Die Gliederung des Rotliegenden und die Stellung seiner Vulkanite am Südwestrand des Frankenwaldes

Zusammenfassung Auswirkungen der saalischen Phase sind nun auch im Stockheimer Becken erstmals festgestellt. In der Hauptsache ist in diesem Gebiet jedoch mit orogenetischen Bewegungen im Unterrotliegenden selbst zu rechnen. — Der Vulkanismus entwickelte sich im Becken bzw. an seinen Rändern vermutlich bereits im jüngsten Oberkarbon (1. Phase, am stärksten ausgebildet) und hält dann im Unterrotliegenden an (2. Phase, evtl. noch Gehrener Stufe). Aus dem mittleren Rotliegenden sind bisher nur Porphyr-Fanglomerate angeführt worden. Allerdings muß berücksichtigt werden, daß deren Neubearbeitung noch nicht abgeschlossen ist und das Stockheimer Becken ohnehin nur einen kleinen Ausschnitt aus der Gesamtentwicklung am Südwestrand des Frankenwaldes darstellt. Mit einem Vulkanismus im mittleren Rotliegenden (3. Phase, ? Goldlauterer Stufe) ist demnach auch hier noch zu rechnen.     

Die Bedeutung der Isotopenforschung für die Geologie

Ohne Zusammenfassung     

Die kristallographischen Konstanten Yon Löweit

Zusammenfassung Künstlich hergestellter Löweit kristallisiert trigonal in kleinen Rhomboedern. Die Gitterkonstanten für die hexagonale Zelle sind:a = 18,96 Å,c = 13,47 Å. Die systematischen Auslöschungen führen auf die Raumgruppe R 3 oder R 3. Der Zellinhalt wird diskutiert.     

Sulfide Oxidation across Diffuse Flow Zones of Hydrothermal Vents

The sulfide (H₂S/HS^?) that is emitted from hydrothermal vents begins to oxidize abiotically with oxygen upon contact with ambient bottom water, but the reaction kinetics are slow. Here, using in situ voltammetry, we report detection of the intermediate sulfur oxidation products polysulfides [ $ {\text{S}}_{\text{x}}^{2 - } $ ] and thiosulfate [ $ {\text{S}}_{ 2} {\text{O}}_{ 3}^{ 2- } $ ], along with contextual data on sulfide, oxygen, and temperature. At Lau Basin in 2006, thiosulfate was identified in less than one percent of approximately 10,500 scans and no polysulfides were detected. Only five percent of 11,000 voltammetric scans taken at four vent sites at Lau Basin in May 2009 show either thiosulfate or polysulfides. These in situ data indicate that abiotic sulfide oxidation does not readily occur as H₂S contacts oxic bottom waters. Calculated abiotic potential sulfide oxidation rates are <10^?3 ??M/min and are consistent with slow oxidation and the observed lack of sulfur oxidation intermediates. It is known that the thermodynamics for the first electron transfer step for sulfide and oxygen during sulfide oxidation in these systems are unfavorable, and that the kinetics for two electron transfers are not rapid. Here, we suggest that different metal catalyzed and/or biotic reaction pathways can readily produce sulfur oxidation intermediates. Via shipboard high-pressure incubation experiments, we show that snails with chemosynthetic endosymbionts do release polysulfides and may be responsible for our field observations of polysulfides.     

Geodesic polygons on surfaces of revolution

This paper presents a way for computing geodesic polygons on real surfaces of revolution with partly continuous curvature and gives an application to coordinate transformations in geodesic coordinate systems. The specific formulas for an ellipsoid of revolution are briefly mentioned.     

Chemical Mechanism Development: Laboratory Studies and Model Applications

Within the German Tropospheric Research Programme (TFS) numerous kinetic and mechanistic studies on the tropospheric reaction/degradation of the following reactants were carried out: oxygenated VOC, aromatic VOC, biogenic VOC, short-lived intermediates, such as alkoxy and alkylperoxy radicals.At the conception of the projects these selected groups were classes of VOC or intermediates for which the atmospheric oxidation mechanisms were either poorly characterised or totally unknown. The motivation for these studies was the attainment of significant improvements in our understanding of the atmospheric chemical oxidation processes of these compounds, particularly with respect to their involvement in photooxidant formation in the troposphere. In the present paper the types of experimental investigations performed and the results obtained within the various projects are briefly summarised. The major achievements are highlighted and discussed in terms of their contribution to improving our understanding of the chemical processes controlling photosmog formation in the troposphere.     

Mean and Turbulent Flow Statistics in a Trellised Agricultural Canopy

Flow physics is investigated in a two-dimensional trellised agricultural canopy to examine that architecture’s unique signature on turbulent transport. Analysis of meteorological data from an Oregon vineyard demonstrates that the canopy strongly influences the flow by channelling the mean flow into the vine-row direction regardless of the above-canopy wind direction. Additionally, other flow statistics in the canopy sub-layer show a dependance on the difference between the above-canopy wind direction and the vine-row direction. This includes an increase in the canopy displacement height and a decrease in the canopy-top shear length scale as the above-canopy flow rotates from row-parallel towards row-orthogonal. Distinct wind-direction-based variations are also observed in the components of the stress tensor, turbulent kinetic energy budget, and the energy spectra. Although spectral results suggest that sonic anemometry is insufficient for resolving all of the important scales of motion within the canopy, the energy spectra peaks still exhibit dependencies on the canopy and the wind direction. These variations demonstrate that the trellised-canopy’s effect on the flow during periods when the flow is row-aligned is similar to that seen by sparse canopies, and during periods when the flow is row-orthogonal, the effect is similar to that seen by dense canopies.     

Surveillance for previously unmonitored organic contaminants in the San Francisco Estuary

The San Francisco Estuary Regional Monitoring Program initiated surveillance monitoring to identify previously unmonitored synthetic organic contaminants in the San Francisco Estuary. Organic extracts of water samples were analyzed using gas chromatography-mass spectrometry in full scan mode. The major contaminant classes identified in the samples were fire retardants, pesticides, personal care product ingredients, and plasticizers. Evidence from the literature suggests that some of these contaminants can persist in the environment, induce toxicity, and accumulate in marine biota and in higher food chain consumers. The major sources of these contaminants into the marine environment are the discharge of municipal and industrial wastewater effluents, urban stormwater, and agricultural runoff. As a proactive effort, it is suggested that surveillance studies be used routinely in monitoring programs to identify and prevent potential problem contaminants from harming the marine environment.     

Using the Climate Forecast System Reanalysis as weather input data for watershed models

Obtaining representative meteorological data for watershed‐scale hydrological modelling can be difficult and time consuming. Land‐based weather stations do not always adequately represent the weather occurring over a watershed, because they can be far from the watershed of interest and can have gaps in their data series, or recent data are not available. This study presents a method for using the Climate Forecast System Reanalysis (CFSR) global meteorological dataset to obtain historical weather data and demonstrates the application to modelling five watersheds representing different hydroclimate regimes. CFSR data are available globally for each hour since 1979 at a 38‐km resolution. Results show that utilizing the CFSR precipitation and temperature data to force a watershed model provides stream discharge simulations that are as good as or better than models forced using traditional weather gauging stations, especially when stations are more than 10 km from the watershed. These results further demonstrate that adding CFSR data to the suite of watershed modelling tools provides new opportunities for meeting the challenges of modelling un‐gauged watersheds and advancing real‐time hydrological modelling. Copyright © 2013 John Wiley & Sons, Ltd.