Devensian Late-glacial environmental change in the Gordano Valley, North Somerset, England: a rare archive for southwest Britain

The Late-glacial and Holocene environmental history of the Gordano Valley, North Somerset, UK has been reconstructed using pollen, sediment particle size and mineralogical analyses and radiocarbon dating. A Devensian sediment ridge across the valley confined the waters of a small lake, within which the initial sedimentation was minerogenic. Radiocarbon dating of overlying organic-rich deposits suggests that this began late in the Dimlington Stadial c. 18,000–15,000 Cal. BP. Petrographic analyses indicate the minerogenic sediments were partly wind-blown in origin. Climatic amelioration during the Windermere Interstadial c. 15,000 Cal. BP encouraged a shift from minerogenic to biogenic sedimentation. A brief return to minerogenic sedimentation between c. 10,400 and c. 9,520 Cal. BP was followed by uninterrupted fen peat accumulation throughout the Holocene. The later minerogenic horizon appears to represent the Loch Lomond Stadial. Few stratigraphic sequences preserving the complete Devensian Late-glacial–Holocene transition exist in southwest Britain, making the sedimentary archive of the Gordano Valley valuable regionally for reconstructing Late-glacial climate change.     

Modeling spatiotemporal pattern of agriculture‐feasible land in China

This study applies a spatial fuzzy multi‐criteria evaluation model to determine agricultural feasibility in China based on physical variables (accumulated temperature, sunshine, precipitation, hydrology, elevation and soil properties). The resulting agricultural feasibility index layer is combined with nightlight images (1992‐2013) to determine the spatiotemporal variation of urban encroachment on feasible agriculture land. It reveals the severity of agricultural land losses to urbanization.     

Learning with Local Help: Expanding the Dialogue on Climate Change and Water Management in the Okanagan Region, British Columbia, Canada

The research activity described in this report is a comprehensive regional assessment of the impacts of climate change on water resources and options for adaptation in the Okanagan Basin. The ultimate goal of the project is to develop integrated climate change and water resource scenarios to stimulate a multistakeholder discussion on the implications of climate change for water management in the region. The paper describes two main objectives: (a) providing a set of research products that will be of relevance to regional interests in the Okanagan, and (b) establishing a methodology for participatory integrated assessment of regional climate change impacts and adaptation that could be applied to climate-related concerns in Canada and other countries. This collaborative study has relied on field research, computer-based models, and dialogue exercises to generate an assessment of future implications, and to learn about regional views on the prospects for adaptation. Along the way, it has benefited from strong partnerships with governments, researchers, local water practitioners, and user groups. Building on the scenario-based study components, and a series of interviews and surveys undertaken for the water management and adaptation case study components, a set of stakeholder dialogue sessions were organized which focused on identifying preferred adaptation options and processes for their implementation. Rather than seeking consensus on the “best” option or process, regional interests were asked to consider a range of available options as part of an adaptation portfolio that could address both supply side and demand side aspects of water resources management in the Okanagan. The Canadian Crown reserves the right to retain a non-exclusive, royalty free licence in and to any copyright.     

Controls on spatial variability in snow accumulation on glaciers in the Southern Alps,New Zealand; as revealed by crevasse stratigraphy

Net accumulation measurements from two glaciers located on opposite sides of the New Zealand Southern Alps were used to explore processes controlling spatial variability. The degree of variability, as measured by the spatial variogram, differed in each of the three successive years, but the lowest variance occurred on both glaciers in March 2008, after a hot and dry summer. Strong relationships between net accumulation and elevation within the accumulation area were only found on Franz Josef Glacier (FJG), despite this being the primary control used in glacier mass balance modelling. Interaction between wind and topography was found to be important to the distribution of net accumulation on both glaciers. The crevasse stratigraphy method is an ideal way to gain good spatial coverage of net accumulation, and particularly suited to glaciers with high annual precipitation. Copyright © 2010 John Wiley & Sons, Ltd.     

Origin of xenoliths in the trachyte at Puu Waawaa,Hualalai Volcano,Hawaii

Rare dunite and 2-pyroxene gabbro xenoliths occur in banded trachyte at Puu Waawaa on Hualalai Volcano, Hawaii. Mineral compositions suggest that these xenoliths formed as cumulates of tholeiitic basalt at shallow depth in a subcaldera magma reservoir. Subsequently, the minerals in the xenoliths underwent subsolidus reequilibration that particularly affected chromite compositions by decreasing their Mg numbers. In addition, olivine lost CaO and plagioclase lost MgO and Fe₂O₃ during subsolidus reequilibration. The xenoliths also reacted with the host trachyte to form secondary mica, amphibole, and orthopyroxene, and to further modify the compositions of some olivine, clinopyroxene, and spinel grains. The reaction products indicate that the host trachyte melt was hydrous. Clinopyroxene in one dunite sample and olivine in most dunite samples have undergone partial melting, apparently in response to addition of water to the xenolith. These xenoliths do not contain CO₂ fluid inclusions, so common in xenoliths from other localities on Hualalai, which suggests that CO₂ was introduced from alkalic basalt magma between the time CO₂-inclusion-free xenoliths erupted at 106±6 ka and the time CO₂-inclusion-rich xenoliths erupted within the last 15 ka.     

A history of violence: magma incubation,timing and tephra distribution of the Los Chocoyos supereruption (Atitlán Caldera,Guatemala)

The climactic Los Chocoyos (LCY) eruption from Atitlán caldera (Guatemala) is a key chronostratigraphic marker for the Quaternary period given the extensive distribution of its deposits that reached both the Pacific and Atlantic Oceans. Despite LCY tephra being an important marker horizon, a radioisotopic age for this eruption has remained elusive. Using zircon (U–Th)/He geochronology, we present the first radioisotopically determined eruption age for the LCY of 75 ± 2 ka. Additionally, the youngest zircon crystallization ²³⁸U–²³⁰Th rim ages in their respective samples constrain eruption age maxima for two other tephra units that erupted from Atitlán caldera, W-Fall (130 ⁺¹⁶/₋₁₄ ka) and I-Fall eruptions (56 ^+8.2/_−7.7 ka), which under- and overlie LCY tephra, respectively. Moreover, rim and interior zircon dating and glass chemistry suggest that before eruption silicic magma was stored for >80 kyr, with magma accumulation peaking within ca. 35 kyr before the LCY eruption during which the system may have developed into a vertically zoned magma chamber. Based on an updated distribution of LCY pyroclastic deposits, a new conservatively estimated volume of ~1220 ± 150 km³ is obtained (volcanic explosivity index VEI > 8), which confirms the LCY eruption as the first-ever recognized supereruption in Central America.     

Formation of CO2 on a carbonaceous surface: a quantum chemical study

The formation of CO₂ in the gas phase and on a polyaromatic hydrocarbon surface (coronene) via three possible pathways is investigated with density functional theory. Calculations show that the coronene surface catalyses the formation of CO₂ on model grain surfaces. The addition of ³O to CO is activated by 2530 K in the gas phase. This barrier is lowered by 253 K for the Eley–Rideal mechanism and 952 K for the hot-atom mechanism on the surface of coronene. Alternative pathways for the formation of CO₂ are the addition of ³O to the HCO radical, followed by dissociation of the HCO₂ intermediate. The O + HCO addition is barrierless in the gas phase and on the surface and is more than sufficiently exothermic to subsequently cleave the H–C bond. The third mechanism, OH + CO addition followed by H removal from the energized HOCO intermediate, has a gas-phase exit barrier that is 1160 K lower than the entrance barrier. On the coronene surface, however, both barriers are almost equal. Because the HOCO intermediate can also be stabilized by energy dissipation to the surface, it is anticipated that for the surface reaction the adsorbed HOCO could be a long-lived intermediate. In this case, the stabilized HOCO intermediate could react, in a barrierless manner, with a hydrogen atom to form H₂+ CO₂, HCO₂H, or H₂O + CO.