The effect of cracks on the thermal expansion of rocks

Thermal expansion during the first heating cycle at atmospheric pressure was measured in several directions in seven igneous rocks between 25° and 400°C at slow heating rates. The coefficient of thermal expansion measured under these conditions increases more rapidly as temperature is increased than the average thermal expansion coefficient of the constituent minerals. The “extra” expansion is attributed to the formation of cracks by differential expansion of mineral grains. The presence of such cracks in the rocks during the cooling part of the cycle and during any subsequent heating and cooling cycles will result in a substantial decrease in the coefficient of thermal expansion as compared to that measured during the first heating cycles. The effect of cracks initially present in a rock was studied by measuring the full tensor of the coefficient of thermal expansion on two rocks with anisotropic crack distributions. In these two rocks the coefficient of thermal expansion is least in the direction perpendicular to the plane of greatest crack concentration. The implication of our data is that thermal expansion depends greatly on the fracture state of the rock. Both the fractures in the rock and the boundary conditions on the rock are significant for the interpretation of thermal expansion measurements and for their application to other problems.     

The contribution of sulphur dioxide from ablating micrometeorites to the atmospheres of Earth and Mars

Atmospheric composition is a key control on climate and the habitability of planetary surfaces. Ablation of infalling micrometeorites has been recognised as one way in which atmospheric chemistry can be changed, especially at times in solar system history when the infall rates of exogenous material were high. Despite its potential to influence climate and habitability, extraterrestrial sulphur dioxide is currently an unquantified contribution to the atmospheres of the terrestrial planets. We have used flash pyrolysis to simulate the atmospheric entry of micrometeorites and Fourier-transform infrared spectroscopy to identify and quantify the sulphur dioxide produced from the carbonaceous meteorites Orgueil (CI1), ALH 88045 (CM1), Cold Bokkeveld (CM2), Murchison (CM2) and Mokoia (CV3). We have used this approach to understand the introduction of sulphur dioxide to the atmospheres of Earth and Mars from infalling micrometeorites. Sulphates, present in carbonaceous chondrites at a few wt.%, are resistant to thermal decomposition, limiting the yields of sulphur dioxide from unmelted micrometeorites. Infalling micrometeorites are a minor source of present-day sulphur dioxide on Earth and Mars, calculated to be up to around 2400 tonnes and about 350 tonnes, respectively. During the Late Heavy Bombardment (LHB), the much greater infall rates of micrometeoritic dust are calculated to be associated with average production rates of sulphur dioxide of around 20 Mt yr⁻¹ for the early Earth and 0.5 Mt yr⁻¹ for early Mars, for a LHB of 100 Myr. These rates of delivery of sulphur dioxide at high altitudes would have reduced the solar energy reaching the surfaces of these planets, via scattering of sunlight by stratospheric sulphate aerosols, and may have had detrimental effects on developing biospheres by promoting cooler climates and reducing the probability of liquid water on planetary surfaces.     

The measurement and extraction of the <nu>6 atmospheric emission band of CFC-12 from interfering emission features

Ground-based thermal emission measurements of the zenith sky have been made at Peterborough, Ontario since January 1993. In this paper, the measurement of the ₆ band of atmospheric CFC-12, an important greenhouse gas, is presented for a cold, clear day in January 1994. A spectrum of the non-CFC-12 emission features has been simulated using the FASCD3P radiation code and measured radiosonde profiles of temperature, pressure and humidity. This has enabled a satisfactory subtraction of the interfering emission features from the CFC-12 emission spectrum. A comparison of the observed and simulated ₆-bands of CFC-12 shows good agreement at all frequencies of emission. From these spectra the total downward greenhouse radiative flux from the CFC-12 ₆ emission based for a very cold day has been estimated to be 0.27 W m⁻²±10%.     

Modeling preferential flow in reactive barriers: implications for performance and design

Reactive barriers are passive and in situ ground water treatment systems. Heterogeneities in hydraulic conductivity (K) within the aquifer-reactive barrier system will result in higher flux rates, and reduced residence times, through portions of the barrier. These spatial variations in residence time will affect the treatment capacity of the barrier. A numerical flow model was used to evaluate the effects of spatial variations in K on preferential flow through barriers. The simulations indicate that the impact of heterogeneities in K will be a function of their location and distribution; the more localized the high K zone, the greater the preferential flow. The geometry of the reactive barrier will also strongly influence flow distribution. Aquifer heterogeneities will produce greater preferential flow in thinner barriers compared to thicker barriers. If the barrier K is heterogeneous, greater preferential flow will occur in thicker barriers. The K of the barrier will affect the flow distribution; decreasing the K of the barrier can result in more even distribution of flow. Results indicate that less variable flow will be attained utilizing thicker, homogeneous barriers. The addition of homogeneous zones to thinner barriers will be effective at redistributing flow only if installed immediately adjacent to both the up- and downgradient faces of the barrier.     

A crustal suture and lineament in North Africa

A possible suture between an old craton in West Africa and the Arabian—Nubian shield is marked by a persistent zone of Phanerozoic weakness. This zone extends between the Nile and Niger deltas and passes through the Qattara embayment, along the Bahariya fault, through the Kufra basin, between the Tibesti and Jabal al Uwaynat massifs, through the Bahr el Ghazal and Lake Chad areas, and along the Benoue trough.     

Sea‐level and ocean‐current control on carbonate‐platform growth,Maldives, Indian Ocean

Multichannel high‐resolution seismic and multibeam data were acquired from the Maldives‐isolated carbonate platform in the Indian Ocean for a detailed characterization of the Neogene bank architecture of this edifice. The goal of the research is to decipher the controlling factors of platform evolution, with a special emphasis on sea‐level changes and changes of the oceanic currents. The stacking pattern of Lower to Middle Miocene depositional sequences, with an evolution of a ramp geometry to a flat‐topped platform, reflects variations of accommodation, which here are proposed to be primarily governed by fluctuations of relative sea level. Easterly currents during this stage of bank growth controlled an asymmetric east‐directed progradation of the bank edge. During the late middle Miocene, this system was replaced by a twofold configuration of bank development. Bank growth continued synchronously with partial bank demise and associated sediment‐drift deposition. This turnover is attributed to the onset and/or intensification of the Indian monsoon and related upwelling and occurrence of currents, locally changing environmental conditions and impinging upon the carbonate system. Mega spill over lobes, shaped by reversing currents, formed as large‐scale prograding complexes, which have previously been interpreted as deposits formed during a forced regression. On a regional scale, a complex carbonate‐platform growth can occur, with a coexistence of bank‐margin progradation and aggradation, as well as partial drowning. It is further shown that a downward shift of clinoforms and offlapping geometries in carbonate platforms are not necessarily indicative for a sea‐level driven forced regression. Findings are expected to be applicable to other examples of Cenozoic platforms in the Indo‐Pacific region.     

A statistical approach to evaluating distance metrics and analog assignments for pollen records

The modern analog technique typically uses a distance metric to determine the dissimilarity between fossil and modern biological assemblages. Despite this quantitative approach, interpretation of distance metrics is usually qualitative and rules for selection of analogs tend to be ad hoc. We present a statistical tool, the receiver operating characteristic (ROC) curve, which provides a framework for identifying analogs from distance metrics. If modern assemblages are placed into groups (e.g., biomes), this method can (1) evaluate the ability of different distance metrics to distinguish among groups, (2) objectively identify thresholds of the distance metric for determining analogs, and (3) compute a likelihood ratio and a Bayesian probability that a modern group is an analog for an unknown (fossil) assemblage. Applied to a set of 1689 modern pollen assemblages from eastern North America classified into eight biomes, ROC analysis confirmed that the squared-chord distance (SCD) outperforms most other distance metrics. The optimal threshold increased when more dissimilar biomes were compared. The probability of an analog vs no-analog result (a likelihood ratio) increased sharply when SCD decreased below the optimal threshold, indicating a nonlinear relationship between SCD and the probability of analog. Probabilities of analog computed for a postglacial pollen record at Tannersville Bog (Pennsylvania, USA) identified transitions between biomes and periods of no analog.     

Resolving mechanisms of toxicity while pursuing ecotoxicological relevance?

In this age of modern biology, aquatic toxicological research has pursued mechanisms of action of toxicants. This has provided potential tools for ecotoxicologic investigations. However, problems of biocomplexity and issues at higher levels of biological organization remain a challenge. In the 1980s and 1990s and continuing to a lesser extent today, organisms residing in highly contaminated field sites or exposed in the laboratory to calibrated concentrations of individual compounds were carefully analyzed for their responses to priority pollutants. Correlation of biochemical and structural analyses in cultured cells and tissues, as well as the in vivo exposures led to the production and application of biomarkers of exposure and effect and to our awareness of genotoxicity and its chronic manifestations, such as neoplasms, in wild fishes. To gain acceptance of these findings in the greater environmental toxicology community, “validation of the model” versus other, better-established often rodent models, was necessary and became a major focus. Resultant biomarkers were applied to heavily contaminated and reference field sites as part of effects assessment and with investigations following large-scale disasters such as oil spills or industrial accidents.

Over the past 15 years, in the laboratory, small aquarium fish models such as medaka (Oryzias latipes), zebrafish (Danio rerio), platyfish (Xiphophorus species), fathead minnow (Pimephales promelas), and sheepshead minnow (Cyprinodon variegatus) were increasingly used establishing mechanisms of toxicants. Today, the same organisms provide reliable information at higher levels of biological organization relevant to ecotoxicology. We review studies resolving mechanisms of toxicity and discuss ways to address biocomplexity, mixtures of contaminants, and the need to relate individual level responses to populations and communities.