Biological and granulometric controls on sedimentary organic matter of an intertidal mudflat

A variety of measures of organic matter concentration and quality were made on samples collected from the top few mm of intertidal mudflat sediment over the course of a year, in order to assess the relative importance of biological and sedimentological influences on sedimentary organic matter. Winter and summer were times of relatively fine-grained sediment accumulation, caused by biological deposition or stabilization processes and resulting in higher organic matter concentrations. Stable carbon isotope and Br:C ratios indicated a planktonic source of bulk organic matter. Ratios of organic carbon to specific surface area of the sediments were consistent with an organic monolayer coverage of sediment grains. Correction for changing grain size during the year showed no change in the organic concentration per unit surface area, in spite of organic matter inputs by in situ primary production, buildup of heterotroph biomass and mucus coatings, and biodeposition of organic-rich seston. There were also no indications of changes in bulk organic quality, measured as hydrolyzable carbohydrates and amino acids, in response to these biological processes. It is concluded that biological processes on a seasonal time scale affect the bulk organic matter of these sediments via a modulation of grain size rather than creation or decay of organic matter.     

A comparative study of the zooplankton in two adjacent embayments,Port Phillip and Westernport Bays,Australia

We report on a year's study of spatial and seasonal patterns of zooplankton abundance in Port Phillip and Westernport Bays, July 1982 to August 1983. These two bays, closely adjacent on the southern coast of Victoria, Australia, differ in several respects: Port Phillip is a nearly landlocked bay with a broad basin, while Westernport is an open tidal embayment with extensive mud and seagrass banks. Both bays have a resident zooplankton fauna distinct from that of Bass Strait. Although these resident communities have many species in common, patterns of abundance and dominance are quite different. We found that the holoplankton of Port Phillip was about half copepods, mostly Paracalanus indicus, with 23% Caldocera and 21% larvaceans. Westernport Bay zooplankton was dominated by Acartia tranteri, with no resident cladoceran fauna. Bass Strait species were more often found in Westernport than in Port Phillip Bay, but the resident community of Port Phillip Bay was more similar to that of Bass Strait than to that of Westernport.Although this study was undertaken in an exceptionally dry year, the available historical data show that the overall patterns found in 1982–1983 are typical for these bays. The differences in community composition probably relate to differences in depth profile, predator abundance, and suspended matter between the bays.     

Hydrodynamic control of phytoplankton in low salinity waters of the James River estuary,Virginia, U.S.A.

Autotrophic biomass and productivity as well as nutrient distributions and phytoplankton cell populations in the James River estuary, Virginia, were quantified both spatially and temporally over a 17-month period. Emphasis was placed on the very low salinity region of the estuary in order to gain information on the fate of freshwater phytoplankters. Differing amounts of freshwater plant biomass are advected into the estuary as living material, DOC or POC and the demonstrated variability of this input must play an important role in marine biogeochemical cycling.Late summer and fall maxima in both chlorophyll a and the photosynthetic production of particulate organic carbon in very low salinity regions were inversely correlated with river discharge.During periods of low river discharge greater than 50% of the chlorophyll a biomass measured at 0‰ disappeared within a narrow range of salinity (0–2‰). Cell enumeration data suggest that species introduced from the freshwater end-member tend to comprise the bulk of the biomass removed. Confounding factors, which may contribute to the regulation of both the abundance and species of phytoplankters mid-river, include the flocculation of colloidal material with phytoplankton cells, the presence of the turbidity maximum and the growth of endemic phytoplankton populations.An inverse relationship exists between the phytoplankton abundance in very low salinity waters and the abundance of biomass measured in the lower portion of the river (estuary). Thus, autotrophic production in the fresh and very low salinity areas may indirectly regulate the onset on the spring bloom in the estuary by controlling the amount of nutrients available.     

Optimization of grid-drilling using computer simulation

A computer simulation method has been developed to find efficient drilling grids for mineral deposits. A well-known ore deposit is used as a model to develop an efficient pattern for undiscovered ore bodies in the same area or in other prospects where similar geometry is suspected. The model for this study is the Austinville, Virginia deposit, a Mississippi Valley-type deposit composed of 17 ore bodies totaling 34 million short tons (30 million metric tons). The method employs a computer program that simulates drilling the model deposit with different patterns, including various levels of follow-up drilling. Follow-up holes are drilled in fences at one half the original spacing around holes in the grid that show ore-grade mineralization. Each pattern is drilled 100 times from random starting locations to provide a range of outcomes of drilling, including the best, worst, and most likely. For this study, patterns of 100 drill holes were composed of 10 fences spaced 1000–5000 feet (305–1524 m) apart, each with 10 holes spaced 200–1000 feet (61–305 m) apart. In all, 25 grids were used with zero to three levels of follow-up drilling. The 600/2000 grid, with drill holes spaced 600 feet (183 m) apart in fences spaced 2000 feet (610 m) apart, was compared with the 200/5000 grid because they represented contrasting outcomes. The 600/2000 grid penetrated many ore bodies consistently but with few multiple hits to individual ore bodies; whereas the 200/5000 grid inconsistently penetrated few ore bodies with many multiple hits. The 600/2000 grid was more efficient than the 200/5000 grid at hitting large ore bodies of 1,000,000 short tons or greater (900,000 metric tons or greater) and was made more effective by adding one cycle of follow-up drilling. The 600/2000 grid had a 97% chance of hitting one or more large ore bodies with at least one drill hole per ore body, and the 200/5000 grid had a 64% chance. Once hit, there was an 82% chance that the largest ore body would be penetrated by three or more holes when using the 600/2000 grid and an 88% chance using the 200/5000 grid.     

Copper(II) humate mobility in kaolinite soil

An investigation of the influence of humate on the mobility of copper(II) ions in a kaolinite soil using leaching tests and electrokinetic experiments is reported. The data are interpreted in terms of humate–copper–clay interactions and humate electrical charge. Humate is mostly immobile below pH8 but is more mobile in alkaline conditions (sorption to kaolinite reduces its mobility in neutral conditions). Copper humate complexes are mobile in both acidic and alkaline conditions, but not in neutral conditions where they are sorbed. The dissolved copper humate complexes that form in acidic conditions are positively charged. The net effect of humate is to increase cupric ion mobility in kaolinite soil, especially in alkaline conditions.     

Hanford tank residual waste – Contaminant source terms and release models

Residual waste is expected to be left in 177 underground storage tanks after closure at the US Department of Energy’s Hanford Site in Washington State, USA. In the long term, the residual wastes may represent a potential source of contamination to the subsurface environment. Residual materials that cannot be completely removed during the tank closure process are being studied to identify and characterize the solid phases and estimate the release of contaminants from these solids to water that might enter the closed tanks in the future. As of the end of 2009, residual waste from five tanks has been evaluated. Residual wastes from adjacent tanks C-202 and C-203 have high U concentrations of 24 and 59 wt.%, respectively, while residual wastes from nearby tanks C-103 and C-106 have low U concentrations of 0.4 and 0.03 wt.%, respectively. Aluminum concentrations are high (8.2–29.1 wt.%) in some tanks (C-103, C-106, and S-112) and relatively low (<1.5 wt.%) in other tanks (C-202 and C-203). Gibbsite is a common mineral in tanks with high Al concentrations, while non-crystalline U–Na–C–O–P ± H phases are common in the U-rich residual wastes from tanks C-202 and C-203. Iron oxides/hydroxides have been identified in all residual waste samples studied to date. Contaminant release from the residual wastes was studied by conducting batch leach tests using distilled deionized water, a Ca(OH)₂-saturated solution, or a CaCO₃-saturated water. Uranium release concentrations are highly dependent on waste and leachant compositions with dissolved U concentrations one or two orders of magnitude higher in the tests with high U residual wastes, and also higher when leached with the CaCO₃-saturated solution than with the Ca(OH)₂-saturated solution. Technetium leachability is not as strongly dependent on the concentration of Tc in the waste, and it appears to be slightly more leachable by the Ca(OH)₂-saturated solution than by the CaCO₃-saturated solution. In general, Tc is much less leachable (<10 wt.% of the available mass in the waste) than previously predicted. This may be due to the coprecipitation of trace concentrations of Tc in relatively insoluble phases such as Fe oxide/hydroxide solids.     

Origin of basaltic magmas in the Mojave Desert area,California

The basaltic lavas erupted throughout the Mojave Desert are basanites (SiO₂<46%, normative nepheline>5%, and K₂O>1.5%), alkali-olivine basalts (SiO₂=46–48%; ne=0–5%; and K₂O=1.0–1.5%), and low-alumina, sub-alkaline basalts (SiO₂=48–51%; ne=0; K₂O<1.0%). One volcano, Pisgah Crater, erupted five times, with lava from each successive phase containing more silica and less potash than the one proceeding it. This compositional trend is the reverse of that expected from differentiation of a single alkalic magma, and therefore, may represent a succession of magmas tapped from a zone of continuing partial melting in the mantle.These lava compositions suggest that first melting was under high water pressure and was followed by relatively dry partial melting of gamet-orthopyroxene-clinopyroxene-olivine assemblages. The successive increase in silica and alkali decrease also requires that the partial melting zone move to shallower levels.All lavas sampled in the Mojave Desert area have compositions that can best be explained by the extraction of magma from such a rising melting zone, analogous to the mantle diapirs suggested by Green and Ringwood.