The single-cell transport problem for two-phase flow with polymer

Polymer injection is a widespread strategy in enhanced oil recovery. Polymer increases the water viscosity and creates a more favorable mobility ratio between the injected water and the displaced oil. The computational cost of simulating polymer injection can be significantly reduced if one splits the governing system of two-phase equations into a pressure equation and a set of saturation/component equations and use a Gauss–Seidel algorithm with optimal cell ordering to solve the nonlinear systems arising from an implicit discretization of the saturation/component equations. This approach relies on a robust single-cell solver that computes the saturation and polymer concentration of a cell, given the total flux and the saturation and polymer concentration of the neighboring cells. In this paper, we consider a relatively comprehensive polymer model used in an industry-standard simulator, and show that, in the case of a discretization using a two-point flux approximation, the single-cell problem always admits a solution that is also unique.     

Sedimentological and palaeohydrological characterization of Late Pleistocene and Holocene tufa mound palaeolakes using trenching methods in the Spanish Pyrenees

Lakes developed in the inner depressions of tufa mounds are rare geomorphic features and still poorly understood. Sedimentation in this unusual type of endorheic lake with a very restricted catchment area is highly sensitive to environmental and hydrological changes. The Isona tufa mound complex, north‐eastern Iberian Peninsula, is associated with the discharge zone of a confined artesian aquifer and comprises 11 tufa mounds consisting of an annular rimstone enclosing a central depression filled with lake deposits. Data gathered from trenches excavated in four palaeolakes located within three different morphostratigraphic units permitted a precise analysis of the geometrical characteristics and stratigraphic relationships of the deposits and provided a sedimentation model for the Late Quaternary infilling of the spring‐fed lakes. The work illustrates that trenches allow a precise characterization of the stratigraphic arrangements, lateral facies changes and deformation structures, which are not apparent in studies relying solely on borehole records, and facilitate sampling for dating and geochemical analyses. The five sedimentary facies described represent different evolutionary stages of the lakes, including: (i) carbonate‐rich palustrine deposits probably related to periods with strong hydrological seasonality; (ii) massive highly bioturbated organic ooze; (iii) banded organic carbonate‐rich facies associated with an increase in the regional effective moisture; (iv) fine‐grained quartz‐rich aeolian/slope‐wash sediments; and (v) colluvial facies deposited following the desiccation of the lakes located at higher altitudes. Geochemical and sedimentological analyses of the lacustrine sequences provided information on the palaeohydrological evolution of the Isona tufa mound complex and the palaeoenvironmental conditions of the area over the last 28 ka. Radiometric dating suggests that deposition occurred simultaneously at ca 22 ka in palaeolakes situated at different elevations. A drop in the piezometric level prompted by the opening of springs at lower altitudes probably caused the deactivation of the upper springs and the desiccation of the lakes. Arid conditions prevailed in the area during the Late Glacial and the early Holocene (28·0 to 8·5 ka bp ). More humid conditions recorded from 8·5 to 4·2 ka and again since 1·7 ka are in accordance with palaeoenvironmental reconstructions available in the Western Mediterranean since the Last Glacial Maximum.     

Nitrogen compound emission from biomass burning in tropical African savanna FOS/DECAFE 1991 experiment (Lamto,Ivory Coast)

Gaseous nitrogen compounds (NO _x , NO _y , NH₃, N₂O) were measured at ground level in smoke plumes of prescribed savanna fires in Lamto, in the southern Ivory Coast, during the FOS/DECAFE experiment in January 1991. During the flaming phase, the linear regression between [NO _x ] and [CO₂] (differences in concentration between smoke plumes and atmosheric background) results volumic emission ratio [NO _x ]/[CO₂]=1.37×10^–3 with only slight differences between heading and backing fires. Nearly 90% of the nitrogen oxides are emitted as NO. Average emission ratios of other compounds are: 1.91, 0.047, and 0.145×10^–3 for NO _y , NH₃ and N₂O, respectively. The emission ratios obtained during this field experiment are compred with corresponding values measured during former experiments with the same plant species in combustion chambers. An accurate determination of both the biomass actually burned and of the plant nitrogen content, allows an assessment of emission fluxes of N-compounds from Guinean savanna burns. Preliminary results dealing with the influence of fire on biogenic emissions from soils are also reported.     

Substitution Random Fields with Gaussian and Gamma Distributions: Theory and Application to a Pollution Data Set

This paper presents random field models with Gaussian or gamma univariate distributions and isofactorial bivariate distributions, constructed by composing two independent random fields: a directing function with stationary Gaussian increments and a stationary coding process with bivariate Gaussian or gamma distributions. Two variations are proposed, by considering a multivariate directing function and a coding process with a separable covariance, or by including drift components in the directing function. Iterative algorithms based on the Gibbs sampler allow one to condition the realizations of the substitution random fields to a set of data, while the inference of the model parameters relies on simple tools such as indicator variograms and variograms of different orders. A case study in polluted soil management is presented, for which a gamma model is used to quantify the risk that pollutant concentrations over remediation units exceed a given toxicity level. Unlike the multivariate Gaussian model, the proposed gamma model accounts for an asymmetry in the spatial correlation of the indicator functions around the median and for a spatial clustering of high pollutant concentrations.     

Kaolinitic meniscus bridges as an indicator of early diagenesis in Nubian sandstones, Sinai, Egypt

Characteristic meniscus geometries formed by kaolinitic infiltration are observed in Nubian sandstones collected on the western coast of the Sinai Peninsula (Egypt). Based on petrographic and scanning electron microscope (SEM) observations, the kaolinite forming the menisci consists of mixed-size discrete platelets that gather into the corners around the framework grain-to-grain contacts. Specifically, the internal fabric of menisci indicates a general organizing trend from (1) the centre, where the platelets coat the framework grains; (2) to the peripheral zone, where they are oriented tangentially to grain surfaces; (3) to the pore linings with curvatures that are consistent with theoretical considerations of air–water interfaces. This typical arrangement suggests a detrital origin of kaolinite platelets by mechanical infiltration into sediments lying above the tablewater, in vadose conditions. This type of clay cementation occurring during early diagenesis can prevent (delay) deep burial diagenetic processes and therefore preserve excellent reservoir properties.     

New Insights in Shallow Gas Generation from Very High Resolution Seismic and Bathymetric Surveys in the Marennes-Oléron Bay, France

Very high resolution seismic profiles, ground-truthed by vibrocores, have revealed the occurrence of kilometre-scale acoustic turbidity in the Marennes-Oléron Bay, France. Such acoustic turbidity is commonly interpreted as gas-charged sediments. Comparison between accurate historical bathymetric data and the present day bathymetry has shown high sediment accretion zones in the study area (locally up to 8 m since 1824). The superimposition of seismic and bathymetric datasets displays a striking correlation between the high sedimentation rate area and the boundaries of the acoustic turbidity, i.e. gas-charged sediments. The key role of sedimentation rates in shallow gas generation in the study area is pointed out. It is also concluded that shallow gas is probably generated at short (decadal to secular) time scales.     

Free allocation rules in the EU emissions trading system: what does the empirical literature show?

This paper analyses the rules for free allocation in the EU Emissions Trading System (EU ETS). The analysis draws on the empirical evidence emerging from two literature strands. One group of studies sheds light on the following questions: how efficient are free allocation rules in minimizing the risk of carbon leakage? Have they become more efficient over the trading periods? What are the technical limits to making them more efficient? Further: is firm behaviour affected by allowance allocation? Did specific provisions induce strategic behaviour with unintended effects? Studies from the second group estimate sectoral pass-through rates for the costs imposed by the EU ETS. Taking cost pass-through into account is necessary for properly targeting free allocation. The difficulty of accurately quantifying sectoral differences in cost pass-through ability, especially in manufacturing sectors (due to limited data availability and market heterogeneity), is the main hindrance to achieving further efficiency in allowance allocation. The new rules defined in the reform for Phase IV (2021–2030) nevertheless make some progress in this direction.

Key policy insights

• The difficulty of accurately quantifying sectoral differences in cost pass-through ability is the main hindrance to efficient free allocation in minimizing carbon leakage risk.

• In Phase IV (2021–2030), carbon leakage risk will be assessed more accurately thanks to: a) carbon intensity and trade intensity considered together through a combined indicator; b) possible use of more disaggregated data, and c) possible consideration of complementary qualitative assessments of abatement potential, market characteristics and profit margins.

• It is expected that benchmarked allocation introduced in Phase III (2013–2020) has induced additional emission abatement, but there is still a lack of empirical evidence.

     

Landslide databases in the Geological Surveys of Europe

Landslides are one of the most widespread geohazards in Europe, producing significant social and economic impacts. Rapid population growth in urban areas throughout many countries in Europe and extreme climatic scenarios can considerably increase landslide risk in the near future. Variability exists between European countries in both the statutory treatment of landslide risk and the use of official assessment guidelines. This suggests that a European Landslides Directive that provides a common legal framework for dealing with landslides is necessary. With this long-term goal in mind, this work analyzes the landslide databases from the Geological Surveys of Europe focusing on their interoperability and completeness. The same landslide classification could be used for the 849,543 landslide records from the Geological Surveys, from which 36% are slides, 10% are falls, 20% are flows, 11% are complex slides, and 24% either remain unclassified or correspond to another typology. Most of them are mapped with the same symbol at a scale of 1:25,000 or greater, providing the necessary information to elaborate European-scale susceptibility maps for each landslide type. A landslide density map was produced for the available records from the Geological Surveys (LANDEN map) showing, for the first time, 210,544 km² landslide-prone areas and 23,681 administrative areas where the Geological Surveys from Europe have recorded landslides. The comparison of this map with the European landslide susceptibility map (ELSUS 1000 v1) is successful for most of the territory (69.7%) showing certain variability between countries. This comparison also permitted the identification of 0.98 Mkm² (28.9%) of landslide-susceptible areas without records from the Geological Surveys, which have been used to evaluate the landslide database completeness. The estimated completeness of the landslide databases (LDBs) from the Geological Surveys is 17%, varying between 1 and 55%. This variability is due to the different landslide strategies adopted by each country. In some of them, landslide mapping is systematic; others only record damaging landslides, whereas in others, landslide maps are only available for certain regions or local areas. Moreover, in most of the countries, LDBs from the Geological Surveys co-exist with others owned by a variety of public institutions producing LDBs at variable scales and formats. Hence, a greater coordination effort should be made by all the institutions working in landslide mapping to increase data integration and harmonization.