Ground Surface Temperature History in Poland in the 16th–20th Centuries Derived from the Inversion of Geothermal Profiles

Ground Surface Temperature (GST) history in Poland was derived from the inversion of temperature-depth profiles in over 20 wells. Temperature histories for the period 1500 A.D. through 1977 A.D. agree well with the instrumental record of the surface-air temperature available for the last two centuries. A statistical correlation of the reconstructed histories (from the well temperature data) with the instrumental record (air temperature) from the homogeneous Warsaw series is high (>0.8). Functional space inversion (FSI) of the temperature data with depth shows that beginning in the early 19th century, temperatures warmed by 0.9 ± 0.1°C following a long period of colder climate before. The last number could be a minimal as higher warming was calculated using a simple model based on surface temperature for the observational period (homogenized Warsaw surface temperature series, Lorenc, 2000) and POM (pre-observational mean; Harris and Chapman, 1998) of –1.53^oC below the 1951–1980 mean temperature level.     

Potentiality of Paleocene source rocks and their contribution in generating the accumulated oil in the Eocene Pila Spi Reservoir in Taq Taq Oil Field, Kurdistan Region, Iraq

The organic matters within the Paleocene Aaliji and Kolosh Formations in the well TT-04, Taq Taq Oil Field in Kurdistan Region, NE Iraq have been studied optically and also analytically by means of pyrolysis, Gas Chromatography (GC), and Gas Chromatography/Mass Spectrometry (GC/MS). Amorphous organic matters seemed to be the dominant component of the extracted organic matters within the studied section with an obvious increase of the Phytoclasts at the upper part of Kolosh Formation. Thermal Alteration Index, vitrinite reflectance, pyrolysis, and gas chromatography data all indicated the maturity of the lower part from the studied layers (known generally as Aaliji/Kolosh) and within the early stages of oil generation. Oil–source correlation indicates the possibility of contribution of the Paleocene source rocks in generating the accumulated oil in the Eocene Pila Spi reservoir in the field which also appeared to be a mature and of marine-to-mixed carbonate source. Oil–oil correlation between the oil in Pila Spi and the oil in the Upper Cretaceous reservoirs showed the possibility of existence of more than one source for the two oils. GC/MS analysis for the Pila Spi oil indicated the effect of biodegradation which may be considered as one of the reasons for being the American Petroleum Institute (API) of this oil about 24° while the oil in the Cretaceous reservoirs is of more than 47° API.     

Influence of calibration methodology on ground water flow predictions

We constructed a numerical model of transient ground water flow and solute transport for a portion of the Biscayne Aquifer in Florida, and calibrated the model with three different combinations of data from a 193-day period: head (h) data alone, data on h and ground water discharge to a canal (q), and data on h, q, and ground water chloride concentration (C). We used each of the three calibrated models to predict h and q during a 182-day test period separate from the calibration period. All three calibrated models predicted h equally well during the test period (r = 0.95, where r = 1 indicates perfect agreement between measured and simulated values), though the model calibrated on h alone had significantly different parameter values than the other two models. Predictions of q during the test period depended on calibration methodology; models calibrated with multiple targets simulated q more accurately than the model calibrated on h alone (r = 0.79 compared to r = 0.49). Based on the results of these simulations, we conclude: (1) Post-calibration prediction is important in assessing the value of different data types in automated calibration; (2) inverse-solution uniqueness is not a requirement for accurate h predictions; (3) relatively simple models can predict with reasonable accuracy transient ground water flow in a complex aquifer, and parameters governing this prediction can be estimated by nonlinear regression methods that incorporate both h and q data; (4) addition of C data to the calibration did not improve model predictive capacity because the information in the C data was similar to that in the q data, from the perspective of model calibration (the subsurface chemical signal in question was controlled mainly by seepage of high-chloride canal water into the low-chloride ground water system).     

Wind-driven upwelling and surface chlorophyll blooms in Greater Cook Strait

We present the results of a combined observational and numerical study to investigate cool plumes of nutrient-rich upwelled water that emanate near the Kahurangi Shoals and extend into Greater Cook Strait. Surface temperature and chlorophyll are mapped using satellite observations to produce surface climatologies, to validate a numerical simulation and to show the utility of using spatial temperature differences as a measure of upwelling. We find upwelling near the Kahurangi Shoals is strongly wind-driven in the weather band. Upwelling occurs at all times of the year, but its surface signature is only visible in summer months. The upwelled nutrient-rich water supports increased primary production compared to surrounding waters, particularly in summer when the water column is more stratified and surrounding surface waters are presumably nutrient depleted.     

The persistence of lead from past gasoline emissions and mining drainage in a large riparian system: Evidence from lead isotopes in the Sacramento River, California

Lead concentrations and isotope ratios measured in river water colloids and streambed sediment samples along 426 km of the Sacramento River, California reveal that the influence of lead from the historical mining of massive sulfide deposits in the West Shasta Cu-mining district (at the headwaters of the Sacramento River) is confined to a 60 km stretch of river immediately downstream of that mining region, whereas inputs from past leaded gasoline emissions and historical hydraulic Au-mining in the Sierra Nevadan foothills are the dominant lead sources in the remaining 370 km of the river. Binary mixing calculations suggest that more than 50% of the lead in the Sacramento River outside of the region of influence of the West Shasta Cu-mining district is derived from past depositions of leaded gasoline emissions. This predominance is the first direct documentation of the geographic extent of gasoline lead persistence throughout a large riparian system (>160,000 km²) and corroborates previous observations based on samples taken at the mouth of the Sacramento River. In addition, new analyses of sediment samples from the hydraulic gold mines of the Sierra Nevada foothills confirm the present-day fluxes into the Sacramento River of contaminant metals derived from historical hydraulic Au-mining that occurred during the latter half of the 19th and early part of the 20th centuries. These fluxes occur predominantly during periods of elevated river discharge associated with heavy winter precipitation in northern California. In the broadest context, the study demonstrates the potential for altered precipitation patterns resulting from climate change to affect the mobility and transport of soil-bound contaminants in the surface environment.     

Helical probe tests in residual soils of the Appalachian Piedmont

Helical probe tests (HPT) are a quick and economical means for manual field testing of soils to depths of 1.5 m with readings taken at 0.15-m intervals in only 10 min. The equipment is lightweight (only 2 kg) and thus amenable to deploy on initial site reconnaissance explorations, shallow pavement projects, earth retention walls, and/or compaction of fills. Although suitable for use in a variety of geomaterials: sands, silts, clays, and mixed soils, the specific application to residual fine sandy silts and silty fine sands of the Appalachian Piedmont and Blue Ridge geologic provinces is shown here. Existing relationships for converting the measured HPT torque reading to equivalent cone penetration testing (CPT) tip resistances are reviewed, as well as other trends.     

Mathematical models for petroleum-forming processes: carbon isotope fractionation

A mathematical model has been developed in which carbon isotope fractionation during thermal cracking of n-paraffins can be simulated. The model has been calibrated based on data from laboratory cracking experiments carried out on n-octadecane. Relative rate constants for cleavage of C¹²-C¹², C¹²-C¹³ and C¹³-C¹³ bonds agree with the experimental values obtained by other workers.Application of this model to the process of petroleum formation gives good agreement with some existing experimental data, but suggests that a review of our understanding of isotope fractionation during thermal cracking may be necessary. The relative importance of the degree to which the organic material has been cracked and of the type of the organic material in influencing δC¹³ values is discussed.The present model predicts that cracking of n-paraffin distributions having initial odd or even carbon number predominances can induce isotopic inhomogeneity among the homologs of the resulting distribution. The model exhibits some deficiencies in explaining or predicting the δC¹³ values of ethane and propane in relation to methane in gases and of oils and associated methane. Explanations for these discrepancies may lie in the simplicity of our mathematical model, in our assumption of initial isotopic homogeneity within molecules and in our use of only n-paraffins as the source molecules for the cracking reactions.