Wildfire effects on extractable elements in ash from a Pinus pinaster forest in Portugal

The aim of this work is to study the effects of a wildfire on water‐extractable elements in ash from a Pinus pinaster forest located in Portugal. The pH, electrical conductivity (EC), calcium (Ca²⁺), magnesium (Mg²⁺), sodium (Na⁺), potassium (K⁺), sodium and potassium adsorption ratio (SPAR), aluminium (Al³⁺), manganese (Mn²⁺), iron (Fe²⁺), zinc (Zn²⁺), sulphur (S), silica (Si) and phosphorous (P) were analysed in ash sampled from a sloped area burned in a wildfire and from litter from a contiguous unburned area, with similar morphological conditions. The results showed that ash leachates had higher pH and EC, and were significantly richer in water‐extractable Ca²⁺, Mg²⁺, Na⁺, K⁺, SPAR, S and Si and significantly poorer in water‐extractable Al³⁺, Fe²⁺, Mn²⁺ and Zn²⁺ than litter solutions. No significant differences were observed in water‐extractable P. The fire changed the ash solute chemistry compared with the unburned litter and increased the sample variability of nutrient distribution with potential implications for plant recovery. Copyright © 2013 John Wiley & Sons, Ltd.     

Future evolution of a tidal inlet due to changes in wave climate, Sea level and lagoon morphology (Óbidos lagoon, Portugal)

Tidal inlets are extremely dynamic, as a result of an often delicate balance between the effects of tides, waves and other forcings. Since the morphology of these inlets can affect navigation, water quality and ecosystem dynamics, there is a clear need to anticipate their evolution in order to promote adequate management decisions. Over decadal time scales, the position and size of tidal inlets are expected to evolve with the conditions that affect them, for instance as a result of climate change. A process-based morphodynamic modeling system is validated and used to analyze the effects of sea level rise, an expected shift in the wave direction and the reduction of the upper lagoon surface area by sedimentation on a small tidal inlet (Óbidos lagoon, Portugal). A new approach to define yearly wave regimes is first developed, which includes a seasonal behavior, random inter-annual variability and the possibility to extrapolate trends. Once validated, this approach is used to produce yearly time series of wave spectra for the present and for the end of the 21st century, considering the local rotation trends computed using hindcast results for the past 57 years. Predictions of the mean sea level for 2100 are based on previous studies, while the bathymetry of the upper lagoon for the same year is obtained by extrapolation of past trends. Results show, and data confirm, that the Óbidos lagoon inlet has three stable configurations, largely determined by the inter-annual variations in the wave characteristics. Both sea level rise and the reduction of the lagoon surface area will promote the accretion of the inlet. In contrast, the predicted rotation of the wave regime, within foreseeable limits, will have a negligible impact on the inlet morphology.     

High-resolution modelling of the Antarctic surface mass balance, application for the twentieth, twenty first and twenty second centuries

About 75 % of the Antarctic surface mass gain occurs over areas below 2,000 m asl, which cover 40 % of the grounded ice-sheet. As the topography is complex in many of these regions, surface mass balance modelling is highly dependent on horizontal resolution, and studying the impact of Antarctica on the future rise in sea level requires physical approaches. We have developed a computationally efficient, physical downscaling model for high-resolution (15 km) long-term surface mass balance (SMB) projections. Here, we present results of this model, called SMHiL (surface mass balance high-resolution downscaling), which was forced with the LMDZ4 atmospheric general circulation model to assess Antarctic SMB variability in the twenty first and the twenty second centuries under two different scenarios. The higher resolution of SMHiL better reproduces the geographical patterns of SMB and increase significantly the averaged SMB over the grounded ice-sheet for the end of the twentieth century. A comparison with more than 3200 quality-controlled field data shows that LMDZ4 and SMHiL reproduce the observed values equally well. Nevertheless, field data below 2,000 m asl are too scarce to efficiently show the added value of SMHiL and measuring the SMB in these undocumented areas should be a future scientific priority. Our results suggest that running LMDZ4 at a finer resolution (15 km) may give a future increase in SMB in Antarctica that is about 30 % higher than by using its standard resolution (60 km) due to the higher increase in precipitation in coastal areas at 15 km. However, a part (～15 %) of these discrepancies could be an artefact from SMHiL since it neglects the foehn effect and likely overestimates the precipitation increase. Future changes in the Antarctic SMB at low elevations will result from the competition between higher snow accumulation and runoff. For this reason, developing downscaling models is crucial to represent processes in sufficient detail and correctly model the SMB in coastal areas.     

Impact of Oyster Farming on Diagenetic Processes and the Phosphorus Cycle in Two Estuaries (Brittany,France)

This study aims to compare the impact of oyster cultures on diagenetic processes and the phosphorus cycle in the sediments of the Aber Benoît and the Rivière d’Auray, estuary of Brittany, France. Our results showed clear evidence of the seasonal impact of oyster cultures on sediment characteristics (grain size and organic matter parameters) and the phosphorus cycle, especially in the Aber Benoît. At this site, seasonal variations in sulfide and Fe concentrations in pore waters, as well as Fe–P concentrations in the solid phase, highlighted a shift from a system governed by iron reduction (Reference) to a system governed by sulfate reduction (beneath oyster). This could be partly explained by the increase in labile organic matter (i.e., biodeposits) beneath oysters, whose mineralization by sulfate led to high sulfide concentrations in pore waters (up to 4,475 µmol l^?1). In turn, sulfide caused an enhanced release of phosphate in the summer, as adsorption sites for phosphate decreased through the formation of iron–sulfide compounds (FeS and FeS₂). In the Aber Benoît, dissolved Fe/PO₄ ratios could be used as an indicator of phosphate release into oxic water. Low Fe/PO₄ ratios in the summer indicated higher effluxes of phosphate toward the water column (up to 47 µmol m^?2 h^?1). At other periods, Fe/PO₄ ratios higher than 2 mol/mol indicated very low phosphate fluxes. In contrast, in the Rivière d’Auray, the occurrence of macroalgae, stranding regularly all over the site, clearly masked the impact of oyster cultures on sediment properties and the phosphorus cycle and made the use of Fe/PO₄ ratios more difficult in terms of indicators of phosphate release.     

Simulating Large Gaussian Random Vectors Subject to Inequality Constraints by Gibbs Sampling

The Gibbs sampler is an iterative algorithm used to simulate Gaussian random vectors subject to inequality constraints. This algorithm relies on the fact that the distribution of a vector component conditioned by the other components is Gaussian, the mean and variance of which are obtained by solving a kriging system. If the number of components is large, kriging is usually applied with a moving search neighborhood, but this practice can make the simulated vector not reproduce the target correlation matrix. To avoid these problems, variations of the Gibbs sampler are presented. The conditioning to inequality constraints on the vector components can be achieved by simulated annealing or by restricting the transition matrix of the iterative algorithm. Numerical experiments indicate that both approaches provide realizations that reproduce the correlation matrix of the Gaussian random vector, but some conditioning constraints may not be satisfied when using simulated annealing. On the contrary, the restriction of the transition matrix manages to satisfy all the constraints, although at the cost of a large number of iterations.     

Analytical orbit predictions with air drag using KS uniformly regular canonical elements

A new nonsingular analytical theory for the motion of near Earth satellite orbits with the air drag effect is developed for long term motion in terms of the KS uniformly regular canonical elements by a series expansion method, by assuming the atmosphere to be symmetrically spherical with constant density scale height. The series expansions include up to third order terms in eccentricity. Only two of the nine equations are solved analytically to compute the state vector and change in energy at the end of each revolution, due to symmetry in the equations of motion. Numerical comparisons of the important orbital parameters semi major axis and eccentricity up to 1000 revolutions, obtained with the present solution, with KS elements analytical solution and Cook, King-Hele and Walker's theory with respect to the numerically integrated values, show the superiority of the present solution over the other two theories over a wide range of eccentricity, perigee height and inclination.     

Recent advances and low cost concept for the gamma-ray lens project MAX

Until recently, focusing of gamma-radiation was regarded as an impracticable task. Today, gamma-ray lenses have become feasible and present promising perspectives for future instrumentation. For the first time in high energy astronomy the signal/noise ratio will be dramatically improved as gamma-rays are collected on the large area of a lens from where they are focused onto a small detector. Besides an unprecedented sensitivity, MAX will feature very high angular and energy resolution. The conjunction of this new technique of Gamma Ray focusing and the new possibilities brought by the developping formation flying technology will allow a great step for Gamma Astronomy. This paper will describe after a short recall of the scientific objectives of MAX, the design of the MAX formation flying concept and the associated main design drivers and constraint.     

Micromechanics of saturated and unsaturated porous media

The homogenization method is used to determine the formulation of the behaviour of both saturated and unsaturated porous media. This approach makes it possible to assess the validity of the effective stress concept as a function of the properties of the porous media at the microscopic scale. Furthermore, the influence of the morphologies of the solid and fluid phases on the macroscopic behaviour is studied. The strain induced by drying is examined as a function of the morphological properties. Copyright © 2002 John Wiley & Sons, Ltd.     

The Piànico tephra: an early Middle Pleistocene record of intraplate volcanism in the Mediterranean

ABSTRACT Distal tephra are a valuable record of the volcano-tectonic evolution of an area under study. Here, we document the case of the Early Middle Pleistocene rhyolitic tephra of Piànico, discovered in the Southern Italian Alps. The geochemical characteristics of Piànico are unique among the distal tephra outcropping in Italy and indicate an intraplate volcanism at the source. The alkali composition and trace elements show a striking resemblance with the rhyolitic complex of the Euganean Hills, located 170 km from Piànico. However, these rhyolites are much older (Oligocene). Alternatively, the source of this intraplate volcanic episode could be located in the southern Tyrrhenian Sea.