NaCl—H_2O溶液包裹体的密度式和等容式及其应用

由于含盐类包裹体不能应用现有的状态方程求解,作者根据实验数值,采用最小二乘法等,得到含盐度(wt%)≤25的NaCl-H_2O溶液包裹体的密度式和等容式。只要测定出包裹体的均一温度和含盐度,代入密度式,即可计算包裹体中的流体密度。再由此密度、含盐度的等容式,进一步可求得包裹体的形成温度和压力。最后,作者列举了三个实例。     

黑龙江省漠河县富源沟林场含电气石花岗岩的形成时代及地质意义

本文对额尔古纳地块北段的富源沟林场含电气石花岗岩体进行了LA-ICP-MS锆石U-Pb同位素定年和岩石地球化学研究。含电气石花岗岩的锆石206Pb/238U年龄加权平均值为458±4 Ma（MSWD = 1.8）,表明含电气石花岗岩形成于晚奥陶世初期。岩石地球化学特征表明该花岗岩应为高钾钙碱性系列（K2O = 3.45%～4.83%）,铝饱和指数A/CNK＞1.1（1.11～1.28）,属强过铝质的S型花岗岩,富集Th、U、Rb、K等元素,相对亏损Sr、Ba、 Nb、Ti、 P、Eu等元素,是同碰撞构造背景下地壳部分熔融的产物。结合前人研究资料和本文数据提出,富源沟林场含电气石花岗岩的形成与额尔古纳地块和兴安地块的碰撞拼贴有关,形成于额尔古纳地块与兴安地块碰撞拼贴作用所引发的碰撞构造背景,由于地缘因素,构造岩浆作用滞后于额尔古纳地块东缘的碰撞拼贴时限,是额尔古纳地块和兴安地块碰撞拼贴的远程效应。     

Thermodynamic modeling of binary CH4-H2O fluid inclusions

This work reports the application of thermodynamic models, including equations of state, to binary (salt-free) CH₄-H₂O fluid inclusions. A general method is presented to calculate the compositions of CH₄-H₂O inclusions using the phase volume fractions and dissolution temperatures of CH₄ hydrate. To calculate the homogenization pressures and isolines of the CH₄-H₂O inclusions, an improved activity-fugacity model is developed to predict the vapor-liquid phase equilibrium. The phase equilibrium model can predict methane solubility in the liquid phase and water content in the vapor phase from 273 to 623 K and from 1 to 1000 bar (up to 2000 bar for the liquid phase), within or close to experimental uncertainties. Compared to reliable experimental phase equilibrium data, the average deviation of the water content in the vapor phase and methane solubility in the liquid phase is 4.29% and 3.63%, respectively. In the near-critical region, the predicted composition deviations increase to over 10%. The vapor-liquid phase equilibrium model together with the updated volumetric model of homogenous (single-phase) CH₄-H₂O fluid mixtures (Mao S., Duan Z., Hu J. and Zhang D. (2010) A model for single-phase PVTx properties of CO₂-CH₄-C₂H₆-N₂-H₂O-NaCl fluid mixtures from 273 to 1273 K and from 1 to 5000 bar. Chem. Geol.275, 148-160), is applied to calculate the isolines, homogenization pressures, homogenization volumes, and isochores at specified homogenization temperatures and compositions. Online calculation is on the website: http://www.geochem-model.org/.     

武汉市汤逊湖沉积物重金属垂向变化的磁响应特征及环境意义

对武汉汤逊湖湖泊沉积物T06-1样芯进行了磁性测量、重金属分析和粒度分析,探讨了利用磁参数追踪、指示城市湖泊重金属污染的可行性。结果表明,低矫顽力的亚铁磁矿物主导了沉积物的磁性特征。磁参数,SIRM和ARM与重金属Cr,Zn,Cu和Pb呈现较为一致的垂向变化特征:55cm之下,磁参数值和重金属的含量均较低且稳定;在50~10cm之间,两者基本呈现随深度的减小而增加的趋势,其中在20~10cm区间,出现小范围内波动;而10cm至表层,元素含量和磁参数值随深度减小而急剧增加。选取粘土(（4μm）对沉积物中Cr,Zn,Cu和Pb进行粒度校正的结果显示:校正后元素的变化趋向于平稳,但在表层的10cm处Cr,Pb,Zn和Cu的含量仍然较高,表明了表层沉积物中金属元素的含量主要受人类活动的影响。相关分析也表明了磁参数X1,SIRM和ARM与重金属Cr,Pb,Zn和Cu之间均呈显著相关关系（0.62≤R≤0.86）,表明磁参数可以用于追踪和指示汤逊湖湖泊沉积物重金属污染。     

扬子陆块庙湾蛇绿岩中橄榄岩的同位素年代学及其构造意义

扬子陆核崆岭高级变质地体内出露一套强变形的基性-超基性岩岩石组合, 主要呈似层状、透镜状分布于崆岭群中, 该套变基性-超基性岩组合对扬子陆块早期构造演化过程具有重要意义.通过同位素稀释法(isotope dilution thermal ionization mass spectrometry, 简称ID-TIMS)获得该套岩石组合中蛇纹石化方辉橄榄岩全岩Sm-Nd等时线年龄为1063±12Ma, 说明Sm-Nd同位素体系可用于对超低含量、发生强蚀变作用的超基性岩样品进行定年.样品Nd同位素组成相对均一(ε_Nd(t)值为6.90~7.32), 表明形成于封闭体系中, 其对应Nd同位素两阶段模式年龄为1.13~1.09Ga, 与形成年龄接近, 说明来自亏损软流圈地幔部分熔融.结合区域上已有的中元古代末期到新元古代早期构造岩浆事件研究, 认为在该时期扬子陆块可能由多个微陆块组成, 就扬子陆核而言, 其与扬子陆块西侧之间很可能存在分隔的大洋.      

甘肃龙首山岩带西井镁铁质岩体成因及其构造意义

西井岩体位于北祁连造山带以北,阿拉善地块西南缘的龙首山隆起带。以往的研究多以沿龙首山断裂分布的镁铁-超镁铁质岩带作为和金川岩体相关的岩浆事件进行,而本次选择西井镁铁质岩体进行了精确的地质年代学和地球化学研究,确定了西井岩体岩性主要为橄榄辉石岩和辉长岩,成岩时代为 (421.0±9.0) Ma,可以和北祁连高压变质带榴辉岩年龄相对应;ε_Nd(t)为4.06~5.52,(⁸⁷Sr/⁸⁶Sr)_i为0.704 548~0.707 575,具有地幔岩石圈特征;微量元素及其同位素计算表明西井岩体经历了约10%的下地壳物质混染。据此得出西井岩体及其龙首山岩带早志留世镁铁质侵入岩体成因模式为:祁连洋壳连续俯冲过程中洋壳与陆壳分离,热的软流圈物质持续冲击地幔岩石圈的底部;由于热传导效应,大地热流沿着地幔岩石圈上升,使得80 km深度的湿的橄榄岩层发生熔融,产生玄武质岩浆作用,玄武质岩浆上升过程中与下地壳物质发生约10%混染,形成西井岩体及其龙首山镁铁超镁铁质岩带。     

Distributions of n-alkanes and their hydrogen isotopic composition in plants from Lake Qinghai (China) and the surrounding area

Various aquatic plants from Lake Qinghai, the largest inland saline lake in China, and terrestrial plants from the surrounding area were investigated for the distribution of n-alkanes and their δD values. The n-alkanes in the samples range from C₁₅ to C₃₃ with C preference index (CPI) values of 4.0–29.7. The n-C₂₃ or n-C₂₅ alkane is the dominant compound in the aquatic submerged plants. The aquatic emergent and terrestrial plants have an abundance maximum at n-C₂₇, n-C₂₉ or n-C₃₁. The average chain length (ACL) values, ranging from 26.0 to 29.6, are closely related to the plant species. The n-alkanes from the aquatic plants have mean δD values of −169‰ to −121‰ and those from the terrestrial plants values of −173‰ to −109‰. The H isotopic composition (δD) and fractionation differ significantly among the plants studied. Comparison shows that additional evaporative enrichment of the lake water associated with saline lakes and humidity influence the δD values of the n-alkanes in aquatic and terrestrial plants, respectively. The mean δD values of n-alkanes in the plants decrease with increasing ACL value. The n-alkanes from the different types of plants are more depleted in D relative to environmental water and those from aquatic plants (with a mean value of −143‰) have a greater isotopic fractionation than terrestrial plants (mean value −113‰).     

近40年湖南洪涝灾害的演变趋势及其成因

利用湖南５２个代表站１９５８￣１９９８年４￣９月的降水资料,确定了洪涝年,分析了近４０年湖南洪涝的特征和演变趋势。在此基础上,探讨了近期洪涝灾害日益严重的原因。它们是：气候背景因素,大气环流异常,厄尔尼诺的影响,洞庭湖的水文特性和面积锐减,社会因素。     

NUMERICAL STUDY ON THE EFFECTS OF SEA SURFACE TEMPERATURE ON TROPICAL CYCLONE INTENSITY-PART I:NUMERICAL EXPERIMENT OF THE TROPICAL CYCLONE INTENSITY RELATED TO SST Duan Yihong;Qin Zenghao;Gu dianfeng;Li Yongping, Shanghai Typhoon Institute.Shangh

In the context of a model of tropical cyclone intensity based on an improved meso-scaleatmospheric model, numerical simulation is performed of the track and intensity variation oftropical cyclones (TC) arising from sea surface temperature (SST) variation over a specified searegion. Evidence suggests that the model is capable of modeling quite welt the track and intensityof TC: SST variation leads to an abrupt change in the cyclone intensity: the response of thecyclone to the abrupt SST change lasts 8—12 h.