Traces of volcanic ash from the Mediterranean,Iceland and North America in a Holocene record from south Wales,UK

A tephra record is presented for a sediment core from Llyn Llech Owain, south Wales, spanning the early- to mid-Holocene. Seven cryptotephra deposits are discovered with three thought to correlate with known eruptions and the remaining four considered to represent previously undocumented events. One deposit is suggested to correlate with the ~6.9 cal ka bp Lairg A tephra from Iceland, whereas more distant sources are proposed as the origin for two of the tephra deposits. A peak of colourless shards in early-Holocene sediments is thought to tentatively correlate with the ~9.6 cal ka bp Fondi di Baia tephra (Campi Flegrei) and a second cryptotephra is tentatively correlated with the ~3.6 cal ka bp Aniakchak (CFE) II tephra (Alaska). The Fondi di Baia tephra has never been recorded beyond proximal sites and its discovery in south Wales significantly extends the geographical distribution of ash from this eruption. The remaining four cryptotephra deposits are yet to be correlated with known eruptions, demonstrating that our current understanding of widespread tephra deposits is incomplete. This new tephra record highlights the potential for sites at more southerly and westerly locations in northwest Europe to act as repositories for ash from several volcanic regions.     

Natural aggregates in the performance and durability of concrete: chemical characteristics

This article continues from the earlier feature in Geology Today (2011, v.27, n.4) and looks at the influence of chemical reactivity within concrete due to the presence of unsound aggregates or deleterious material incorporated in the aggregate used in the concrete mix. Some of the more disruptive problems from chemical unsoundness come from the presence of chlorides, which cause rusting in reinforced concrete or, sulphate attack from ground waters. Both of these reactions are relatively common in Britain. Alkali–silica reactions with aggregates and cement is not too prevalent in Britain but can be very prevalent and disruptive elsewhere in the world.     

Spongy pahoehoe in Hawaii: A study of vesicle-distribution patterns in basalt and their significance

A well-defined pahoehoe lava type that is very common medially and distally in Hawaii is characterized by a high concentration and fairly uniform distribution of spherical or near-spherical vesicles. Measurements of vesicle sizes and concentrations have been made on ten of these spongy pahoehoe lava flow-units. The vesicles increase in size toward the middle, accompanied by a moderate increase in lava porosity. The close approach to bilateral symmetry on either side of the horizontal median plane and the common occurrence of a median gas blister shows that no significant upward movement of vesicles occurred, suggesting that the lava possessed a yield strength and was more or less static. Olivine phenocrysts when present are, however, concentrated in the lower half of the same flow units, showing that the lava previously lacked a significant yield strength. The vesicles are regarded as early, inherited from the vent, but the size characteristics of the vesicle population are a late-formed feature. Vesicles grew in static lava mostly by coalescence, and it is postulated that coalescence was promoted by the presence of abundant diktytaxitic voids which punctured the walls of contiguous vesicles. Zones in which the vesicle concentration is lower and the vesicles are larger and strongly deformed interrupt the symmetry of some spongy pahoehoe units, and gas blisters higher than the median plane occur in many examples. These zones are interpreted to result from late-stage shearing, and point to a mechanism by which vesicles may be eliminated from a lava.     

Infrared spectroscopic investigation of hydroxyl in β-(Mg,Fe)2SiO4 and coexisting olivine: Implications for mantle evolution and dynamics

Wadsleyite (β-(Mg,Fe)₂SiO₄) is a major constituent of the Earth's transition zone and is known to accommodate OH. The portion of the transition zone between 400–550 km could be an important source or sink for hydroxyl in plumes and slabs intersecting this region. Micro-infrared spectroscopy has been carried out on the β-phase and coexisting metastable olivine synthesized in a multianvil apparatus at 14 GPa and 1550–1650 K under hydrous conditions. Single-crystal and polycrystal specimens of both phases were analyzed in the 1800–8500 cm^?1 frequency region to determine the speciation, abundances, and partitioning behavior of the hydrous components in coexisting β-phase and olivine. β-phase spectra consistently show three distinct OH bands at 3329, 3580, and 3615 cm^?1. OH concentrations range from 10000–65000 H/10⁶ Si. A strong positive correlation of grain size and extent of transformation with OH concentration in the β-phase indicates that grain-growth and transformation rates are enhanced in a hydrous environment. Olivine spectra are variable, but consistently show a prominent broad-band absorbance representing molecular H₂O, consistent with the infrared signature of the starting material. OH concentrations in olivine range from <300–1400 H/10⁶ Si. The highest OH concentrations measured for olivine and the β-phase may represent solubility limits, in which case the OH solubility ratio between these two phases is approximately 1∶40. Where both phases coexist and are undersaturated with OH, the partitioning ratio of OH between them is about 1∶100. The large solubility contrast between olivine and the β-phase suggests a mechanism for hydrating the transition zone via olivine carried down in subducting slabs. Plumes impinging on an OH-rich upper transition region could cause H₂ or H₂O to be released upon transformation of the β-phase to olivine, resulting in initiation of secondary upwellings. If dissolution of OH weakens the β-phase, and if OH is present in the mantle, the region between 400–550 km could be a zone of low viscosity.     

Pahoehoe and aa in Hawaii: volumetric flow rate controls the lava structure

The historical records of Kilauea and Mauna Loa volcanoes reveal that the rough-surfaced variety of basalt lava called aa forms when lava flows at a high volumetric rate (>5–10 m³/s), and the smooth-surfaced variety called pahoehoe forms at a low volumetric rate (<5–10 m³/s). This relationship is well illustrated by the 1983–1990 and 1969–1974 eruptions of Kilauea and the recent eruptions of Mauna Loa. It is also illustrated by the eruptions that produced the remarkable paired flows of Mauna Loa, in which aa formed during an initial short period of high discharge rate (associated with high fountaining) and was followed by the eruption of pahoehoe over a sustained period at a low discharge rate (with little or no fountaining). The finest examples of paired lava flows are those of 1859 and 1880–1881. We attribute aa formation to rapid and concentrated flow in open channels. There, rapid heat loss causes an increase in viscosity to a threshold value (that varies depending on the actual flow velocity) at which, when surface crust is torn by differential flow, the underlying lava is unable to move sufficiently fast to heal the tear. We attribute pahoehoe formation to the flowage of lava at a low volumetric rate, commonly in tubes that minimize heat loss. Flow units of pahoehoe are small (usually <1 m thick), move slowly, develop a chilled skin, and become virtually static before the viscosity has risen, to the threshold value. We infer that the high-discharge-rate eruptions that generate aa flows result from the rapid emptying of major or subsidiary magma chambers. Rapid near-surface vesiculation of gas-rich magma leads to eruptions with high discharge rates, high lava fountains, and fast-moving channelized flows. We also infer that long periods of sustained flow at a low discharge rate, which favor pahoehoe, result from the development of a free and unimpeded pathway from the deep plumbing system of the volcano and the separation of gases from the magma before eruption. Achievement of this condition requires one or more episodes of rapid magma excursion through the rift zone to establish a stable magma pathway.     

Partitioning of siderophile elements in the FeNiS system: 1 bar to 80 kbar

Partition coefficients for Au, Ni, P and Ge between solid FeNi metal and sulfur-bearing metallic liquids have been measured at 7,27 and 80 kbar. To our knowledge, these are the only such data for Au, P and Ge at high pressure. Comparison of our partitioning results to those obtained at 1 bar indicate that only the 80 kbar Ge data differ significantly from the 1-bar experiments. Thus, many low-pressure partitioning experiments in the FeNiSP system may have applicability to the greater portion of the Earth's upper mantle or, alternatively, the entire mantle of Mars.