Anisotropic mechanical properties of zircon and the effect of radiation damage

This study provides new insights into the relationship between radiation-dose-dependent structural damage due to natural U and Th impurities and the anisotropic mechanical properties (Poisson’s ratio, elastic modulus and hardness) of zircon. Natural zircon samples from Sri Lanka (see Muarakami et al. in Am Mineral 76:1510–1532, 1991) and synthetic samples, covering a dose range of zero up to 6.8 × 10¹⁸ α-decays/g, have been studied by nanoindentation. Measurements along the [100] crystallographic direction and calculations, based on elastic stiffness constants determined by Özkan (J Appl Phys 47:4772–4779, 1976), revealed a general radiation-induced decrease in stiffness (~54 %) and hardness (~48 %) and an increase in the Poisson’s ratio (~54 %) with increasing dose. Additional indentations on selected samples along the [001] allowed one to follow the amorphization process to the point that the mechanical properties are isotropic. This work shows that the radiation-dose-dependent changes of the mechanical properties of zircon can be directly correlated with the amorphous fraction as determined by previous investigations with local and global probes (Ríos et al. in J Phys Condens Matter 12:2401–2412, 2000a; Farnan and Salje in J Appl Phys 89:2084–2090, 2001; Zhang and Salje in J Phys Condens Matter 13:3057–3071, 2001). The excellent agreement, revealed by the different methods, indicates a large influence of structural and even local phenomena on the macroscopic mechanical properties. Therefore, this study indicates the importance of acquiring better knowledge about the mechanical long-term stability of radiation-damaged materials.     

From taxonomies to ontologies: formalizing generalization knowledge for on-demand mapping

Automation of the cartographic design process is central to the delivery of bespoke maps via the web. In this paper, ontological modeling is used to explicitly represent and articulate the knowledge used in this decision-making process. A use case focuses on the visualization of road traffic accident data as a way of illustrating how ontologies provide a framework by which salient and contextual information can be integrated in a meaningful manner. Such systems are in anticipation of web-based services in which the user knows what they need, but do not have the cartographic ability to get what they want.     

Using a Thermal Proxy to Examine Sediment–Water Exchange in Mid-Continental Shelf Sandy Sediments

Fluid exchange across the sediment–water interface in a sandy open continental shelf setting was studied using heat as a tracer. Summertime tidal oscillation of cross-shelf thermal fronts on the South Atlantic Bight provided a sufficient signal at the sediment–water interface to trace the advective and conductive transport of heat into and out of the seabed, indicating rapid flushing of ocean water through the upper 10–40 cm of the sandy seafloor. A newly developed transport model was applied to the in situ temperature data set to estimate the extent to which heat was transported by advection rather than conduction. Heat transported by shallow 3-D porewater flow processes was accounted for in the model by using a dispersion term, the depth and intensity of which reflected the depth and intensity of shallow flushing. Similar to the results of past studies in shallower and more energetic nearshore settings, transport of heat was greater when higher near-bed velocities and shear stresses occurred over a rippled bed. However, boundary layer processes by themselves were insufficient to promote non-conductive heat transport. Advective heat transport only occurred when both larger boundary layer stresses and thermal instabilities within the porespace were present. The latter process is dependent on shelf-scale heating and cooling of bottom water associated with upwelling events that are not coupled to local-scale boundary layer processes.     

A method of alternating characteristics with application to advection-dominated environmental systems

We present a numerical method for solving a class of systems of partial differential equations (PDEs) that arises in modeling environmental processes undergoing advection and biogeochemical reactions. The salient feature of these PDEs is that all partial derivatives appear in linear expressions. As a result, the system can be viewed as a set of ordinary differential equations (ODEs), albeit each one along a different characteristic. The method then consists of alternating between equations and integrating each one step-wise along its own characteristic, thus creating a customized grid on which solutions are computed. Since the solutions of such PDEs are generally smoother along their characteristics, the method offers the potential of using larger time steps while maintaining accuracy and reducing numerical dispersion. The advantages in efficiency and accuracy of the proposed method are demonstrated in two illustrative examples that simulate depth-resolved reactive transport and soil carbon cycling.     

Defining the Potential of Nanoscale Re‐Os Isotope Systematics Using Atom Probe Microscopy

Atom probe microscopy (APM) is a relatively new in situ tool for measuring isotope fractions from nanoscale volumes (< 0.01 μm³). We calculate the theoretical detectable difference of an isotope ratio measurement result from APM using counting statistics of a hypothetical data set to be ± 4δ or 0.4% (2s). However, challenges associated with APM measurements (e.g., peak ranging, hydride formation and isobaric interferences), result in larger uncertainties if not properly accounted for. We evaluate these factors for Re‐Os isotope ratio measurements by comparing APM and negative thermal ionisation mass spectrometry (N‐TIMS) measurement results of pure Os, pure Re, and two synthetic Re‐Os‐bearing alloys from Schwander et al. (2015, Meteoritics and Planetary Science, 50, 893) [the original metal alloy (HSE) and alloys produced by heating HSE within silicate liquid (SYN)]. From this, we propose a current best practice for APM Re‐Os isotope ratio measurements. Using this refined approach, mean APM and N‐TIMS ¹⁸⁷Os/¹⁸⁹Os measurement results agree within 0.05% and 2s (pure Os), 0.6–2% and 2s (SYN) and 5–10% (HSE). The good agreement of N‐TIMS and APM ¹⁸⁷Os/¹⁸⁹Os measurements confirms that APM can extract robust isotope ratios. Therefore, this approach permits nanoscale isotope measurements of Os‐bearing alloys using the Re‐Os geochronometer that could not be measured by conventional measurement principles.     

Use of photo-based 3D photogrammetry in analysing the results of laboratory pressure grouting tests

This paper presents a non-destructive, low-cost, photo-based, 3D reconstruction technique for characterizing geo-materials with irregular shapes of a relatively large size. After being validated against two traditional volume measurement methods, namely the vernier caliper method and the fluid displacement method for regular and irregular shapes, respectively, 3D photogrammetry was used to analyse the grout bulbs formed in laboratory pressure grouting tests. The reconstructed 3D mesh model of the sample provides accurate and detailed 3D vertex data, which allowed the volume, densification efficiency and bleeding behaviour of the grout bulbs to be analysed. Comparing the bulb section views at different grouting pressures also offers an intuitive observation of the grout development and propagation process. Moreover, the 3D vertex data and surface area included in the model are of great importance in validating numerical predictions of the pressure grouting process and analysing the interface shear resistance of grouted soil nails or anchors. Compared to existing approaches, the new 3D photogrammetry method possesses several key advantages: (a) it does not require expensive, specialized equipment; (b) samples are not destroyed or modified during testing; (c) it allows to reconstruct objects of various scales and (d) the software is public domain. Therefore, the adoption of this 3D photogrammetry method will facilitate research in the pressure grouting process and can be extended to other problems in geotechnical engineering.