油气田开发中油气藏地质成因分析

本文从油气藏地质成因分析的基础资料入手,总结该项研究的主要内容包括:构造、储层和油气水分布特征等3方面.结合自身科研实践,认为油气藏地质成因分析方法主要包括:野外露头和现代沉积考察、岩心观察描述、显微镜下薄片观察鉴定、地球物理解释预测、地质统计学分析、分析测试、各种物理模拟和数值模拟、油气藏动态监测和生产动态等,并阐述了不同研究方法的优缺点.目前油气藏地质成因分析存在的主要问题包括:对油气藏地质成因分析重视程度不够、研究方法偏定性、地质成因分析和油气藏表征结合不紧密、油气藏表征精度制约了地质成因分析的准确度、油气藏地质成因分析综合性不强、特殊类型油气藏地质成因分析还存在诸多难题等.本文指出了该研究未来发展方向.主要包括:依靠油气藏地质成因分析解决油气田开发中的难题、通过各种模拟方法提高油气藏地质成因分析定量化水平、加强地质成因分析以提高油气藏表征水平、利用油气藏表征促进地质成因分析进步、拓展油气藏地质成因分析在油气田开发中应用的领域、特殊类型油气藏地质成因分析等.     

Molecular Structure of Kerogen in the Longmaxi Shale: Insights from Solid State NMR,FT‐IR,XRD and HRTEM

Kerogen plays an important role in shale gas adsorption, desorption and diffusion. Therefore, it is necessary to characterize the molecular structure of kerogen. In this study, four kerogen samples were isolated from the organic-rich shale of the Longmaxi Formation. Raman spectroscopy was used to determine the maturity of these kerogen samples. High-resolution transmission electron microscopy (HRTEM), 13C nuclear magnetic resonance (13C NMR) , X-ray diffraction (XRD) and Fourier transform infrared (FT-IR) spectroscopy were conducted to characterize the molecular structure of the shale samples. The results demonstrate that VReqv of these kerogen samples vary from 2.3% to 2.8%, suggesting that all the kerogen samples are in the dry gas window. The macromolecular carbon skeleton of the Longmaxi Formation kerogen is mainly aromatic (fa’=0.56). In addition, the aromatic structural units are mainly composed of naphthalene (23%), anthracene (23%) and phenanthrene (29%). However, the aliphatic structure of the kerogen macromolecules is relatively low (fal*+falH=0.08), which is presumed to be distributed in the form of methyl and short aliphatic chains at the edge of the aromatic units. The oxygen-containing functional groups in the macromolecules are mainly present in the form of carbonyl groups (fac=0.23) and hydroxyl groups or ether groups (falO=0.13). The crystallite structural parameters of kerogen, including the stacking height (Lc=22.84 ?), average lateral size (La=29.29 ?) and interlayer spacing (d002=3.43 ?), are close to the aromatic structural parameters of anthracite or overmature kerogen. High-resolution transmission electron microscopy reveals that the aromatic structure is well oriented, and more than 65% of the diffractive aromatic layers are concentrated in the main direction. Due to the continuous deep burial, the longer aliphatic chains and oxygen-containing functional groups in the kerogen are substantially depleted. However, the ductility and stacking degree of the aromatic structure increases during thermal evolution. This study provides quantitative information on the molecular structure of kerogen samples based on multiple research methods, which may contribute to an improved understanding of the organic pores in black shale.     

In Situ U‐Th‐Pb Dating and Sr‐Nd Isotope Analysis of Bastnäsite by LA‐(MC)‐ICP‐MS

Bastnäsite is the end member of a large group of carbonate–fluoride minerals with the common formula (REE) CO₃F·CaCO₃. This group is generally widespread and, despite never occurring in large quantities, represents the major economic light rare earth element (LREE) mineral in deposits related to carbonatite and alkaline intrusions. Since bastnäsite is easily altered and commonly contains inclusions of earlier‐crystallised minerals, in situ analysis is considered the most suitable method to measure its U‐Th‐Pb and Sr‐Nd isotopic compositions. Electron probe microanalysis and laser ablation (multi‐collector) inductively coupled plasma‐mass spectrometry of forty‐six bastnäsite samples from LREE deposits in China, Pakistan, Sweden, Mongolia, USA, Malawi and Madagascar indicate that this mineral typically has high Th and LREE and moderate U and Sr contents. Analysis of an in‐house bastnäsite reference material (K‐9) demonstrated that precise and accurate U‐Th‐Pb ages could be obtained after common Pb correction. Moreover, the Th‐Pb age with its high precision is preferable to the U‐Pb age because most bastnäsites have relatively high Th rather than U contents. These results will have significant implications for understanding the genesis of endogenous ore deposits and formation processes related to metallogenic geochronology research.     

南海北部西沙海槽沉积物管状黄铁矿特征及其形成机理*

南海北部西沙海槽S1站位的岩心柱沉积物中广泛发育自生矿物黄铁矿,其形态以管状为主,且具有内部中空的圈层结构。使用扫描电镜、电子探针、LA-ICP-MS、SIMS等测试方法研究了管状黄铁矿的形态及圈层结构,结果显示: (1)管状黄铁矿发育内部中空的圈层结构,其中内圈层(I_py)由莓球状黄铁矿呈五角十二面体紧密堆积组成,外圈层(O_py)由晶形较好晶粒较大的八面体黄铁矿组成,并混有沉积碎屑及钙质生物壳体;(2)内圈层和外圈层分别呈现出贫S富Fe和富S贫Fe的特征,其成因是甲烷渗漏造成的局部还原环境使得As进入黄铁矿中导致晶格空缺或被扭曲,从而促进Ni、Co、Cu、Zn、Pb等微量元素的掺入;(3)内圈层、外圈层发生了明显的硫同位素分馏现象,内圈层中 δ³⁴S 平均为-37.8‰,外圈层中 δ³⁴S 平均为-29.3‰。研究认为,管状黄铁矿作为曾经甲烷渗漏的通道,其生长机制可分为3个阶段: (1)气水通道形成阶段: 向上运移的甲烷流体在沉积物孔隙中逐渐形成气水通道;(2)外圈层形成阶段: 当向上运移的甲烷与硫酸盐发生甲烷厌氧氧化时,逐渐形成晶体较大、晶形较好的八面体黄铁矿外圈层;(3)内圈层形成阶段: 随着甲烷浓度逐渐降低,在气水通道中的微生物作用下,剩余甲烷与向下运移的硫酸盐继续反应形成莓球状黄铁矿内圈层。因此,南海北部的泥岩中大量发育的管状黄铁矿常常与地层中甲烷水合物的存在有关。     

赣南狮吼山硫铁多金属矿区花岗岩地球化学、年代学特征及其成因

狮吼山矿区是江西省内规模最大的矽卡岩型硫铁多金属矿床,伴生W、Cu、Au多种成矿元素,成矿作用与矿区出露的茶山迳复式花岗岩体有关。岩体主要包括茶山迳似斑状黑云母二长花岗岩和莲湖细粒二长花岗岩两期,为研究成矿岩体的侵位时代、岩石成因及与成矿的关系,本次工作进行了U-Pb锆石定年、岩相学和岩石地球化学等测试分析。结果表明：岩体具有高硅、高钾、富铝的特征,属高钾钙碱性系列花岗岩;轻重稀土元素分馏明显,均为右倾型,弱Eu负异常,以富集Cs、Rb、Th、U、Pb,亏损Ba、Nb、Sr、和Ti等元素为主要特征,属于低Ba-Sr壳源花岗岩类;锆石具较好晶形,具典型岩浆锆石特征,利用LA-ICP-MS进行U-Pb测年,获得谐和年龄为（162.4±0.6）Ma（MSWD=1.8）,加权平均年龄为（162.4±1.4）Ma（MSWD=1.4）,谐和年龄与加权平均年龄在误差范围内高度一致,表明茶山迳复式岩体侵位于燕山早期中侏罗世;综合考虑岩体矿物组合、主微量元素及高分异特征,认为其成因分类应属于S型花岗岩;对比中国花岗岩成矿元素平均含量,茶山迳两期花岗岩均具有较高的W、Mo、Bi、Pb等成矿元素含量,可同时为成矿作用提供热源、流体及物质。     

分形岩石裂隙中渗流扩散运动的试验研究

由于存在大量粗糙不规则裂隙,使得岩体中流体运动极为复杂。针对天然粗糙岩石裂隙渗流试验存在物理模型隐蔽性和不可重复性等难点,基于三维Weierstrass-Mandelbrot分形函数构建了粗糙节理面的裂隙通道,采用3D打印技术获得了透明精细的裂隙模型,使用微流体控制仪研究了不同试验条件下的裂隙渗流扩散运动,分析了裂隙通道流量与压力水头、裂隙宽度和分形维数之间的关系。研究结果表明:与平行板立方定律近似,在分形裂隙中,裂隙通道流量与压力水头成线性关系;单宽流量与裂隙通道的宽度成近似的三次方关系;考虑分形维数影响时,相同条件下流过裂隙通道的流量随着分形维数的增加而增加;粗糙裂隙渗流立方定律可采用与分形维数相关的幂指数函数进行修正。     

Southeast Bayuda volcano-sedimentary sequences (Kurmut terrane,Sudan): juvenile island arc series within the mega-shear zone marking the eastern boundary of the Saharan Metacraton

This study was conducted to investigate the volcano-sedimentary sequence of Kurmut terrane in southeast Bayuda Desert and its continuation east of the Nile. The sequence is situated at the inferred transition between the Neoproterozoic juvenile Arabian–Nubian Shield and the old reworked Saharan Metacraton. Lithologically, the rocks are composed of intermediate to basic metavolcanics and volcanoclastics intercalated with tuffeous material and metapelite sediments that formed in cyclic graded bedding, indicating a turbid environment in the active orogenic zone. For the first time in the study area, intraformational conglomerates with cigar-shaped volcanic clasts within the low-grade metasediments suggest a high-energy depositional environment. Minerals and textural examination of rock assemblage indicate an anticlockwise P/T condition from amphibolite facies to retrograde greenschist facies conditions in a large high strain zone of distributed deformation. Geochemical results of metavolcanics indicate derivation from different mantle sources (island arc tholeite, calc-alkaline basalt, mid-oceanic ridge, and back-arc basalt). Within this sequence, field relation and microstructural analysis clearly show the best evidence of superimposition of sinistral shear of the NNE–SSW-trending Keraf Shear Zone on the early dextral NE–SW Nakasib Suture Zone. Consequently, based on lithological and structural observations with support of available geochemical data, the volcano-sedimentary sequences SE of Bayuda Desert and east of Nile are similar to their equivalent assemblage of juvenile Neoproterozoic arc lavas association of the Arabian–Nubian Shield.     

海拉尔盆地贝尔凹陷伸展断层转折褶皱作用及其对沉积作用的制约

海拉尔盆地是叠置于内蒙－大兴安岭古生代碰撞造山带之上的中新生代盆地,总体上呈北东向展布,由3坳、2隆5个一级构造单元组成,自西向东依次为扎贲诺尔坳陷、嵯岗隆起、贝尔湖坳陷、巴彦山隆起和呼和湖坳陷, 其中贝尔凹陷是贝尔湖坳陷南部的1个二级构造单元。贝尔凹陷的控陷断层为1个上凸、2个上凹断层转折组合构成的犁式正断层,在深部发育伸展双重构造。在犁式正断层上盘由于上凸断层转折产生的活动轴面与断层面为同旋向剪切,而上凹断层转折产生的活动轴面与断层面为反旋向剪切,在断层上盘形成2个背斜中间夹1个向斜的构造组合。由活动轴面与固定轴面之间滚动面的宽度确定控陷断层F₁在早白垩世南屯期晚期的水平伸展量为6 850 m。贝尔坳陷伸展断层转折褶皱的几何学和运动学特征,反映了断层滑移速率、构造沉降速率和沉积速率对凹陷内沉积地层变形特征的影响和构造活动对沉积作用和油气地质条件的制约。贝尔凹陷南屯组上段内部角度不整合的形成与变形作用中的剥蚀作用和沉积间断无关,而是由于半地堑从略欠补偿充填向过补偿充填状态转变时,沉积速率相对于构造沉降速率显著增加所致。     

Carboniferous Biostratigraphy of Guizhou Province

The Carboniferous in Guizhou may be divided into 3 lithostratigraphic regions, 2 series and 7 stages. TheLower Carboniferous is composed of 4 regional stages, 1 foraminifer assemblage, 4 fossil coral zones (with 9subzones) and 11 brachiopod assemblages; the Upper Carboniferous is divided into 3 regional. stages, 9fusulinid zones (with 2 subzones) and 4 ammonite zones. Based on the studies of foraminifers and conodonts.the base of the Carboniferous in Guizhou 1s placed at least near the top of the coral Cystophrentis zone.     

关于氡测量标定装置(氡室)和测量单位的统一

本文介绍了作者研制的8505—I型氡室,该氡室可用于准确和快速标定多种测氡装置。作者提出了相应的标定方法,并测定了野外常用的10种氡探测器的标定系数。根据法定计量单位选用了贝克(Bq)和贝克/升(Bq/L)。相应作为各种氡测量的[放射性]活度单位和氡浓度单位。