Diffusive mass exchange of non‐reactive substances in dual‐porosity porous systems – column experiments under saturated conditions

Diffusive mass exchange into immobile water regions within heterogeneous porous aquifers influences the fate of solutes. The percentage of immobile water is often unidentified in natural aquifers though. Hence, the mathematical prediction of solute transport in such heterogeneous aquifers remains challenging. The objective of this study was to find a simple analytical model approach that allows quantifying properties of mobile and immobile water regions and the portion of immobile water in a porous system. Therefore, the Single Fissure Dispersion Model (SFDM), which takes into account diffusive mass exchange between mobile and immobile water zones, was applied to model transport in well‐defined saturated dual‐porosity column experiments. Direct and indirect model validation was performed by running experiments at different flow velocities and using conservative tracer with different molecular diffusion coefficients. In another column setup, immobile water regions were randomly distributed to test the model applicability and to determine the portion of immobile water. In all setups, the tracer concentration curves showed differences in normalized maximum peak concentration, tailing and mass recovery according to their diffusion coefficients. These findings were more pronounced at lower flow rates (larger flow times) indicating the dependency of diffusive mass exchange into immobile water regions on tracers' molecular diffusion coefficients. The SFDM simulated all data with high model efficiency. Successful model validation supported the physical meaning of fitted model parameters. This study showed that the SFDM, developed for fissured aquifers, is applicable in porous media and can be used to determine porosity and volume of regions with immobile water. Copyright © 2015 John Wiley & Sons, Ltd.     

Energy partitioning over a semi‐arid shrubland in northern China

During the last decade, the widely distributed shrublands in northern China have shown significant signs of recovery from desertification, the result of widespread conservation practices. However, to support the current efforts in conservation, more knowledge is needed on surface energy partitioning and its biophysical controls. Using eddy‐covariance measurements made over a semi‐arid shrubland in northwest China in 2012, we examined how surface energy‐balance components vary on diurnal and seasonal scales, and how biophysical factors control bulk surface parameters and energy exchange. Sensible heat flux (H) exceeded latent heat flux (λE) during most of the year, resulting in an annual Bowen ratio (β, i.e. H/λE) of 2.0. λE exceeded H only in mid‐summer when frequent rainfall co‐occurred with the seasonal peak in leaf area index (LAI). Evapotranspiration reached a daily maximum of 3.3 mm day^?1, and summed to 283 mm yr^?1. The evaporative fraction (EF, i.e. λE/R_n), Priestley–Taylor coefficient (α), surface conductance (g_s) and decoupling coefficient (Ω) were all positively correlated with soil water content (SWC) and LAI. The direct enhancement of λE by high vapour pressure deficit (VPD) was buffered by a concurrent suppression of g_s. The g_s played a direct role in controlling EF and α by mediating the effects of LAI, SWC and VPD. Our results highlight the importance of adaptive plant responses to water scarcity in regulating ecosystem energy partitioning, and suggest an important role for revegetation in the reversal of desertification in semi‐arid areas. Copyright © 2015 John Wiley & Sons, Ltd.     

Deep massive sulphide exploration using 2D and 3D geoelectrical and induced polarization data in Skellefte mining district,northern Sweden

Geoelectrical and induced polarization data from measurements along three profiles and from one 3D survey are acquired and processed in the central Skellefte District, northern Sweden. The data were collected during two field campaigns in 2009 and 2010 in order to delineate the structures related to volcanogenic massive sulphide deposits and to model lithological contacts down to a maximum depth of 1.5 km. The 2009 data were inverted previously, and their joint interpretation with potential field data indicated several anomalous zones. The 2010 data not only provide additional information from greater depths compared with the 2009 data but also cover a larger surface area. Several high‐chargeability low‐resistivity zones, interpreted as possible massive sulphide mineralization and associated hydrothermal alteration, are revealed. The 3D survey data provide a detailed high‐resolution image of the top ～450 m of the upper crust around the Maurliden East, North, and Central deposits. Several anomalies are interpreted as new potential prospects in the Maurliden area, which are mainly concentrated in the central conductive zone. In addition, the contact relationship between the major geological units, e.g., the contact between the Skellefte Group and the Jörn Intrusive Complex, is better understood with the help of 2010 deep‐resistivity/chargeability data. The bottommost part of the Vargfors basin is imaged using the 2010 geoelectrical and induced polarization data down to ～1‐km depth.     

Geologie zwischen Cañete-San Juan 13‡ 00′-15‡ 24′ Südperu

The Peruvian coastal belt between Cañete and San Juan includes three geological units: The Coastal Cordillera on the west, the foothills of the High Sierra on the east, and the Para-Andean trough in between. Igneous, sedimentary and metamorphic rocks form a sequence ranging in age from Paleozoic (or Pre-Cambrian?) to Cenozoic, with various gaps. The area lies in a mobile belt, which was folded in late Paleozoic, Jurassic (Nevadian), and upper Cretaceous times. Further tectonic activity, involving warping and block faulting, occurred in the late Tertiary, and suggests an approach to cratonic conditions. Tectonic events were accompanied by emplacement of magmatic suites. There is no evidence for a Pacific landmass.     

The contribution of scattering to near-surface attenuation

The rapid decrease of the acceleration spectral amplitude at high frequencies has widely been modeled by the spectral decay factor kappa (κ). Usually, the path-corrected component of κ, often called κ₀, is believed to be a local and frequency-independent site characteristic, in turn representing attenuation related to waves propagating vertically through the very shallow layers beneath the study site. Despite the known relevance of κ₀ in a wide range of seismological applications, most methods for its calculation do not fully consider the influence of the scattering component. To account for the scattering component, we present a summary of statistical observations of the seismic wavefield at sites of the Swiss seismic networks. The intrinsic properties of the wavefield show a clear dependency on the local shallow subsoil conditions with differences in the structural heterogeneity of the shallow subsoil layers producing different scattering regimes. Such deviations from the ballistic behavior (i.e., direct waves that sample only distinct directions) are indicative for local structural heterogeneities and the associated level of scatter. Albeit the attenuation term related to scattering depends nonlinearly on the intrinsic term, the results indicate that the commonly used explanation for the high-frequency decay spectrum might not be appropriate but involving the amount of scattering might allow better constrained estimates of κ₀.     

Untersuchungen über die Trübungsverhältnisse,die Durchsichtigkeit und die Wasserfarbe in schweizerischen Gewässern

Zusammenfassung Im ersten, der Festlegung der theoretischen Grundlagen der Trübung gewidmeten Kapitel wird die Sinkgeschwindigkeit kleiner Teilchen auf Grund der Gesetze der ?Schwebetheorie? vonWesenberg-Lund, W. Ostwald sowie der Stokesschen Formel diskutiert. Ein weiteres Kapitel orientiert anhand bisheriger Kenntnisse über die Erscheinungen der Lichtdurchl?ssigkeit (bzw.-absorption) und des Lichtklimas in verschiedenen Tiefen unserer Seen. Die Trübung der in einer Reihe von Flu?systemen und Seen erhobenen W?sser wurde mittels der absoluten Messung im Pulfrich-Stufenphotometer festgestellt. Sodann wurden die analysierten Proben nach steigenden Trübungswerten geordnet und unterteilt in ?Klarseen?, ?mitteltrübe? und ?trübe? Seen. Schliesslich wurde zusammen mitH. Züllig der Grad der Trübung, der Transparenz und die Seefarbe zueinander in Beziehung gebracht, wobei unterschieden wird zwischen Seen, die a) durch vorwiegend anorganische Stoffe, b) durch vorwiegendOscillatoria-armes Plankton, c) durch vorwiegendOscillatoria rubescens getrübt sind. Die in mehreren Tabellen und Abbildungen wiedergegebenen Werte der Wassertrübung spiegeln die unterschiedlichen Verh?ltnisse wider, die sich im Laufe einer ausgedehnteren Flu?strecke oder in einem See ergeben aus der Mischung des verschieden stark mit Schwebestoffen belasteten Wassers von Haupt- und Nebenfluss, sodann aus der fortschreitenden oder von Strecke zu Strecke wechselnden Sedimentation, und natürlich auch von der lokalen oder regionalen Wetterlage (Niederschl?ge und Schneeschmelze). In ausgedehnten und zum Teil über Monate hinweg durchgeführten Sedimentationsversuchen im Laboratorium wurde schliesslich der Kl?rvorgang von W?ssern verschiedener Herkunft in Funktion der Zeit untersucht. Dabei ergaben sich unterschiedliche Kurven, die ein Bild zu vermitteln verm?gen über den mittleren Durchmesser der die Trübung verursachenden sedimentierbaren, anorganischen Partikeln.     

MELIMEX,an experimental heavy metal pollution study: Effects of increased heavy metal load on uptake of glucose by natural planctonic communities

Glucose uptake in lake water samples has been determined with short-time¹⁴C-experiments at different additions of the single heavy metals Cu⁺⁺, Zn⁺⁺, Cd⁺⁺, Pb⁺⁺, Hg⁺⁺ and at different additions of a combination of all metals. The degree of a metal induced inhibition of glucose uptake varied from lake to lake and from season to season, whereby the addition of legally tolerated concentrations of 10 μg Cu/l and 200 μg Zn/l inhibited glucose uptake in most samples significantly, as well as the simultaneous addition of all metals. The legally tolerated limit of 1 μg Hg/l inhibited glucose uptake in Lake Lucerne samples almost completely, showed however no effect in samples of Lake Baldegg. The equimolar toxicity sequence of heavy metals for heterotrophic microorganisms has been determined as: Hg>Cu>Cd>(Zn. Pb). Glucose uptake of plankton sampled from metal polluted limno-corrals was less inhibited than that of the control plankton, when heavy metals were added to the samples singly or in combination. It is assumed that this effect is due to the natural selection of more resistant plankton species.     

Rates of sulfur dioxide and particle emissions from White Island volcano,New Zealand,and an estimate of the total flux of major gaseous species

Airborne correlation spectrometry (COSPEC) was used to measure the rate of SO₂ emission at White Island on three dates, i.e., November 1983, 1230 ± 300 t/d; November 1984, 320 ± 120 t/d; and January 1985, 350 ± 150 t/d (t = metric tons). The lower emission rates are likely to reflect the long-term emission rates, whereas the November 1983 rate probably reflects conditions prior to the eruption of December 1983. The particle flux in the White Island plume, as determined with a quartz crystal microbalance/cascade in November 1983, was 1.3 t/d, unusually low for volcanic plumes. The observed plume particles, as shown from scanning electron microscopy, include halite, native sulfur, and silicates and are broadly similar to other volcanic plumes.Gas analyses from high-temperature volcanic fumaroles collected from June 1982 through November 1984 werde used together with the COSPEC data to estimate the flux of other gas species from White Island. The rates estimated are indicative of the long-term volcanic emission, i.e., 8000–9000 t/d H₂O, 900–1000 t/d CO₂, 70–80 t/d HCl, 1.5–2 t/d HF, and about 0.2 t/d NH₃. The long-term thermal power output at White Island is estimated at about 400 MW.     

Natural shock behavior of almandite in metamorphic rocks from the ries crater,Germany

An extensive study of a big number of gneiss specimens with various shock features from the suevite allowed unravelling of the shock behavior of almandite garnets.Almandites in shocked metamorphic rocks show with increasing dynamic pressures strong irregular fracturing. differently oriented sets of planar fractures or elements, brown turbidity and nucleation of minute crystals of an unknown phase in solid garnets. At higher peak pressures garnet was found to break down to (1) orthopyroxene + spinel + glass, and to (2) spinel + glass due to fast shock-melting.Extensive quantitative electron microprobe studies of almandite garnets and their breakdown products were carried out. The breakdown products within the original grain boundaries of the garnets consist of an alumina-rich orthopyroxene (with up to 10 wt. % Al₂O₃), hercynite to pleonaste spinels and a silica and calcium-rich glass matrix. The chemical zonation of magnesium and manganese of the former garnets is inherited in the composition of the newly formed orthopyroxenes.Petrographic evidence and chemical composition suggest a fast breakdown of the almandite garnets after passing of shock waves at rapidly falling pressures and very high post-shock temperatures within the ejected gneissic rock material.