The Coolgardie Goldfied,Western Australia: district-scale controls on an Archaean gold camp in an amphibolite facies terrane

Archaean lode gold deposits in the Coolgardie Goldfield, Western Australia, occur in mafic and ultramafic rocks which have been metamorphosed to the amphibolite facies. Mineralisation was broadly synchronous with peak metamorphism, the main phase of granitoid emplacement, and regional deformation. Several different structural styles are represented by the deposits of the Coolgardie Goldfield. Mineralisation occurs along sheared felsic porphyry-ultramafic rock contacts, in gabbro-hosted quartz-vein sets, in fault-bounded quartzvein sets, and in laminated quartz reefs sited in brittleductile shear zones. The structures hosting mineralisation formed in response to a progressive deformation event, related to granitoid emplacement in an east-west compressional far-field stress régime, but with local heterogeneous stress orientations. This occurred after an earlier period of thrust-stacking, with probable north-south directed tectonic transport. Two contrasting styles of goldrelated wallrock alteration are associated with the auriferous lodes of the Coolgardie Goldfield. A high-temperature assemblage (formation temperature >500°C), characterised by the proximal alteration assemblage garnet+ hornblende + plagioclase + pyrrhotite, contrasts with a medium-temperature assemblage (formation temperature <500°C), consisting of calcic amphibole + biotite + plagioclase + calcite + arsenopyrite + pyrrhotite. The distribution of the two styles of gold-related alteration is controlled by distance from voluminous syntectonic granitoids located to the west of the Coolgardie Goldfield, with the high-temperature style of alteration more proximal to the granitoid-greenstone contact than the medium-temperature style. The occurrence of gold deposits that formed under amphibolite facies conditions throughout the Coolgardie Goldfield supports a crustal continuum model for Archaean lode-gold deposits, which proposes that gold is deposited in metamorphic environments that range from the sub-greenschist to granulite facies. In addition, the data from Coolgardie suggest that syntectonic, synmineralisation granitic plutons may play a significant role in controlling the style of gold associated wallrock-alteration at deep crustal levels.     

Source(s) and cycling of the nonhydrolyzable organic fraction of oceanic particles

A major fraction of particulate organic carbon (POC) in the deep ocean remains molecularly uncharacterized. In an effort to determine the chemical characteristics and source(s) of sinking POC, we studied a nonhydrolyzable fraction of sinking POC using ¹³C NMR (nuclear magnetic resonance) spectroscopy and analytical pyrolysis. ¹³C NMR spectra and products from analytical pyrolysis of the nonhydrolyzable fraction exhibit a strongly aliphatic character that is distinct from that of bulk POC. The aliphatic nature of this fraction is consistent with its low stable carbon isotope values. We hypothesize that the nonhydrolyzable fraction derives to a significant extent from a refractory component of organisms that selectively accumulates, resulting in its manifestation as a major part of POC sinking to the deep ocean and in underlying sediments.     

The geochemistry of uranium occurrences and speciation in groundwater of Chinnar sub basin,South India

An attempt has been made in Chinnar sub basin of Dharmapuri district, South India to isolate the geochemistry of uranium occurrences in groundwater. The geology of the area is mainly of charnockite and granite gneiss. Groundwater samples were collected for two different seasons post and pre monsoon in two different litho units (granite gneiss and charnockite) and analysed for major, minor and uranium concentrations. Higher uranium (18.45 μg L^?1) has been recorded during pre monsoon season in granite gneiss with increasing pH. The saturation index calculation for the groundwater isolated minerals like uaraninite, coffinite, haiweeite and soddyite to be precipitating and uranium oxides like UO_2.25, UO_2.25beta, UO_2.33beta as oversaturated. The Eh-pH diagram attempted represents solubility of uraninite within the pH range of 6.0 to 8.0. The study isolate uranium in groundwater of the study area is controlled by the presence of (U₄O₉) uranium oxide.     

Factors controlling the adsorption of acid blue 113 dye from aqueous solution by dried <Emphasis Type="Italic">C. edulis</Emphasis> plant as natural adsorbent

Contamination of surface water and groundwater by organic pollutants is a serious problem due to their persistence, bioaccumulation and biomagnification through food webs. Since the removal of dyes from wastewater is considered an environmental challenge and government legislation requires textile wastewater to be treated, therefore there is a constant need to have an effective process that can efficiently remove these dyes. The aim of the present study is to evaluate the potentiality of dried Carpobrotus edulis plant as low-cost adsorbent for the removal of the industrial acid blue 113 dye from aqueous solutions using the batch equilibration technique. The effects of different physicochemical parameters such as adsorbent dose, contact time, initial dye concentration, solution pH and temperature on adsorption rate of anionic AB113 dye on microparticles of dried C. edulis plant were investigated. The experimental data were analyzed by using mathematical models to determine the thermodynamic parameters. The negative values of free energy change indicated the spontaneous nature of the adsorption and negative value of enthalpy change suggested the exothermic nature of the adsorption process. These results indicate that dried C. edulis plant as an environmentally friendly adsorbent could be potentially used for the removal of anionic dyes from aqueous solutions.     

Hydrothermal bitumen generated from sedimentary organic matter of rift lakes – Lake Chapala, Citala Rift, western Mexico

Lake Chapala is in the Citala Rift of western Mexico, which in association with the Tepic-Zacoalco and Colima Rifts, form the well-known neotectonic Jalisco continental triple junction. The rifts are characterized by evidence for both paleo- and active hydrothermal activity. At the south shore of the lake, near the Los Gorgos sublacustrine hydrothermal field, there are two tar emanations that appear as small islands composed of solid, viscous and black bitumen. Aliquots of tar were analyzed by GC-MS and the mixtures are comprised of geologically mature biomarkers and an UCM. PAH and n-alkanes are not detectable. The biomarkers consist mainly of hopanes, gammacerane, tricyclic terpanes, carotane and its cracking products, steranes, and drimanes. The biomarker composition and bulk C isotope composition (δ¹³C = −21.4%) indicate an organic matter source from bacteria and algae, typical of lacustrine ecosystems. The overall composition of these tars indicates that they are hydrothermal petroleum formed from lacustrine organic matter in the deeper sediments of Lake Chapala exceeding 40 ka (¹⁴C) in age and then forced to the lakebed by tectonic activity. The absence of alkanes and the presence of an UCM with mature biomarkers are consistent with rapid hydrothermal oil generation and expulsion at temperatures of 200–250 °C. The occurrence of hydrothermal petroleum in continental rift systems is now well known and should be considered in future energy resource exploration in such regions.     

Multi-isotopic (Li,B, Sr,Nd) approach for geothermal reservoir characterization in the Limagne Basin (Massif Central,France)

A multi-isotopic study of thermo-mineral waters from the Limagne Basin (French Massif Central) is reported. Lithium, B, Sr and Nd isotopic signatures in thermo-mineral waters and bedrocks were combined in order to determine the origin of these fluids from a reservoir point of view. Strontium and Nd isotopic systems showed that the thermo-mineral waters are mostly derived from a granitic reservoir type, with the exception of a few water samples having Sr and Nd isotopic signatures also reflecting a volcanic contribution (basalts). In a second step, Li and B isotopes were investigated, given that Li and B isotopic systematics are potentially affected by mass dependent fractionation during water/rock interaction and could provide some information on what takes place during this process. A great diversity of thermo-mineral waters within the Aigueperse area was clearly observed, which is directly related to the origin of these thermal waters in terms of reservoirs. These different geothermal reservoirs are characterized by different geological settings and intensity of water/rock interaction (i.e. depth and temperature).     

Unstable climates: Exploring the statistical and social constructions of ‘normal’ climate

The idea of climate has both statistical and social foundations. Both of these dimensions of climate change over time: climate, as defined by meteorological statistics, changes for both natural and anthropogenic reasons; and our expectations of future climate also change, as cultures, societies and knowledge evolves. This paper explores the interactions between these different expressions of climate change by focusing on the idea of ‘normal’ climates defined by statistics. We show how this idea came into being in meteorological circles and then review how this idea of climatic normality gets entangled with cultural and psychological processes. Using data from historical and predicted climates in the UK, we illustrate the significance of choosing different baseline ‘normals’ for retrospective and prospective interpretations of climate change. Since the choice of these statistical ‘normals’ reflects cultural, political and psychological preferences and practices as much as scientific ones, we argue that expectations of the climatic future are influenced by social as well as statistical norms. Seeing climate as co-constructed between the psycho-cultural constraints of society and the physical constraints of the material world offers a different way of thinking about the instabilities of climate and the ways we adapt to them.     

Hypoxia in the northern Gulf of Mexico: Does the science support the Plan to Reduce,Mitigate, and Control Hypoxia?

We update and reevaluate the scientific information on the distribution, history, and causes of continental shelf hypoxia that supports the 2001 Action Plan for Reducing, Mitigating, and Controlling Hypoxia in the Northern Gulf of Mexico (Mississippi River/Gulf of Mexico Watershed Nutrient Task Force 2001), incorporating data, publications, and research results produced since the 1999 integrated assessment. The metric of mid-summer hypoxic area on the LouisianaTexas shelf is an adequate and suitable measure for continued efforts to reduce nutrients loads from the Mississippi River and hypoxia in the northern Gulf of Mexico as outlined in the Action Plan. More frequent measurements of simple metrics (e.g., area and volume) from late spring through late summer would ensure that the metric is representative of the system in any given year and useful in a public discourse of conditions and causes. The long-term data on hypoxia, sources of nutrients, associated biological parameters, and paleoindicators continue to verify and strengthen the relationship between the nitratenitrogen load of the Mississippi River, the extent of hypoxia, and changes in the coastal ecosystem (eutrophication and worsening hypoxia). Multiple lines of evidence, some of them representing independent data sources, are consistent with the big picture pattern of increased eutrophication as a result of long-term nutrient increases that result in excess carbon production and accumulation and, ultimately, bottom water hypoxia. The additional findings arising since 1999 strengthen the science supporting the Action Plan that focuses on reducing nutrient loads, primarily nitrogen, through multiple actions to reduce the size of the hypoxic zone in the northern Gulf of Mexico.