陕西地洞河高分辨率石笋记录的DO18季风增强事件

千年尺度事件的结构特征和区域响应是理解和认识冰期气候变化及动力机制的关键。本文基于陕西汉中宁强县地洞河一支长417 mm石笋DDH1的11个U-Th年代和417个氧同位素（δ¹⁸O）数据,重建了末次冰期（64.8~33.2 ka B.P.）亚洲季风演化历史。石笋δ¹⁸O记录在64.7±0.2 ka B.P.和59.3±0.1 ka B.P.快速负偏,分别指示了DO18事件的开始和H6事件的结束。在DO18事件结束过程,石笋δ¹⁸O记录在64.0~60.4 ka B.P.持续正偏,振幅达2.9 ‰,反应季风逐渐减弱,但未出现明显转型阶段。其总体形态与大西洋Cariaco盆地岩芯反射率、南极冰芯的记录较为一致,但是不同于格陵兰冰芯的记录。因地洞河所处青藏高原、秦岭叠加影响的区域,纬度和地形的双重影响使得其石笋δ¹⁸O记录较其他地区偏负,振荡幅度更大。因地形阻挡了高纬信号,使得低纬甚至南半球的信号突现出来,ITCZ的移动、南半球温度和水汽潜热的释放作用在这一区域尤为显著。

     

末次冰盛期东亚夏季风变化的重庆石笋记录

基于重庆小山岩洞XSY1石笋的5个²³⁰Th年龄和582个氧同位素数据,重建了23134~19345 a B.P.期间分辨率约6.5 a的东亚夏季风变化历史。此石笋δ¹⁸O记录的长期趋势逐渐负偏,在其上叠加了一系列千年-百年尺度季风振荡,呈现为4谷3峰的结构形态。重庆XSY1和南京MSD石笋δ¹⁸O记录在数百年尺度的反相关系表明冰盛期时东亚大陆东部水汽并非来自印度洋。与北高纬记录对比显示东亚季风的增强与减弱基本对应格陵兰温度的升高与降低时期,暗示在冰量最大时期东亚季风与北高纬气候仍密切联系。此外,XSY1的δ¹⁸O与冰芯¹⁰Be通量亦存在明显的对应关系,表明太阳活动对东亚季风的调控作用受冰量边界条件影响较小。功率谱分析结果显示出1011 a、722 a、460 a、337 a和163 a的周期,与太阳活动周期相近,进一步确认太阳活动对东亚季风的驱动作用。石笋XSY1与澳大利亚石笋MC-S2 δ¹⁸O记录在千年尺度呈反相位变化,表明冰盛期时东亚季风与全球其他气候系统的动力联系。

     

湖北永兴洞降水对2015年厄尔尼诺的响应

通过对湖北永兴洞为期3年（2013年6月至2016年7月）的地表降水δ¹⁸O观测,发现该地点降水δ¹⁸O在2015夏季显著偏正。利用HYSPLIT后向轨迹方法对永兴洞降水水汽来源进行分析,结果表明在厄尔尼诺事件的影响下2015年夏季来自远源印度洋的水汽显著减少,而近源太平洋水汽相对增多,即降水δ¹⁸O因"环流效应"而偏正。本研究提供的观测证据表明永兴洞石笋δ¹⁸O记录在重建ENSO主导下的亚洲季风大气环流方面具有重要潜力。

     

Geochemistry of rare-earth elements in shallow groundwater,northeastern Guangdong Province,China

Shallow groundwater and hot springs were collected from northeastern Guangdong Province, Southeast China, to determine the concentrations and fractionation patterns of rare-earth elements(REE). The results show that the La, Ce and Nd of REEs are abundant in groundwater and rock samples, and the ∑REE contents in groundwater and rock samples range from 126.5 to 2875.3 ng/L, and 79.44 to 385.85 mg/L, respectively. The shallow groundwater has slightly HREE-enriched PAAS-normalized patterns. However, the granitic rocks PAAS-normalized patterns, with remarkable negative Eu anomalies, are different from that of shallow groundwater. The enrichment of HREE is considered to be controlled by REE complexation and readsorption for most groundwater has Ce and Eu positive anomalies. The Ce and Eu anomalies in groundwater are controlled by redox conditions. Moreover, the Fe-contain sediments dissolution and/or the reduction of Fe oxyhydroxides are another factor contributing to Ce anomalies. The Eu anomalies in groundwater are controlled by the preferential mobilization of Eu2+ during water-rock interaction compared to Eu3+.     

Determination of trace and rare-earth elements in Chinese soil and clay reference materials by ICP-MS

Inductively coupled plasma mass spectrometry(ICP-MS) has become a powerful tool for providing reliable analytical results in many laboratories around the word. In this study, the mixture of HF and HNO3 acids in high-temperature and high-pressure closed-vessel digestion technique were used to decompose some Chinese reference materials, and thirty seven elements were determined by ICP-MS. Most of the results for Chinese soil reference materials were found to be in reasonable agreement with the reference values, except Cs, Ta, Li, Ge, Zn, Nd, Tb and Ta whose values need to be revised. Their precisions were typically lower than 5% RSD. However, the Precisions of Chinese clay reference materials, especially for GBW03102 and GBW03102a, were significantly different with reference values, probably reflecting the existence of a coarser-grained fraction(70 μm) in samples, and the formation of fluorides in Al-rich samples during sample decomposition by using the mixture of HF and HNO3 acids. Moreover, thirty-seven trace elements covering the mass range from Li to U in four Chinese clay reference materials were firstly provided with good precision and accuracy in this study.     

Evaluation of adsorption potential of bamboo biochar for metal-complex dye: equilibrium,kinetics and artificial neural network modeling

Metal-complex dyes are widely used in textile industry, but harmful to the environment and human health due to aromatic structure and heavy metal ions. The objective of this work was to evaluate the adsorption potential of bamboo biochar for the removal of metal-complex dye acid black 172 from solutions. Freundlich model was more suitable for the adsorption process of bamboo biochar than Langmuir isotherm, indicating multilayer adsorption of acid black 172 on a heterogeneous bamboo biochar surface. Adsorption kinetics analysis of pseudo-second-order and Weber–Morris models revealed that intraparticle transport was not the only rate-limiting step. The bamboo biochar exhibited a good adsorption performance even at high ionic strength. Analysis based on the artificial neural network indicated that the temperature with a relative importance of 29 % appeared to be the most influential parameter in the adsorption process for dye removal, followed by time, ionic strength, pH and dye concentration.     

水热条件下黄铁矿片、板状晶体的微结构

利用透射电子显微镜(TEM)系统观测了黄铁矿片、板状晶体的微结构,发现在水热条件下生成的黄铁矿片、板状晶体具有正方形、矩形等多种形貌。其中,正方形较多,矩形次之,另可见到一些其他不规则形状。黄铁矿片、板状晶生长完好,未见缺陷。经测定多数四边形片状黄铁矿的两组边分别平行(010)和(100),其生长晶面为(001);个别四边形片状黄铁矿的两组边分别平行(010)和(101),其生长晶面为(101),矩形片状黄铁矿长轴生长方向为001。在水热条件下黄铁矿以多形貌出现,黄铁矿的片、板状晶体多数是沿(001)面生长的结果,(001)为黄铁矿片、板状晶体的主要二维生长面,并沿001方向扩展,构成了二维晶体。     

地震多属性拟测井多参数反演预测煤层顶底板岩石赋水性研究

通过实例介绍利用地震多属性与测井成果联合反演,获得表征煤层顶底板岩石赋水性强弱的拟测井参数体,进而对其进行赋水性分析：首先利用伽马-伽马测井及视电阻率曲线重构岩石视孔隙度曲线,以获得研究区岩石视孔隙度成果;利用测井成果合成地震记录进行精细的地震地质层位标定及采区地震数据的保幅、保真处理;在测井成果约束下进行地震多属性拟测井多参数反演,利用反演成果的高低异常区评价煤层顶底板赋水强弱分区——低波阻抗、低电阻率、高孔隙度分布的区域对应赋水性强的区域,反之为赋水性弱的区域。     

胶东西北部地区金矿床铅同位素特征及其地质意义

胶东地区不同类型金银、铅锌矿床及交代—深熔花岗岩三者的铅同位素特征相似,皆为来自铀针亏损型源区的多阶段铅。在Pb~(207)/Pb~(204)-Pb~(206)/Pb~(204)图解上,它们的投影点可拟合成一条直线。据此,并根据大量的K-Ar、U-Pb、Rb-Sr和Ar~(30)-Ar~(40)年龄数据,得t_1=3.2Ga,t_2=0.15Ga,μ_1=7.07～8.17,W_1=29.16～35.80,Th/U=3.97～4.52。矿石铅与胶东群变质岩岩石铅同位素统计对比表明,金银、铅锌和交代—深熔花岗岩中的铅皆来自再活化的下地壳源铅。     

Thermal impact of waste emplacement and surface cooling associated with geologic disposal of high-level nuclear waste

This article is a study of the thermal effects associated with the emplacement of aged radioactive high-level wastes in a geologic repository, with emphasis on the following subjects: waste characteristics, repository structure, and rock properties controlling the thermally induced effects; thermal, thermomechanical, and thermohydrologic impacts, determined mainly on the basis of previous studies that assume 10-yr-old wastes; thermal criteria used to determine the repository waste loading densities; and technical advantages and disadvantages of surface cooling of the wastes prior to disposal as a means of mitigating the thermal impacts. Waste loading densities determined by repository designs for 10-yr-old wastes are extended to older wastes using the near-field thermomechanical criteria based on room stability considerations. Also discussed are the effects of long surface cooling periods determined on the basis of far-field thermomechanical and thermohydrologic considerations. Extension of the surface cooling period from 10 yr to longer periods can lower the near-field thermal impact but have only modest long-term effects for spent fuel. More significant long-term effects can be achieved by surface cooling of reprocessed high-level waste.