The impact of salt water inflows on the distribution of polycyclic aromatic hydrocarbons in the deep water of the Baltic Sea

Salt-water inflows into the Baltic Sea are important events for renewing the deep and bottom waters of the deep basins of the Baltic Sea. These events occur only at irregular intervals. The last strong event was in January 1993 followed by minor inflows in winter 1993/1994. As a result of these inflows, the deep water of the central Baltic basins was completely renewed.Based on extensive observations of polycyclic aromatic hydrocarbons (PAHs) in water, fluffy layer material and surface sediments between 1992 and 1998, the transformation of PAHs and the modification of their distribution in the Baltic deep water is discussed in connection with the spreading of the inflowing highly saline and oxygen-rich water along its pathway from the sills into the central basins. In the course of the inflows in 1993/1994, the PAH concentration in the deep water of the different basins increased significantly. The concentrations were elevated, at least by a factor of 2 and as much as seven to eight times (for the four-ring PAHs) compared to the previous and the following years. Two hypotheses for the causes were discussed: the inflowing salt water may have entrained more highly polluted surface water in the western Baltic Sea, or it may have entrained contaminated fluffy layer material or sediment particles along the route of transport.     

Automated Extraction of a Five‐Year LA‐ICP‐MS Trace Element Data Set of Ten Common Glass and Carbonate Reference Materials: Long‐Term Data Quality,Optimisation and Laser Cell Homogeneity

LA‐ICP‐MS is increasingly applied to obtain quantitative multi‐element data with minimal sample preparation, usually achieved by calibration using reference materials (RMs). However, some ubiquitous RMs, for example the NIST SRM 61× series glasses, suffer from reported value uncertainties for certain elements. Moreover, no long‐term data set of analyses conducted over a range of ablation and tuning conditions exists. Thus, there has been little rigorous examination of the extent to which offsets between measured and reported values are the result of error in these values rather than analytically induced fractionation. We present new software (‘LA‐MINE’), capable of extracting LA‐ICP‐MS data with no user input, and apply this to our system, yielding over 5 years of data (~ 5700 analyses of ten glass and carbonate RMs). We examine the relative importance of systematic analytical bias and possible error in reported values through a mass‐specific breakdown of fourteen of the most commonly determined elements. Furthermore, these data, obtained under a wide range of different ablation conditions, enable specific recommendations of how data quality may be improved, for example the role of diatomic gas, the effect of differential inter‐glass fractionation factors and choice of transport tubing material. Finally, these data demonstrate that the two‐volume Laurin ablation cell is characterised by no discernible spatial heterogeneity in measured trace element ratios.     

Über stratigraphische Untersuchungsmethoden in rezenten Tiefseesedimenten

Zusammenfassung Durch Bestimmung der Foraminiferenanzahl in I g Sediment wird die biostratigraphische Untersuchungsmethode, die mittels einer qualitativen und quantitativen Erfassung der Foraminiferenfauna in den Tiefseekernen der deutschen Meteor-Expedition und schwedischen Albatroß-Expedition durchgeführt werden ist, auf ihre Richtigkeit hin geprüft. Die Untersuchung hat die Anwendbarkeit dieser stratigraphischen Methode bestätigt. Sie hat daneben wiederum gezeigt, daß die Verbreitung und Entwicklung der einzelnen Foraminiferenarten vor allem von der Temperatur des Meerwassers abhängig sind; andere Faktoren wie Phosphatgehalt des Wassers usw. scheinen in dieser Hinsicht eine mehr untergeordnete Rolle zu spielen. Unter gewissen Voraussetzungen können Tiefseekerne durch Bestimmung der Foraminiferenanzahl je 1 g Sediment in groben Zügen stratigraphisch gegliedert werden; auch kann die Individuenanzahl der einzelnen Foraminiferenarten aus der Foraminiferenanzahl in 1 g Sediment und aus der prozentualen Zusammensetzung der Gesamtfauna errechnet werden. Mit den hier gewonnenen Erkenntnissen wird versucht, die engen Bezichungen zwischen dem prozentualen Anteil der Warmwasserforaminiferen in der Gesamtfauna und dem CO₂-Gehalt des Sedimentes, dieOvey im Kern 241 der schwedischen Albatroß-Expedition beobachtet hat, zu deuten.Herrn Professor Dr.Carl W. Correns zum 60. Geburtstag gewidmet.     

Pulsar radio emission

Radio emission by pulsars is calculated from first principles. In an almost current-free magnetosphere, the two charged components (of the unsteadily escaping pair plasma) have different (and varying) bulk Lorentz factors. Curvature radiation emitted by the more energetic component is thus locally coherent, (so-called antenna mechanism). Strong enough seed signals cause the relativistically streaming charges to enhance their radiation, via an induced drift that can largely exceed the curvature drift. This amplification mechanism is similar to - but different from - that of a maser; we call it a MAIDER. Maximal amplification occurs at an (emission) altitude where the two components have sufficiently separated in energy though not yet separated too strongly in space.     

Atmospheric superrotation on Saturn and Jupiter

The problem is discussed whether atmospheric superrotation is driven by internal or external torques. An integral constraint is derived which under certain conditions forbids geostrophic flow, and suggests corkscrew-shaped motion along zones of constant latitude. A momentum balance consideration restricts effective viscosities in the upper atmospheres to be much smaller than maximal eddy viscosity, perhaps as small as molecular viscosity.     

The dependence on system parameters of strange-mode instabilities in accretion discs

A systematic study of the dependence on disc parameters and input physics, such as opacity and the treatment of convection, of strange-mode instabilities in thin accretion discs, which have been discovered recently, is presented. The instabilities are found to exist for a wide range of parameters, are partly very robust, and their growth rates can reach the dynamical range. Even discs on galactic scales around massive black holes are affected by them. Two groups of instabilities can be distinguished, the first of which is related to the radiation-pressure-dominated part of the disc, and the second to helium/hydrogen ionization. By application of the NAR approximation, both of them can be shown to be of mechanical origin, and the classical κ -mechanism can be excluded as the instability mechanism. A heuristic model for strange-mode instabilities proposed in the context of stellar strange-mode instabilities in luminous stars seems to be applicable to the group associated with dominant radiation pressure.     

Advances in radiative transfer

This review describes advances in radiative transfer theory since about 1985. We stress fundamental aspects and emphasize modern methods for the numerical solution of the transfer equation for spatially multidimensional problems, for both unpolarized and polarized radiation. We restrict the discussion to two-level atoms with noninverted populations for given temperature, density and velocity fields. Unfortunately this article was originally published with typesetter's errors: The correct publication date was 25 February 2006, not 3 January 2006. The content was not in the final form. The publishers wish to apologize for this mistake. The online version of the original version can be found at /10.1007/s00159-005-0025-8.     

Numerical simulation of coronal heating by resonant absorption of Alfvén waves

The heating of coronal loops by resonant absorption of Alfvén waves is studied in compressible, resistive magnetohydrodynamics. The loops are approximated by straight cylindrical, axisymmetric plasma columns and the incident waves which excite the coronal loops are modelled by a periodic external driver. The stationary state of this system is determined with a numerical code based on the finite element method. Since the power spectrum of the incident waves is not well known, the intrinsic dissipation is computed. The intrinsic dissipation spectrum is independent of the external driver and reflects the intrinsic ability of the coronal loops to extract energy from incident waves by the mechanism of resonant absorption.The numerical results show that resonant absorption is very efficient for typical parameter values occurring in the loops of the solar corona. A considerable part of the energy supplied by the external driver, is actually dissipated Ohmically and converted into heat. The heating of the plasma is localized in a narrow resonant layer with a width proportional to ^1/3. The energy dissipation rate is almost independent of the resistivity for the relevant values of this parameter. The efficiency of the heating mechanism and the localization of the heating strongly depend on the frequency of the external driver. Resonant absorption is extremely efficient when the plasma is excited with a frequency near the frequency of a so-called collective mode.