冈底斯驱龙斑岩铜钼矿床的岩浆侵位中心和矿化中心:破裂裂隙和矿化强度证据

驱龙斑岩铜钼矿床是迄今为止在西藏冈底斯成矿带上发现的规模最大的铜矿床.文章根据对驱龙矿区各类岩石破裂裂隙的野外实测数据,结合矿区已有钻孔品位资料,分别绘制了矿区地表破裂裂隙等值线图、走向投影图及梅花图、钻孔5 000 m海拔标高水平切面Cu、Mo品位等值线图.研究结果表明,驱龙斑岩铜钼矿床的岩石中破裂裂隙相当发育,连成一片,没有明显的多个高值中心,空间上破裂裂隙呈放射状产出;5 000 m海拔标高水平切面显示Cu、Mo矿化较强、较均匀,矿化呈面状,为典型的由单一斑岩体侵位造成的中心式矿化特征.据破裂裂隙和Cu、Mo矿化空间分布,可确定驱龙矿区岩浆中心和矿化中心均位于钻孔405、1205、801、809所围成的矩形区域附近.     

用随机介质模型方法描述孔洞型油气储层

孔洞型储集层具有强烈的非均质性,在空间分布上变化剧烈,规律性差,其地球物理参数(如速度、密度、弹性参数等)在空间上的变化很难用传统的层状介质模型进行刻画.本文借助随机模型方法,研究孔洞型储层中不同孔洞尺度、分布密度与模型参数的关系,建立反映实际孔洞油气储层介质地球物理参数空间分布统计特征的随机介质模型,以更方便地对孔洞型油气储层进行描述,并为碳酸盐岩孔洞型储层地震反射特征的研究提供有效的方法途径.     

赣南淘锡坑钨多金属矿床花岗岩和云英岩岩石特征及云英岩中白云母40Ar/39Ar定年

赣南崇义县淘锡坑钨矿位于南岭东西向构造带东段,属于以黑钨矿石英脉型为主的钨多金属矿床。矿床形成与燕山期中酸性岩浆作用有密切关系,石英矿脉受一组北西向断裂控制,穿切新元古界。本文在淘锡坑钨矿区3个揭露到花岗岩体顶部的中段（206、106、56中段）采集到岩体顶部云英岩样品,利用40Ar/39Ar同位素定年测得云英岩中的白云母的坪年龄分别为152.7 ± 1.5 Ma（206中段）,153.4 ± 1.3 Ma（106中段）,155.0 ± 1.4 Ma（56中段）。与前人用其他方法测定的花岗岩成岩和成矿年龄几乎一致。花岗岩和云英岩全岩稀土元素均具有M型四分组效应和强烈的Eu亏损特征,反映出花岗质岩浆经历了高度分异演化及其岩体结晶晚期流体/熔体相互作用。综合前人在南岭地区同类矿床的研究资料,可知南岭地区160～150Ma成岩成矿作用主要分布于南岭中-东段,可能为大陆边缘弧后岩石圈伸展的构造动力学背景的产物。     

贵州青岩剖面青岩阶上部牙形石的发现及其意义

在贵州青岩剖面的青岩组之上,原被认为是拉丁期的垄头组下部的层段中发现了牙形石动物群,除少量的分枝分子外,都归属于Neogondolella属,可鉴定为4个种,即Neogondolella bifurcata,N.constricta,N.mombergensis和N.navicula.建立了2个牙形石带,自下而上是Neogondolella bifurcata带和N.cinstricta带.牙形石面貌证明这段地层在时代上非常接近但尚未进入拉丁阶,属于安尼期中晚期,进一步的牙形石工作将很有可能在目前发现的牙形石层段的上部寻找到安尼阶和拉丁阶之间的界限,从而为青岩阶顶界的限定提供可靠的牙形石证据.此外,牙形石的发现还初步实现了青岩阶2大主导门类化石--牙形石和菊石在同一剖面的直接对比关系.     

辽河断陷大民屯凹陷静北潜山孢粉化石新发现

静北潜山的油气勘探始于上世纪70年代初,并将钻井揭示的未见化石的碳酸盐岩和石英砂岩沉积划归中元古界长城系,沿用至今.2002年在对该区的地层研究中,首次发现了晚古生代孢粉化石,从而证实静北潜山存在晚古生代地层.本文以孢粉化石为主要依据,对潜山地层进行了重新划分,并与邻区进行对比.在此基础上对本区的构造和沉积作一讨论.     

安徽铜陵狮子山矿田岩浆岩锆石SHRIMP定年及其成因意义

铜陵狮子山矿田发育大量岩浆岩,且与矿田中的铜金多金属成矿关系密切。锆石SHRIMP同位素精确定年表明,矿田中的岩浆侵位年龄在132.4～142.9Ma之间,即晚侏罗世—早白垩世,属燕山早期晚阶段。矿田岩浆岩体是在同期岩浆活动中多次侵位形成的,岩浆侵入活动可以划分为分别起始于140Ma前后和约136Ma的早晚两次。从岩浆上升侵位到冷却结晶的时间间隔均较短,但其中白芒山辉石二长闪长岩冷却史相对较长,且经历了早期深部岩浆房中的分离结晶作用和后期构造脉动、岩浆上升侵位、减压受热、早期晶体再熔蚀及冷却结晶的过程。结合主量元素和微量元素地球化学研究认为,狮子山矿田岩浆演化的后期,即起源于上地幔或下地壳的原生岩浆在同化了壳源物质并聚集到岩浆房中以后,在滞留的过程中发生了一定程度的分离结晶作用,但尚未固结,成分上显示了一定的带状分布,在区域构造应力松弛及构造事件诱发下,随机地沿发育的构造裂隙先后上升侵位,冷凝结晶。     

阿尔金断裂昌马大坝—宽滩山段全新世活动特征

阿尔金断裂是我国西部著名的巨型走滑断裂带之一,也是全新世活动断裂和发震断裂。该断裂昌马大坝—宽滩山段运动方式为以左行走滑占主导,伴有弱的垂直运动;在距今2.7ka以来发生过明显的新构造活动（和地震）。在沙坪—宽滩山段全新世左行走滑位移速率为0.9～2.2mm/a,明显低于阿尔金断裂东段昌马大坝以西地区4～5mm/a和中西段9～11mm/a的位移速率。阿尔金断裂东段在肃北和昌马大坝出现二次位移速率的锐减,锐减的部分分别转化为海原活动断裂西段（党河南山断裂）和祁连山北缘活动断裂西段的左行走滑和逆冲,且在位移速率数值上相互之间具有非常好的对应性。阿尔金断裂在肃北位移速率减少部分（4.6mm/a）与海原活动断裂西段（党河南山断裂）的位移速率（4～5mm/a）非常接近,同样阿尔金断裂在昌马大坝位移速率减少部分（3.2mm/a）与祁连山北缘活动断裂的位移速率（3.0mm/a）也非常接近。     

Zircon U–Pb and Hf isotopic study of gneissic rocks from the Chinese Altai: Progressive accretionary history in the early to middle Palaeozoic

Gneissic rocks in the Chinese Altai Mountains have been interpreted as either Paleozoic metasedimentary rocks or Precambrian basement. This study reports geochemical and geochronological data for banded paragneisses and associated gneissic granitoids collected along a NE–SW traverse in the northwestern Chinese Altai. Petrological and geochemical data suggest that the protoliths of the banded gneisses were possibly immature sediments with significant volcanic input and that the gneissic granitoids were derived from I-type granites formed in a subduction environment. Three types of morphological features can be recognized in zircons from the banded gneisses and are interpreted to correlate with different sources. Zircons from five samples of banded paragneiss cluster predominantly between 466 and 528 Ma, some give Neoproterozoic ages, and a few yield discordant Paleoproterozoic to Archean ages. Zircon Hf isotopic compositions indicate that both juvenile/mantle and crust materials were involved in the generation of the source rocks from which these zircons were derived. In contrast, zircons occur ubiquitously as elongated euhedral prismatic crystals in the four samples of the gneissic granitoids, and define single populations for each sample with mean ages between 380 and 453 Ma. The general absence of Precambrian inheritance and positive zircon ?Hf values for these granitoids suggest insignificant crustal contribution to the generation of the precursor magmas. Our data can be interpreted in terms of a progressive accretionary history in early to middle Palaeozoic times, and the Chinese Altai may possibly represent a magmatic arc built on a continental margin dominated by Neoproterozoic rocks.     

Atmospheric mercury near Salmon Falls Creek Reservoir in southern Idaho

Gaseous elemental mercury (GEM) and reactive gaseous mercury (RGM) were measured over 2-week seasonal field campaigns near Salmon Falls Creek Reservoir in south-central Idaho from the summer of 2005 through the fall of 2006 and over the entire summer of 2006 using automated Tekran Hg analyzers. GEM, RGM, and particulate Hg (HgP) were also measured at a secondary site 90 km to the west in southwestern Idaho during the summer of 2006. The study was performed to characterize Hg air concentrations in the southern Idaho area for the first time, estimate Hg dry deposition rates, and investigate the source of observed elevated concentrations. High seasonal variability was observed with the highest GEM (1.91 ± 0.9 ng m⁻³) and RGM (8.1 ± 5.6 pg m⁻³) concentrations occurring in the summer and lower values in the winter (1.32 ± 0.3 ng m⁻³, 3.2 ± 2.9 pg m⁻³ for GEM, RGM, respectively). The summer-average HgP concentrations were generally below detection limit (0.6 ± 1 pg m⁻³). Seasonally averaged deposition velocities calculated using a resistance model were 0.034 ± 0.032, 0.043 ± 0.040, 0.00084 ± 0.0017 and 0.00036 ± 0.0011 cm s⁻¹ for GEM (spring, summer, fall and winter, respectively) and 0.50 ± 0.39, 0.40 ± 0.31, 0.51 ± 0.43 and 0.76 ± 0.57 cm s⁻¹ for RGM. The total annual RGM + GEM dry deposition estimate was calculated to be 11.9 ± 3.3 μg m⁻², or about 2/3 of the total (wet + dry) deposition estimate for the area. Periodic elevated short-term GEM (2.2–12 ng m⁻³) and RGM (50–150 pg m⁻³) events were observed primarily during the warm seasons. Back-trajectory modeling and PSCF analysis indicate predominant source directions to the SE (western Utah, northeastern Nevada) and SW (north-central Nevada) with fewer inputs from the NW (southeastern Oregon and southwestern Idaho).     

运用3DEEMs及荧光偏振方法研究pH、离子强度及浓度效应对腐殖酸荧光光谱特性的影响

利用三维荧光激发.发射光谱(3DEEMs)及荧光偏振法研究了3例腐殖酸和1例湖泊溶解有机物(DOM)在不同腐殖酸浓度、离子强度和pH条件下的荧光光谱特性.实验结果表明,随着浓度增大,各腐殖酸样的荧光强度增大,其中垃圾渗滤液腐殖酸和Pahokee泥炭腐殖酸的荧光峰出现红移.随着浓度进一步增大,腐殖酸的荧光偏振值增大,由此推断在此浓度范围内腐殖酸由于分子间的排斥作用使其构型出现伸展.离子强度增大导致腐殖酸及阿哈湖DOM的荧光强度降低.随着氯化钾(KCI)浓度增大,Fluka腐殖酸的荧光峰A蓝移,荧光峰B的荧光偏振值出现减小,推测是由于静电中和作用使其荧光基团发生卷曲造成的.离子强度对其余腐殖酸样和阿哈湖DOM的其他荧光特性没有明显的影响.总的来说,pH值的变化对腐殖酸和湖泊DOM的荧光特征的影响是很明显的.随着pH值增大,腐殖酸和湖泊DOM的荧光强度增强.而pH值减小时,Fluka腐殖酸和Pahokee泥炭腐殖酸的荧光峰(A峰)蓝移,当pH值降到5时,Fhka腐殖酸的荧光峰突然红移到最大,随后又继续蓝移;垃圾渗滤液腐殖酸和阿哈湖DOM的荧光峰位无明显的漂移.所有样品的荧光偏振值都减小(但阿哈湖DOM的A峰变化不大),但在pHi≤5时又增大,这种现象表明随着pH值降低,腐殖酸和湖泊DOM中有机大分子发生卷曲,但在pH≤5时由于羧基的质子化又以平面伸展构型出现在溶液中.