The effects of soil sand contents on characteristics of humic acids along soil profiles

It is generally accepted that the compositions and properties of soil organic matter (SOM) are influenced by many factors. In order to reveal the effects of soil texture on characteristics and dynamics of SOM and its sub-fraction, humic acid (HA), along two soil profiles, a yellow soil profile and a purplish soil profile, under the same climate and vegetation conditions were determined. Results indicate that the decomposition and humification degrees of SOM and HA of the purplish soils are higher than those of the corresponding yellow soils indicated by A/O–A ratios of HAs, TOCs and HA yields of bulk soil samples, nevertheless, the development degree of the purplish soil is lower than that of the yellow soil. The variations of E₄/E₆ ratios of HAs along the soil profiles indicate the overall molecular sizes of HAs decreased downward along the soil profiles. A/O–A ratios of HAs decreased downward along both the soil profiles indicate that humification processes decrease downward along both the soil profiles. Leaching of SOM shows significant effects on the distribution and characteristics of HAs in the yellow soil profile but the purplish soil profile, which is consistent with the higher hydrophobicity of HAs in purplish soils, shows that the distribution characteristics of SOM along the soil profiles are a complex result of the combination of soil texture and characteristics of SOM itself. The remarkably different sand contents are concluded tentatively as one of reasons to the different distributions and dynamics of HAs along the soil profiles, however, to profoundly understand the evolution and transport of SOM along soil profiles needs more researches.     

The Influence of Chlorine on the Determination of Combined Water: An Investigation of a Correction Procedure

Differential thermal analysis, pH determination and ion chromatography were used to investigate the interference of chlorine in the determination of combined water (H₂O⁺) by the Penfield tube gravimetric method. The magnitude of the chlorine interference was quantified and a correction method was proposed to obtain accurate results for H₂O⁺. The method was applied to the determination of H₂O⁺ in deep sea sediments containing chlorine and certified reference materials of oceanic polymetallic nodules.     

桥梁气象专题研究与服务

根据实际开展的桥梁气象专题研究，分析桥梁气象研究与服务如何面对国内大型桥梁建设发展趋势所带来的机遇和挑战，提出开展桥梁气象研究与服务的必要性，并从桥位气候背景、桥位气象参数取值、桥梁气象研究方法以及桥梁施工及营运期气象服务与保障等方面介绍桥梁气象专题研究及服务应开展的主要内容，同时，给出一个已投入实际使用的桥梁施工期气象环境监测与预警系统的建设思路。     

多普勒雷达基本观测量直接同化对模式物理量场的影响

在GRAPES一3DVar雷达同化模块的基础上,建立了多普勒径向速度和基本反射率因子的直接同化观测算子,实现了雷达反射率因子和径向速度的直接同化,并对2007年7月3日的江淮梅雨进行了模拟试验。结果表明,多普勒径向速度的直接同化的主要影响表现在风场上,能够改善几乎整个三维风场分析,在雷达影响半径范围内,风场明显得到加强,影响当时天气的系统及其高低层配置被合理模拟,但对湿度场影响甚微。雨水混合比的直接同化的主要影响表现在湿度场上,改进了模式对湿度场的模拟,对降水的影响十分显著,有利于准确模拟降水的发展和维持,减小了Spin—up现象;其亦可使整个风场微弱增强,但影响甚微。     

The characteristics of ultraviolet radiation in arid and semi-arid regions of China

Measurements of the broadband global solar radiation (R _S) and total ultraviolet radiation (the sum of UV-A and UV-B) were conducted from 2005 to 2010 at 9 sites in arid and semi-arid regions of China. These data were used to determine the temporal variability of UV and UV/R _S and their dependence on the water vapor content and clearness index. The dependence of UV/R _S on aerosol optical depth (AOD) and water vapor content was also investigated. In addition, a simple and efficient empirically model suited for all-weather conditions was developed to estimate UV from R _s. The annual average daily UV level in arid and semi-arid areas is 0.61 and 0.59 MJ m^?2 d^?1, respectively. The highest value (0.66?±?0.25 MJ m^?2 d^?1) was recorded at an arid area at Linze. The lowest value (0.53?±?0.22 MJ m^?2 d^?1) was recorded at a semi-arid area at Ansai. The highest daily value of UV radiation was measured in May, whereas the lowest value was measured in December. The monthly variation of the UV/R _s ratio ranged from 0.41 in Aksu to 0.35 in Qira. The monthly mean value of UV/R _s gradually increased from November and then decreased in August. A small decreasing trend of UV/R _s was observed in the arid and semi-arid regions due to recently increasing amounts of fine aerosol. A simple and efficient empirically model suit for all-weather condition was developed to estimate UV from R _s. The slope a and intercept b of the regression line between the estimated and measured values were close to 1 and zero, respectively. The relative error between the estimated and measured values was less than 11.5%. Application of the model to data collected from different locations in this region also resulted in reasonable estimates of UV.     

东胜区污染状况分析

文章利用东胜区主要污染源排放情况以及2005年9月1日-2007年8月31日每日SO2、NO2、PM10浓度监测值和2005-2007年SO2、NO2、PM10平均值,分析了东胜区主要污染类型、污染物来源以及东胜区近3年SO2、NO2、PM10监测值日、月、季、年分布特征和变化规律;提出了消减大气污染物排放的对策。     

风应力的旋转和辐散分量在ENSO循环中作用的数值试验研究

将 1 960～ 1 991年的月平均 FSU风应力资料分解为旋转部分和辐散辐合部分 ,分别用以强迫模式海洋。所用的模式为一个 2层热带太平洋区域海洋模式。结果表明 ,就季节变化而言 ,不论是用旋转分量还是散合分量强迫海洋 ,都不能产生合理的冷舌 ,哪怕将旋转或散合分量放大一倍或缩小二分之一 ,也不能使冷舌的强度和分布得到合理的改善。若采用气候平均的含有季节变化的风应力 (未对旋转和辐散分量进行分离 ) ,则可产生与实际相符的海表温度分布。在此基础上 ,分别叠加旋转和辐散分量的年际异常部分 ,通过对海洋的强迫 ,可产生海表温度异常。在年际异常旋转分量的强迫下 ,可产生较强的 SSTA振荡且具有明显的 ENSO周期 ;而在辐散辐合年际异常风应力的强迫下 ,则产生较弱的 SSTA,且振荡频率较高 ,ENSO周期不很明显。这些结果说明 ,风应力的涡旋和辐散辐合分量在海温季节变化和年际变化的形成中具有不同的作用 ,即合理的冷舌分布需要风应力旋转分量和散合分量同时作用于海洋方可产生 ,而仅有异常风应力的旋转强迫就可产生合理的 EL Nino/ La Nina现象。同时 ,风应力的辐散辐合分量在海洋平均状态的形成过程中是重要的 ,但在 EN-SO过程中就对海洋的作用而言则不如旋转分量重要。     

Characteristics of dry-wet abrupt alternation events in the middle and lower reaches of the Yangtze River Basin and the relationship with ENSO

During recent decades, more frequent flood-drought alternations have been seen in China as a result of global climate change and intensive human activities, which have significant implications on water and food security. To better identify the characteristics of flood-drought alternations, we proposed a modified dry-wet abrupt alternation index (DWAAI) and applied the new method in the middle and lower reaches of the Yangtze River Basin (YRB-ML) to analyze the long-term spatio-temporal characteristics of dry-wet abrupt alternation (DWAA) events based on the daily precipitation observations at 75 rainfall stations in summer from 1960 to 2015. We found that the DWAA events have been spreading in the study area with higher frequency and intensity since 1960. In particular, the DWAA events mainly occurred in May and June in the northwest of the YRB-ML, including Hanjiang River Basin, the middle reaches of the YRB, north of Dongting Lake and northwest of Poyang Lake. In addition, we also analyzed the impact of El Niño Southern Oscillation (ENSO) on DWAA events in the YRB-ML. The results showed that around 41.04% of DWAA events occurred during the declining stages of La Niña or within the subsequent 8 months after La Niña, which implies that La Niña events could be predictive signals of DWAA events. Besides, significant negative correlations have been found between the modified DWAAI values of all the rainfall stations and the sea surface temperature anomalies in the Nino3.4 region within the 6 months prior to the DWAA events, particularly for the Poyang Lake watershed and the middle reaches of the YRB. This study has significant implications on the flood and drought control and water resources management in the YRB-ML under the challenge of future climate change.     

微X射线束荧光扫描成份分析研究：元素二维分布图

经过改进的微X射线扫描分析装置,扩大了测量范围;提高了位移精度;处理数据及绘制二维(平面)元素分布图实现计算机化。测量并绘制出大洋锰结核中多元素平面分布图。     

水中氯代烃单体碳同位素分析中预富集方法进展

高精度准确测定氯代烃单体碳同位素对示踪污染物来源,了解污染物的生物降解过程具有重要意义。在环境转化过程中,有机污染物的同位素组成可能是稳定不变的,也有可能发生改变。若污染物的同位素组成在迁移转化过程中不变,根据其同位素组成可以示踪污染物的来源;若同位素组成变化,根据同位素分馏结果,可以评价环境中有机污染物降解发生的可能性和程度。本文综述了固相微萃取、静态顶空进样、吹扫-捕集、多级串联技术等前处理方法与气相色谱-燃烧-同位素比值质谱仪(GC-C-IRMS)联用分析水中氯代烃单体碳同位素的研究进展,比较了分析方法的优缺点。液-液萃取较少用于水中氯代烃的单体同位素分析。静态顶空进样、固相微萃取、吹扫-捕集都是无溶剂富集技术,与GC-C-IRMS联用分析水中氯代烃单体同位素过程中不存在或存在小且恒定的可校正的同位素分馏,分析精度一般优于1‰,没有二次污染,降低了杂质干扰,提高了GC-C-IRMS的分辨率和分析精度,降低了检测限。从静态顶空进样、固相微萃取、吹扫-捕集,到多级串联等技术与GC-C-IRMS联用分析水中氯代烃单体同位素比值,检测限逐渐降低。目前,吹扫-捕集-GC-C-IRMS在分析水中氯代烃中应用最广泛,重现性好、检测限低。针内微萃取、管内微萃取、搅动棒吸附萃取和顶空进样吸附萃取等前处理方法与GC-C-IRMS仪联用具有一定的应用前景。