics. A methodology is presented in order to accurately estimate the total and soluble copper grade bivariate distribution, based on an explicit modeling of the conditional distributions of soluble copper grade. Co-simulation is then realized by converting the copper grades into Gaussian random fields, through stepwise conditional transformation, and by fitting a coregionalization model while accounting for the preferential sampling design. The proposed approach is illustrated through an application to an ore deposit located in northern Chile.