Kinetics and Equilibrium Sorption Studies of 4-Nitrophenol on pyrolyzed and activated oil shale residue

Sorption of the organic pollutant 4-nitrophenol (4-NP) by pyrolyzed and activated Jordanian oil-shale was studied. Pyrolyzed oil shale was prepared using a fluidized bed reactor at 520 °C in the presence of nitrogen. Physical activation was carried out by treating the pyrolyzed oil shale with CO₂ at 830 °C, while chemical activation was achieved by using KOH and ZnCl₂ as impregnating agents. Batch kinetics and isotherm studies were conducted to evaluate the sorption process. Effects of contact time, initial sorbate concentration, sorbent concentration, temperature, pH and inorganic salts (NaCl and KCl) on the sorption process by the different sorbents were considered. Chemically activated oil shale, pretreated with ZnCl₂, gave the highest uptake of 4-NP. The isotherm experimental data fit reasonably well to Langmuir, Freundlich and Redlich-Paterson models. Three kinetic models, namely the Morris-Weber, Lagergren, and Pseudo-Second-Order model (PSOM), were applied to represent the experimental results for both pyrolyzed and ZnCl₂-oil shale sorbents.     

西藏甲玛-卡军果推-滑覆构造系特征

通过矿区填图和路线调查,结合室内研究,指出:①甲玛-卡军果推-滑覆构造系由印度-欧亚板块碰撞引发,具有递进变形、自盆地中心向边部推覆、新盖老等特点,强变形于50Ma±。②推覆体下盘为叶巴组构造岩系;推覆体由上侏罗统和下白垩统碳酸盐-碎屑沉积岩系构成,主体为轴面北倾的复式褶皱,自南而北分为前部带、中部带和后部带。滑覆构造系推覆形成的复背斜轴部高位岩块失稳向北滑覆形成,自南而北分为后部带、中部带和前部带。③导致矿区蚀变的主要岩浆活动发生于推覆强变形后的松弛期,上侵受近南北向基底断裂和推覆断裂联合控制,就位受控于前部带推-滑覆褶断系,其后发生多次构造-岩浆-成矿液叠加,造就甲玛铜多金属矿床。     

Comparative Planetary Space Physics

It has been 60 years since the space physics as new branch of geophysics started to grow in 1957 when the space age was opened by a small satellite called sputnik. The knowledge of Earth and planetary space has been significantly extended and deepened, but the questions we are facing today are more challenging. A consensus reached is that we have to regard the Earth (planet) as an integrated system including all spheres from the inner core to the magnetosphere, and we should try to investigate some questions standing on the ground of interdisciplinary study, especially those questions related to Earth’s (planetary) evolution. Space environment as the outer part of a planetary system, commonly exists in all planets but also exhibits strong diversity. Here, we introduce the short history of basic ideas and methods of comparative study, the advantages on understanding of some issues of global scale, and the prospect from comparative perspective.     

毕节煤矿区晚二叠世煤层稀土元素的物质来源

对取自毕节地区晚二叠世11个可采煤层的13个样品的稀土元素(REE)的物质来源进行分析。发现:海洋来源对稀土元素的富集作用极其微弱;来自植物成因的物质来源小于1%;煤样中δEu负异常,而陆源岩具有Eu负异常的特点。结合晚二叠世多期喷发的峨眉山玄武岩,因此认为稀土元素的物质来源主要受陆源影响和控制。     

西藏当雄地区拉屋矿床磁黄铁矿Re-Os同位素测年 和成矿物质来源示踪

拉屋矿床位于西藏自治区当雄县境内,大地构造位置处于冈底斯成矿区申扎-旁多铜、银、铅、锌、金成矿带,为大型矽卡岩型铜铅多金属矿床。在系统研究拉屋矿床地质地球化学特征的基础上,以矿石的磁黄铁矿为对象,测定Re-Os同位素年龄,获得等时线年龄数据为(309±31)Ma,187Os/188Os的初始值为0.51±0.12,γOs值为306.90~880.29,Re/Os为20.46~80.46。上述结果,结合矿区野外地质特征和稳定同位素特征,证明拉屋矿床主要形成于晚石炭世来故期,其成矿物质来源于地幔,并在喷流过程中与地壳海底卤水汇合,遭受了壳源物质的混染,形成喷流成因矽卡岩型矿床。     

气象应用平台WebGIS产品测试

中国气象局气象探测中心正在开发建设综合气象观测系统运行监控平台(ASOM:Atmospheric Observing systern Operations Monitoring),平台中部分功能采用webGIS技术实现.为了选择相对较好的WebGIS运行支撑平台,对当前主流的3个WebGIS产品进行了测试.从分析气象应...     

长江、黄河大洪水前期地球系统演变的分析

通过分析江、淮、黄、海四大洪共１４个大洪水年的前期地震场特征,发现大洪水前在青藏高原东南地区、亚欧中纬地带和台湾以东洋面三处的有强地震发生,若强震出现在中印缅热点则对应着江淮大小;强震出现在川青甘地区则对应着黄海河大水。引发大水的直接原因是本地区地热涡的强烈发展,它因刚好位于数组”同向等距地热涡族”的相交点上,交相干共振的结果,文中详细分析了１９５４和１９８２年两个个例。最后分析了“中印缅热点”的     

东北冷涡引发的局地暴雨数值模拟研究

利用CDAS-NCEP/NCAR 再分析资料,应用Penn State/NCAR的高分辨率中尺度模式MM5V3-7,成功模拟出2005年7月9—12日东北冷涡诱发的一次连续雷雨过程,重点分析了7月9日造成沈阳及周边地区的一次局地暴雨过程,并对其中的一个连续发展的中β尺度对流系统的演变、中尺度结构特点进行了研究。结果表明：冷涡总是以水平旋转的中高层的干冷空气堆作为其结构特点。在冷涡的东南侧高空干冷堆的边缘区域,轨迹呈直立状,从行星边界层向上穿越整个对流层,显示出该地区存在强对流。干冷堆的边缘区域下方的低层暖湿输送是冷涡局地强对流发展的关键。局地对流发展时,出现干冷堆的边缘区域的S_e上下层接近或者打通现象。