Chemical structural units of macromolecular coal components

Chemical degradations of coal resins, coal asphaltenes and coal residues have been performed with selective, non-oxidative reagents. The coal comprise samples a rank interval 0.30–1.21 %R_m. Degraded low-molecular-weight compounds were analyzed by GC-MS. The distributions of pentacyclic terpanes, isoprenoids, n-alkanes, acids and alcohols obtained as degradation products illustrate a considerable variability between the macromolecular coal fractions. A structural study on the molecular level of the degraded compounds from coal resins and coal asphaltenes show their potential to generate hydrocarbons during coalification process.     

Structure and origin of terpenoid hydrocarbons in some German coals

Hydrocarbon extracts of coal samples from major coal fields in West Germany have been investigated by gas chromatography-mass spectrometry (GC/MS). The samples are of Carboniferous and Tertiary age and derive from limnic and paralic environments, the Saar District, the Ruhr Area and the Lower Rhine Basin.Differences in facies, maturity and age reflected in the distribution patterns of the extracted alkylcyclohexanes. An unexpected occurrence of cyclic diterpenoid hydrocarbons in some samples of Carboniferous age has been found. The tetracyclic compounds mainly show phyllocladane type structures and can serve as source indicators.Hydrocarbons obtained from chemical degradation of the macromolecular material of the samples also revealed phyllocladane-type compounds which are normally associated to resins of modern and extinct familes of conifers. Origin and structural variations of this class of hydrocarbons are discussed in terms of maturity and palaeobotanical implications.     

The accessibility of nodes in the Belgian road network

This paper presents an analysis of the accessibility of nodes in the Belgian road network. The intersection of roads are considered as the nodes and their connecting roads as the edges of a network. By means of the Dijkstra algorithm accessibility values are computed for each node by summing shortest travel times to a reference system of 158 nodes spread evenly over the Belgian territory. A comparison of the measured actual accessibility with that determined from an optimal situation provides an indication of the quality of directness of the Belgian road system. Accessibility and directness are shown cartographically. An isochronal map illustrates the access to Brussels.     

Factors influencing the salinity regime of Lake Pontchartrain,Lousiana, a shallow coastal lagoon: Analysis of a long-term data set

Lake Pontchartrain., Louisiana is a 1,630 km² shallow brackish lagoon with a mean salinity from 1.2‰ in the west to 5.4‰ in the east., The construction of a 120 km long deep-water connection to the Gulf of Mexico in 1963, was expected to cause a 5‰ increase in lagoon salinity. However, the actual increase was everywhere in the lagoon less than 2‰ Analysis of 31 years of daily salinity and discharge records indicates that discharge is the most important factor controlling salinity variations in Lake Pontchartrain., Seventy-four percent of low-frequency salinity variations are explained by freshwater discharge and the completion of the deep-water canal. Lake Pont.-chartrain experiences annual variations of salinity as high as 8‰ This salinity signal has remained constant since the beginning of the salinity records in 1946. It appears that the deep-water canal is not responsible for observed die-back of freshwater swamps and retreat of lagoon shorelines.     

The Application of Telemetry to Large-Scale Horizontal Anisotropic Permeability Determinations by Surface Tiltmeter Survey

An advanced two-way radio link (transceiver units) and data logging system have provided a powerful means of real-time series data collection and analysis. The application of this telemetry system to surface tiltmeter surveys provides significant cost savings for testing and analysis of deep, large-scale horizontal anisotropic permeability and heterogeneity determinations.
The determination of horizontal anisotropic properties requires one pumping well and eight to 10 tiltmeter monitoring stations. The validity of the depth of the test may reach 4,000 feet below land surface. With the addition of one partially penetrating observation well, the entire three-dimensional anisotropic permeability can be determined. With the addition of a fully penetrating well, the storage coefficient can be determined as well as leakage property (including vertical permeability of the confining layers). An example test case was analyzed for horizontal anisotropic permeability with remarkable success despite relatively unfavorable detection conditions.
A thorough understanding of the geology overlying the aquifer system must be made in order to assess the applicability of the surface tiltmeter survey to large-scale horizontal anisotropic permeability determinations.     

Lower Cretaceous turbiditic sediments from the Rif chain (Northern Marocco) — palynology,stratigraphy and palaeogeographic setting

The paper describes the palynology, stratigraphy, sedimentology and palaeogeographic setting of Lower Cretaceous turbiditic and terrigenous deep-sea sediments at the Tethyan margins of Africa and Alboran (External Domain of the Rif, and Flysch Nappes). During the Early Cretaceous terrigenous turbiditic deep-water sedimentation characterizes two different palaeogeographic domains in the southern part of the western Tethys:

In the northern area of the External Domain (Ketama Unit of the Rif) alternating turbiditic arenites and pelites are interpreted as sediments of a distal part of a fan system on the Tethyan margin of Africa. The main sources for the terrigenous material were situated in Central and Western Algeria; only little sand transited through the Prerif and the Mesorif zones of Morocco. The terrigenous sedimentation began in the Hauterivian, but the main turbiditic cycles are of Aptian to Lower and Middle Albian age.

The Flysch Domain probably was situated far to the Northeast with respect to the Rif basin, at the western and southern margins of the Alboran microplate. Relatively proximal turbidites form most of the Tisirène Nappe, whereas more distal turbidites constitute the series of the Melloussa and the Chouamat Nappes. The existence of two different source areas is demonstrated, one to the NE and the other to the NW of the depositional area. The turbidites probably were deposited on a E-W oriented fan system which progradated into a longitudinal trench-like trough. In the Central Rif area, the Tisirène Flysch is of Valanginian to Albian (pre-Vraconian) age. In the Western Rif and in the Melloussa and Chouamat Nappes of the whole area no sediments older than Aptian have been found.

The stratigraphy of the investigated series is based on a new tentative palynostratigraphic zonation, using pollen, spores and dinoflagellate cysts. Rich and well preserved assemblages have been found in the Western Rif only, whereas the samples of the Tisirène Nappe and the Chouamat Nappe in the Central and Eastern Rif have been affected by some thermal alteration. Black and mostly opaque palynomorphs from the Ketama Unit reflect the strong thermal influence in the External Domain of the Central and Eastern Rif.     

Long-term erosion on granitic roadcuts based on exposed tree roots

Exposed roots were used to estimate soil and bedrock erosion on the cut slopes of a 45-year-old road constructed in granitic soils of the Idaho Batholith. The original roadcut surface was defined by projecting a straight line from the toe of the cut past the end of the exposed root to the intersection of a straight line projected along the surface of the hillslope. A cross-sectioning technique was then used to determine erosion to the present roadcut surface. A total of 41 exposed root sites were used to estimate erosion on a 1350 m-long section of road. Average erosion was 1·0 and 1·1 cm/year for soil and bedrock respectively. Buttressing by tree roots caused lower erosion rates for soil as compared to bedrock. Both soil and bedrock erosion rates showed statistically significant correlations with the gradients of the original cut slope. The bedrock erosion data provide a reasonable estimate of the disintegration rate of exposed granitic bedrock exhibiting the weathering and fracturing properties common to this area. The road is located in a study watershed where long-term sediment yield data are available. Sediment data from adjacent study watersheds with no roads were compared to sediment data from the roaded watershed to estimate the long-term increase in sediment yield caused by the road. The increase amounts to about 2·4 m³/year. This figure, compared to the average annual on-site road erosion, provides an erosion to sediment delivery ratio of less than 10 per cent. Based on study results, road construction and maintenance practices are suggested for helping reduce roadcut erosion.