Analysis of adobe wall composition at the Chaves‐Hummingbird Site,New Mexico,by diffuse reflectance spectrophotometry

This article investigates adobe wall construction materials utilized by prehistoric inhabitants of Chaves‐Hummingbird Pueblo, an ancestral Pueblo village located ˜20 miles west of Albuquerque, New Mexico. The walls were constructed with native clay‐rich soils some time between approximately 1275–1450 A.D. Samples were analyzed with a diffuse reflectance spectrophotometer from the near ultraviolet (NUV) through the visible (VIS) and into the near infrared (NIR) region of the electromagnetic spectrum. Cluster analysis of samples from 275 adobe walls and 36 soil locations surrounding the pueblo room blocks indicates four clusters. Comparison of typical samples from the four clusters indicates that they are very similar and are distinguished by minor variations in the three primary spectrally determined components, Na‐Ca montmorillonite, bentonite, and goethite. In general, clusters correspond with room construction episodes that are discernible through patterns of wall bonding and abutment recorded during the archaeological investigation of the site. This suggests that during different phases of construction the source of the wall adobe changed. Many of the soil samples are included in wall clusters and therefore reveal a potential source of material used for adobe, adjacent soils. However, not all the soil surrounding the pueblo grouped with wall clusters indicating a preference for certain soil types and that some soils were probably unsuitable for making adobe. Therefore, diversity in spectrally identified construction materials provides insights into source locations and possible construction preferences of the site inhabitants. © 2007 Wiley Periodicals, Inc.     

GROUND-WATER DISPERSION CALCULATIONS WITH A PROGRAMMABLE CALCULATOR

Abstract. A simple and convenient method for calculating two-dimensional dispersion on a TI 58 or 59 programmable calculator utilizing the normal distribution program available in the Solid State Software Master Library module as a subroutine is presented with an example.     

Evaluating the effect of the global ionospheric map on aiding retrieval of radio occultation electron density profiles

Radio occultation (RO) has been proven to be a powerful technique for ionospheric electron density profile (EDP) retrieval. The Abel inversion currently used in RO EDP retrieval has degraded performance in regions with large horizontal gradients because of an assumption of spherical symmetry as indicated by many studies. Some alternative methods have been proposed in the past; the global ionospheric map (GIM)-aided Abel inversion is most frequently studied. Since the number of RO observations will likely increase rapidly in the near future, it is worthwhile to continue to improve retrieval method. In this study, both the simulations and the real data test have been done to evaluate the GIM-aided Abel inversion method. It is found that the GIM-aided Abel inversion can significantly improve upon the standard Abel inversion in either the F or the E region if an accurate GIM is available. However, the current IGS GIM does not appear accurate enough to improve retrieval results significantly, because of the spherical symmetry assumption and sparse global navigation satellite system (GNSS) stations used in its creation. Generating accurate GIM based on dense GNSS network to aid the Abel inversion might be an alternative method.     

A new tool for evaluating the physics of coupled atmosphere�Cocean variability in nature and in general circulation models

Intermediate models of the coupled tropical atmosphere?Cocean system have been used to illuminate the physics of interannual climate phenomenon such as El Ni?o Southern Oscillation (ENSO) in the tropical Pacific and to explore how the tropics might respond to a forcing such as changing insolation (Milankovitch) or atmospheric carbon dioxide. Importantly, most of the intermediate models are constructed as anomaly models: models that evolve on a prescribed climatological mean state, which is typically prescribed and done so on a rather ad hoc basis. Here we show how the observed climatological mean state fields [ocean currents and upwelling, sea surface temperature (SST) and atmospheric surface winds] can be incorporated into a linearized intermediate model of the tropical coupled atmosphere?Cocean system: called Linear Ocean?CAtmosphere Model (LOAM), it is a linearized version of the Zebiak and Cane model. With realistic, seasonally varying mean state fields, we find that the essential physics of the ENSO mode is very similar to that in the original model and to that in the observations and that the observed mean fields support an ENSO mode that is stable to perturbations. Thus, our results provide further evidence that ENSO is generated and maintained by stochastic (uncoupled) perturbations. The method that we have outlined can be used to assimilate any set of ocean and atmosphere climatological data into the linearized atmosphere?Cocean model. In a companion paper, we apply this same method to incorporate mean field output from two global climate models into the linearised model. We use the latter to diagnose the physics of the leading coupled mode (ENSO) that is supported by the climate models, and to illuminate why the structure and variance in the ENSO mode changes in the models when they are forced by early Holocene and Last Glacial Maximum boundary conditions.     

Nitrogen uptake kinetics in the Ross Sea, Antarctica

The first estimates of uptake kinetic parameters for NH₄⁺, NO₃⁻, and urea in the Ross Sea, Antarctica were measured on three cruises during austral late winter–early spring 1996 (pre-bloom), late spring 1997 (bloom development), and summer 1997 (bloom decline). Nitrogen (N) uptake experiments were conducted with water collected at the 50% light penetration depth using trace-metal clean protocols and ¹⁵N tracer techniques. At all sites, ambient NO₃⁻ concentrations ranged from 5.8 to 30.5 μg-at N l⁻¹ and silicic acid concentrations were greater than 62.0 μg-at Si l⁻¹. The following trends were observed. First, based on maximum uptake rates (V_max), apparent N utilization followed the order NO₃⁻>NH₄⁺>urea during the pre-bloom and bloom development cruises. During the summer cruise, as the bloom was declining, the apparent order of utilization was NH₄⁺>NO₃⁻>urea. Second, evidence for possible repression of NO₃⁻ uptake by elevated NH₄⁺ concentrations was only observed at one site. Third, the kinetic parameters of NH₄⁺ uptake rates corrected for isotope dilution were compared with the kinetic parameters determined from uncorrected rates. In this comparison, the measure of substrate affinity, α (α=V_max/K_s) increased by an average of 4.6-fold when rates were corrected for isotope dilution, but values of V_max remained unchanged. Fourth, using bacterial production data, the magnitude of bacterial N uptake was estimated. Assuming that all bacterial N demands were met with NH₄⁺, the estimated bacterial portion of NH₄⁺ uptake ranged from <1%, when the ratio of bacteria to autotrophic biomass was low, to 35%, when bacterial abundance and biomass were highest. Finally, dramatic changes in NH₄⁺ uptake capacity were observed at one station (Stn. O), where kinetic parameters were measured during all three cruises. We hypothesize that a mutualistic relationship exists between phytoplankton and heterotrophic bacteria, and that the creation of microzones of high NH₄⁺ concentrations contributed to the changes seen at this station.     

Measurement of manganese, zinc and cadmium complexation in seawater using Chelex ion exchange equilibria

Equilibria between Chelex 100* and manganese, zinc and cadmium ions were used to determine the complexation of these trace metals in 36‰ Gulf Stream seawater at 25°C and pH 8.2. The method utilized radiotracers (⁵⁴Mn, ⁶⁵Zn, and ¹⁰⁹Cd) to quantify trace metal adsorption from trace metal-amended seawater and from seawater containing a series of ethylenediaminetetracetate (EDTA)—metal ion buffers. Results were consistent with Chelex adsorption of both trace metal ions and trace metal—EDTA chelates. Equilibrium models fitted to the data were used to establish conditional stability constants for Chelex adsorption of manganese, zinc and cadmium ions and for adsorption of EDTA-chelates. These models also yielded ratios of free metal ions to total dissolved trace metal concentrations in seawater: 10^−0.1 for manganese, 10^−0.2 for zinc, and 10^−1.5 for cadmium. Independent measurements with a cadmium ion-selective electrode also yielded a free: total cadmium ratio of 10^−1.5.     

Atmospheric absorption in the O2 Schumann-Runge band spectral range and photodissociation rates in the stratosphere and mesophere

A general analysis of the absorption of the Schumann-Runge bands of molecular oxygen has been made in order to compare the various experimental and theoretical results which have been obtained for an application to the O₂ atmospheric absorption and its photodissociation in the mesosphere and stratosphere. The different values of the oscillator strengths deduced from the laboratory absorption spectra and of the predissociation linewidths used for the calculation of the absorption have been compared.Calculations based on a Voight profile of the O₂ rotational lines have led to simple formulas for atmospheric applications taking into account that the total photodissociation rate in the stratosphere depends strongly on the absorption of solar radiation in the spectral range of the O₂ Herzberg continuum. Specific examples are given.     

Regional climate gradients in precipitation and temperature in response to climate teleconnections in the Greater Everglades ecosystem of South Florida

Precipitation and temperature in Florida responds to climate teleconnections from both the Pacific and Atlantic regions. In this region south of Lake Okeechobee, encompassing NWS Climate Divisions 5, 6, and 7, modern movement of surface waters are managed by the South Florida Water Management District and the US Army Corps of Engineers for flood control, water supply, and Everglades restoration within the constraints of the climatic variability of precipitation and evaporation. Despite relatively narrow, low-relief, but multi-purposed land separating the Atlantic Ocean from the Gulf of Mexico, South Florida has patterns of precipitation and temperature that vary substantially on spatial scales of 10¹–10² km. Here we explore statistically significant linkages to precipitation and temperature that vary seasonally and over small spatial scales with El Niño-Southern Oscillation (ENSO), the Atlantic Multidecadal Oscillation (AMO), and the Pacific Decadal Oscillation (PDO). Over the period from 1952 to 2005, ENSO teleconnections exhibited the strongest influence on seasonal precipitation. The Multivariate ENSO Index was positively correlated with winter (dry season) precipitation and explained up to 34 % of dry season precipitation variability along the southwest Florida coast. The AMO was the most influential of these teleconnections during the summer (wet season), with significant positive correlations to South Florida precipitation. These relationships with modern climate parameters have implications for paleoclimatological and paleoecological reconstructions, and future climate predictions from the Greater Everglades system.