Magmato-sedimentary Carboniferous to Jurassic evolution of the western Tauern window,Eastern Alps (constraints from U-Pb zircon dating and geochemistry)

New geochronological U-Pb (LA-ICP-MS) zircon data and geochemical analyses from the Variscan orthogneisses and metavolcanic rocks in the western Tauern window are presented and used to reconstruct the pre-Alpine evolution of this area. The late- and post-Variscan stage in the Tauern window was characterised by distinct magmatic pulses accompanied by the formation of volcano-sedimentary basins. The magmatic activity started in the Visean (335.4 ± 1.5 Ma) with the intrusion of a K-rich, durbachitic biotite-granite (protolith of the Ahorn gneiss). Following a period of exhumation and erosion, Westfalian–Stefanian volcanics were deposited (Grierkar meta-rhyodacite: 309.8 ± 1.5 Ma; Venntal meta-rhyolite: 304.0 ± 3.0 Ma). A renewed magmatic pulse occurred in the Early Permian, producing large volumes of tonalites and granodiorites (Tux meta-granodiorite: 292.1 ± 1.9 Ma). The youngest magmatism is characterised by pyroclastic and tuffitic deposits (Pfitsch meta-rhyolite: 280.5 ± 2.6 Ma; Schönach valley meta-andesite: 279.0 ± 4.8 Ma). This volcanism was probably related to crustal extensional faulting within an intra-continental graben and horst setting, asthenospheric upwelling and heat flow increase due to the onset of the Permian rifting. The Permo-Triassic peneplanation and subsidence is documented by shallow marine and evaporitic deposits. Probably in the Middle Jurassic times, the area was flooded and in the Late Jurassic the whole area was covered by limestones, representing post-rift sediments on the southern European continental margin.     

Intercalation of kaolinite with acetamide

Upon intercalation of both ordered (low defect) and disordered (high defect) kaolinites with acetamide, two types of interaction are observed. Firstly, hydrogen bonding between the NH₂ groups of the acetamide with the siloxane oxygens is formed, as evidenced by the formation of two new bands at 3400 and 3509 cm^–1. Secondly, the appearance of additional bands at ∼3600 cm^–1 in both the infrared and Raman spectra of the acetamide intercalates is attributed to a second type of hydrogen bonding by the interaction of the C=O group and the inner surface hydroxyls. Changes in the intensity of the hydroxyl deformation modes in the 895 to 940 cm^–1 region are attributed to the changes in the hydrogen bonding of the kaolinite surfaces. It is proposed that the hydrogen bonding between the adjacent kaolinite layers is replaced with hydrogen bonding between both kaolinite surfaces and the acetamide molecule. Changes in the molecular structure of acetamide are observed upon intercalation. The amide 1 band is lost and replaced with a well-defined NH₂ deformation vibration. The loss of the amide 1 band is attributed the hydrogen bond formation between the amide hydrogens and the siloxane surface. The bands of the C=O group at 1680 and 1740 cm^–1 become a single band at 1680 cm^–1. The amide 2 band remains unchanged. The lack of intensity of the 1740 cm^–1 band is attributed to the formation of hydrogen bonding between the inner surface hydroxyl groups and the carbonyl group. Received: 4 February 1998/ Revised, accepted: 30 June 1998     

Nicht senkrechte Schwingungsrichtungen bei der U-Tisch-Betrachtung von Calcit-Körnern

Deviation of the extinction positions from 90° regarding calcite grains at the universal stage.     

Biot dispersion for P‐ and S‐wave velocities in partially and fully saturated sandstones

Ultrasonic compressional‐ and shear‐wave velocities have been measured on 34 samples of sandstones from hydrocarbon reservoirs. The sandstones are all of low clay content, high porosity, and cover a wide range of permeabilities. They were measured dry and brine‐saturated under hydrostatic effective stresses of 10, 20 and 40 MPa. For eight of the sandstones, ultrasonic velocity measurements were made at different partial water saturations in the range from dry to fully saturated. The Gassmann–Biot theory is found to account for most of the changes in velocities at high effective stress levels when the dry sandstones are fully saturated with brine, provided the lower velocities resulting when the dry sandstone initially adsorbs small amounts of moisture are used to determine the elastic properties of the ‘dry’ sandstone. At lower effective stress levels, local flow phenomena due to the presence of open microcracks are assumed to be responsible for measured velocities higher than those predicted by the theory. The partial saturation results are modelled fairly closely by the Gassmann–Biot theory, assuming heterogeneous saturation for P‐waves.     

Process‐based modeling of kilometer‐scale alongshore sandbar variability

Subtidal nearshore sandbars may exhibit cyclic net offshore migration during their multi‐annual lifetime along many sandy coasts. Although this type of behavior can extend continuously for several kilometers, alongshore variations in cross‐shore bar position and bar amplitude are commonly observed. Alongshore variability is greatest when bars display km‐scale disruptions, indicative of a distinct alongshore phase shift in the bar cycle. An outer bar is then attached to an inner bar, forming a phenomenon known as a bar switch. Here, we investigate such large‐scale alongshore variability using a process‐based numerical profile model and observations at 24 transects along a 6 km section of the barred beach at Noordwijk, The Netherlands. When alongshore variability is limited, the model predicts that the bars migrate offshore at approximately the same rate (i.e. the bars remain in phase). Only under specific bar configurations with high wave‐energy levels is an increase in the alongshore variability predicted. This suggests that cross‐shore processes may trigger a switch in the case of specific antecedent morphological configurations combined with storm conditions. It is expected that three‐dimensional (3D) flow patterns augment the alongshore variability in such instances. In contrast to the observed bar behaviour, predicted bar morphologies on either side of a switch remain in different phases, even though the bars are occasionally located at a similar cross‐shore position. In short, the 1D model is not able to remove a bar switch. This data‐model mismatch suggests that 3D flow patterns are key to the dissipation of bar switches. Copyright © 2014 John Wiley & Sons, Ltd.     

Multi‐year water balance assessment of a newly constructed wetland,Fort McMurray,Alberta

Oil sands mining in Alberta transforms the boreal landscape of forests and wetlands into open pits, tailings ponds and overburden piles. Whereas reclamation efforts have primarily focused on upland forests, rebuilding wetland systems has recently become a motivation for research. Wetland creation and sustainability in this region is complicated by the sub‐humid climate and salinity of underlying mining material. In 2012, Syncrude Canada Ltd. completed the construction of the Sandhill Fen Watershed (SFW), a 52‐ha upland‐wetland system to evaluate wetland reclamation strategies on soft tailings. SFW includes an active pumping system, upland hummocks, a fen wetland and underdrains. To evaluate the influence of management practices on the hydrology of the system, this study reports the water balance from January 2013 to December 2014, the first 2 years after commissioning. A semi‐distributed approach was taken to examine the fluxes and stores of water in uplands and lowlands. Natural and artificial inputs and outputs were measured using a series of precipitation gauges and pumps, and evapotranspiration was quantified using three eddy covariance towers. A series of near surface wells recorded water table position. Both 2013 and 2014 were normal rainfall years, with 2013 having more and 2014 less snow than normal. In 2013, inflow/outflow from pumping was the predominant hydrological fluxes, resulting in considerable variability in water table position and storage changes throughout the summer. In 2014, the artificial addition of water was negligible, yet the water table remained near the surface in lowland locations, suggesting that wetland conditions could be maintained under current conditions. Evapotranspiration rates between uplands and lowlands were similar between years and sites, ranging from 2.2 ± 1.8 to 2.5 ± 1.2 mm/day and were largely controlled by climate. These rates were less than nearby older upland systems, suggesting that water balance partitioning will change as vegetation develops. Comparison between years and with natural systems provides insight on how management practices influence hydrologic dynamics and the overall water balance of the SFW. Copyright © 2016 John Wiley & Sons, Ltd.