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931.
Quantum-thermodynamic treatment of intrinsic anharmonicity; Wallace’s theorem revisited 总被引:1,自引:0,他引:1
Wallace (in Thermodynamics of crystals, 1972) developed a theorem, rooted in rigid lattice dynamics, which incorporates intrinsic anharmonic effects in solids. The practical
application of this theorem in mineral physics is computationally involved and this is the main reason for the theorem not
getting the attention it deserves. Because intrinsic anharmonicity is an important issue at the extreme conditions in planetary
mantles, we derived a method which removes the computational obstacles in applying this theorem. We extended the theorem to
incorporate details of the phonon spectrum and tested our algorithm on forsterite (Mg2SiO4). Using a least squares inversion technique applied to all available experimental data, we show that it results in an accurate
representation of thermodynamic properties and sound wave velocities of Mg2SiO4 in its complete pressure–temperature stability range. We also show that the accuracy of our results is not significantly
affected by the use of a different equation of state. 相似文献
932.
933.
Variation in nitrate and calcium as indicators of recharge pathways in Nolte Spring, PA 总被引:1,自引:0,他引:1
This study documents variations in calcium and nitrate concentrations that suggest changes in recharge pathways in a karst
spring. The nitrate concentrations increased at the end of the growing season, showing the importance of the soil zone in
the recharge pathway. The increase occurred over just a few days, which may be indicative of a change in contribution of baseflow
in different seasons from deep to shallow groundwater. The calcium concentrations decreased several days after storm events.
A change in the carbonate equilibrium is hypothesized because chloride was not diluted during these events. The decrease in
calcium could be due to outgassing and calcite precipitation in the recharge area when older, higher ionic strength matrix
water mixes with stormwater in open conduits. The use of geochemical indicators to better understand recharge pathways benefited
from long-term monitoring and periods of daily sampling. 相似文献
934.
B. A. Elliott W. H. Peck O. T. Rämö M. Vaasjoki M. Nironen 《Mineralogy and Petrology》2005,85(3-4):223-241
Summary Oxygen isotope ratios of igneous zircon from magmatic rocks in Finland provide insights into the evolution and growth of the
Precambrian crust during the Svecofennian orogeny. These data preserve magmatic δ18O values and correlate with major discontinuities in the lower crust. Oxygen isotope ratios of zircon across the 1.88–1.87 Ga
Central Finland granitoid complex (CFGC) range from 5.50‰ to 6.84‰, except for three plutons in contact with the adjacent
greenstone and metasedimentary belts (δ18O(Zrc) = 7.60‰–7.78‰). There is a systematic variation in δ18O(Zrc) with respect to geographic location in the CFGC, ranging from 6.60±0.23‰ (σ) in the northeast to 5.90±0.40‰ in the
west-southwest. These values correlate with a change in crustal thickness and shift in geochemical composition. The oxygen
isotope composition of the 1.65–1.54 Ga rapakivi granites and related rocks in southern Finland show a decreasing trend from
north to south, independent of their emplacement age. The southern anorogenic granite group has an average δ18O in zircon of 6.14±0.07‰ and the northern anorogenic group has an average δ18O in zircon of 8.14±0.59‰. This difference reflects the boundary between island arc terrains accreted during the Paleoproterozoic.
Deceased 相似文献
935.
The capacity to adapt is a critical element of the process of adaptation: it is the vector of resources that represent the asset base from which adaptation actions can be made. Adaptive capacity can in theory be identified and measured at various scales, from the individual to the nation. The assessment of uncertainty within such measures comes from the contested knowledge domain and theories surrounding the nature of the determinants of adaptive capacity and the human action of adaptation. While generic adaptive capacity at the national level, for example, is often postulated as being dependent on health, governance and political rights, and literacy, and economic well-being, the determinants of these variables at national levels are not widely understood. We outline the nature of this uncertainty for the major elements of adaptive capacity and illustrate these issues with the example of a social vulnerability index for countries in Africa. To cite this article: W.N. Adger, K. Vincent, C. R. Geoscience 337 (2005). 相似文献
936.
937.
W. L. Fourney U. Leiste R. Bonenberger D. J. Goodings 《Fragblast: International Journal for Blasting and Fragmentation》2005,9(4):205-217
This paper investigates the various mechanisms and parameters that are responsible for delivering impulse to a vehicle that is unfortunate enough to detonate a buried mine. Small scale tests are used to examine the effects of air blast or ejected sand in imparting impulse to a plate that is located above the surface of the saturated soil that contains the explosive. Parameters such as confinement, stand off distance, depth of burial of the explosive, density of the soil, and saturation level of the soil are also examined. 相似文献
938.
K. Reicherter A. Kaiser W. Stackebrandt 《International Journal of Earth Sciences》2005,94(5-6):1083-1093
The recent evolution of the north German Basin (NGB), which is presently a low-seismic area, was partly affected by glacial
loading and unloading of the ice masses. Major stresses acting within the NGB are induced by the North-Atlantic ridge push,
the ongoing Alpine collision, and the post-glacial rebound of Fennoscandia. Present-day horizontal stresses within the NGB
are directed generally NW–SE, but fan and bend north of 52°N towards NNE. Major basement faults are directed NW–SE, minor
faults NE–SW and NNE–SSW, and are clearly detectable in geomorphological and satellite lineaments. Furthermore, the drainage
pattern and the distribution of lakes in northern Germany follow exactly block boundaries and, hence, mark zones of present-day
subsidence. The understanding of the post-glacial morphology and reactivation of faults requires a view into the very heterogeneous
crust and upper mantle below the NGB. The re-adjustment of the individual fault blocks during post-glacial relaxation of the
lithosphere leads to differential, crust-dependent uplift and, probably, to the formation of Urstrom valleys. The Urstrom
valleys and terminal moraines in northern Germany appear to parallel the major tectonic lineaments and lithospheric “block”
boundaries. The lithospheric memory is expressed in the post-glacial landscape evolution of the NGB. 相似文献
939.
The Stonyford Volcanic Complex: a Forearc Seamount in the Northern California Coast Ranges 总被引:2,自引:0,他引:2
SHERVAIS JOHN W.; SCHUMAN MARCHELL M. ZOGLMAN; HANAN BARRY B. 《Journal of Petrology》2005,46(10):2091-2128
Jurassic age volcanic rocks of the Stonyford volcanic complex(SFVC) comprise three distinct petrological groups based ontheir whole-rock geochemistry: (1) oceanic tholeiites; (2) transitionalalkali basalts and glasses; (3) high-Al, low-Ti tholeiites.Major and trace element, and SrNdPb isotopic dataindicate that the oceanic tholeiites formed as low-degree partialmelts of normal mid-ocean ridge basalt (N-MORB)-source asthenospheresimilar in isotope composition to the East Pacific Rise today;the alkalic lavas were derived from an enriched source similarto that of E-MORB. The high-Al, low-Ti lavas resemble second-stagemelts of a depleted MORB-source asthenosphere that formed bymelting spinel lherzolite at low pressures. Trace element systematicsof the high-Al, low-Ti basalts show the influence of an enrichedcomponent, which overprints generally depleted trace elementcharacteristics. Tectonic discrimination diagrams show thatthe oceanic tholeiite and alkali suites are similar to present-daybasalts generated at mid-oceanic ridges. The high-Al, low-Tisuite resembles primitive arc basalts with an enriched, alkalibasalt-like overprint. Isotopic data show the influence of recycledcomponents in all three suites. The SFVC was constructed ona substrate of normal Coast Range ophiolite in an extensionalforearc setting. The close juxtaposition of the MORB-like olivinetholeiites with alkali and high-Al, low-Ti basalts suggestsderivation from a hybrid mantle source region that includedMORB-source asthenosphere, enriched oceanic asthenosphere, andthe depleted supra-subduction zone mantle wedge. We proposethat the SFVC formed in response to collision of a mid-oceanridge spreading center with the Coast Range ophiolite subductionzone. Formation of a slab window beneath the forearc duringcollision allowed the influx of ridge-derived magmas or themantle source of these magmas. Continued melting of the previouslydepleted mantle wedge above the now defunct subduction zoneproduced strongly depleted high-Al, low-Ti basalts that werepartially fertilized with enriched, alkali basalt-type meltsand slab-derived fluids. KEY WORDS: CRO; oceanic basalts; California 相似文献
940.
Extensive high-grade polydeformed metamorphic provinces surroundingArchaean cratonic nuclei in the East Antarctic Shield recordtwo tectono-thermal episodes in late Mesoproterozoic and lateNeoproterozoicCambrian times. In Western Dronning MaudLand, the high-grade Mesoproterozoic Maud Belt is juxtaposedagainst the Archaean Grunehogna Province and has traditionallybeen interpreted as a Grenvillian mobile belt that was thermallyoverprinted during the Early Palaeozoic. Integration of newUPb sensitive high-resolution ion microprobe and conventionalsingle zircon and monazite age data, and ArAr data onhornblende and biotite, with thermobarometric calculations onrocks from the H.U. Sverdrupfjella, northern Maud Belt, resultedin a more complex PTt evolution than previouslyassumed. A c. 540 Ma monazite, hosted by an upper ampibolite-faciesmineral assemblage defining a regionally dominant top-to-NWshear fabric, provides strong evidence for the penetrative deformationin the area being of Pan-African age and not of Grenvillianage as previously reported. Relics of an eclogite-facies garnetomphaciteassemblage within strain-protected mafic boudins indicate thatthe peak metamorphic conditions recorded by most rocks in thearea (T = 687758°C, P = 9·411·3kbar) were attained subsequent to decompression from P >12·9 kbar. By analogy with limited UPb singlezircon age data and on circumstantial textural grounds, thisearlier eclogite-facies metamorphism is ascribed to subductionand accretion around 565 Ma. Post-peak metamorphic K-metasomatismunder amphibolite-facies conditions is ascribed to the intrusionof post-orogenic granite at c. 480 Ma. The recognition of extensivePan-African tectonism in the Maud Belt casts doubts on previousRodinia reconstructions, in which this belt takes a pivotalposition between East Antarctica, the Kalahari Craton and Laurentia.Evidence of late Mesoproterozoic high-grade metamorphism duringthe formation of the Maud Belt exists in the form of c. 1035Ma zircon overgrowths that are probably related to relics ofgranulite-facies metamorphism recorded from other parts of theMaud Belt. The polymetamorphic rocks are largely derived froma c. 1140 Ma volcanic arc and 1072 ± 10 Ma granite. KEY WORDS: Maud Belt; Pan-African orogeny; geochronology; PTt path, East Antarctica 相似文献