P-T-X conditions of hydrothermal fluids and precipitation mechanism of stibnite-gold mineralization at the Wiluna lode-gold deposits,Western Australia: conventional and infrared microthermometric constraints

The Wiluna lode-gold deposits are located in the Archean Wiluna greenstone belt, in the northern sector of the Norseman-Wiluna belt in the Yilgarn Craton of Western Australia. They are hosted in subgreenschist facies meta-basalts, and controlled by the Wiluna strike-slip fault system and associated shear veins and breccias. The 13 individual lode-gold deposits have produced around 115 t Au from 1901 to 1946 and 1986 to today. Historically, they also produced 38.3 t As and 3.5 t Sb. Gold formed in two stages: stage 1 gold-pyrite-arsenopyrite is finely disseminated in the wallrock and breccia fragments, whereas stage 2 gold-stibnite is located in massive shear veins and breccia matrix, as fracture-fill and in banded-colloform textured veins. Stibnite-gold orebodies only occur in some of the deposits (e.g., Moonlight and northern part of the West Lode) and also display a restricted vertical extent, being preserved only in the uppermost 200 m of stibnite-bearing lodes.Petrographic, conventional, and infrared microthermometric and laser-Raman analysis on stibnite-bearing quartz veins and breccias reveal that the antimony- and gold-rich hydrothermal fluid was of mixed H₂O-NaCl-CO₂±CH₄ type. Microthermometric measurements reveal maximum homogenization temperatures of 340 °C (average 290±25 °C), and a wide range of salinities between 0.2 and 23 eq. wt% NaCl. Aqueous-carbonic fluid inclusions contain variable X_CO2+CH4 (0.03 to 0.82), with the carbonic phase containing a maximum X_CH4 of 0.21.Combined petrographic and microthermometric evidence suggests that the fluid inclusion properties reflect fluid immiscibility of a low-salinity, medium X_CO2+CH4, homogeneous parent fluid at about 290 °C and pressures between 700 and 1,700 bar. Fluid immiscibility was triggered by cyclic pressure release during fault-zone movement. The decompression (adiabatic cooling) of the hydrothermal fluids shifted the ore fluid to lower temperatures, significantly reduced the degree of stibnite undersaturation, and caused stibnite to precipitate. The deposition of stibnite reduced the ore-fluid H₂S concentration, thereby destabilized gold bisulfide complexes in solution, and caused gold precipitation locally. This mechanism explains the intimate spatial association of stibnite and gold in quartz veins and breccias in the stibnite-gold orebodies at Wiluna.Editorial handling: B. Lehmann     

Exsolution and coarsening in iron-free clinopyroxene during isothermal annealing

Exsolution and coarsening in Fe-free clinopyroxene of composition En_45.1Di_54.9 was studied at temperatures of 1300, 1200, and 1100°C, and annealing times between 10 min and 4320 h. Based on the wavelength of the exsolution lamellae, the exsolution process can be divided into exsolution sensu stricto and coarsening. During exsolution sensu stricto, the average wavelength of the “001” and “100” lamellae remains constant in contrast to the subsequent coarsening process. A progressive development of the microstructure is observed before coarsening which includes formation of island-like regions of dark contrast without phase separation, occurrence of pigeonite and diopside domains predominantly elongated along (100), formation of “100” exsolution lamellae, dissolution of the “100” lamellae, and predominant occurrence of “001” exsolution lamellae. All observations are in accordance with the exsolution mechanism of spinodal decomposition. After termination of the exsolution process, coarsening of the exsolution lamellae is observed. The “001” lamellae coarsen according to the rate law

     

Tracing element sources of hydrothermal mineral deposits: REE and Y distribution and Sr-Nd-Pb isotopes in fluorite from MVT deposits in the Pennine Orefield,England

Fluorite from Mississippi Valley Type (MVT) deposits in the South Pennine Orefield, England, displays significantly different distributions of rare earths and yttrium (REY) compared to fluorite from similar MVT deposits in the North Pennine Orefield. Samples from the South Pennine Orefield display negative Ce and positive Gd and Y anomalies but lack any Eu anomaly, indicating that the REY were mobilized from relatively pure marine sedimentary carbonates. In marked contrast, fluorite from the North Pennine Orefield lacks any Ce and Gd anomalies but shows a pronounced positive Eu anomaly, suggesting that the REY were provided by different source rock(s), that the mineralizing hydrothermal fluid had experienced higher temperatures prior to fluorite precipitation, and that it was derived from deeper crustal levels in the north compared to the south. The isotopic composition of Sr in Blue John fluorite from the South Pennine Orefield suggests that Sr was mobilized from Lower Carboniferous (Tournaisian) limestones, whereas Pb isotopes suggest that in contrast to REY and Sr, Pb was derived from aluminosilicate rocks. Neither Nd nor Sr or Pb isotopes can be used to radiometrically date the formation of Blue John fluorite. All isotope systems studied indicate that the limestone host rock of this fluorite mineralization did not contribute to the trace element budget of the hydrothermal fluid. Our results show that different solutes in a natural water (hydrothermal fluid, groundwater, etc.) may be derived from different sources, and that the study of a small set of elements or isotope ratios may not provide full insight into the genesis or history of a mineralization or a hydrothermal fluid. Our data provide evidence for the uncoupling of Sr, Nd and Pb during fluid-rock interaction and fluid migration, and show that the use of plots such as ⁸⁷Sr/⁸⁶Sr vs. _Nd. to learn about mixing relationships (as is commonly done in igneous geochemistry) is unreliable when applied to natural waters and their precipitates.Editorial handling: B. Lehmann     

Comptel Constraints on Unidentified EGRET Sources

A major legacy of the EGRET experiment aboard the Compton Gamma-Ray Observatory (CGRO) is the detection of a large number of unidentified Gamma-ray sources. Out of the 271 EGRET sources are 170 not identified yet [Hartman et al. ApJS (123) (1999) 79]. To provide additional information on these unidentified EGRET sources, we derived simultaneous MeV fluxes or flux limits for each source by analyzing the contemporaneous COMPTEL data. Then we compare these MeV fluxes to the extrapolations of the published EGRET spectra. Our results can be grouped into 4 categories [Zhang et al. A&A (421) (2004) 983]: (1) non-constraining upper limits (∼120 sources), (2) hints (> 2 sigma) or detections with consistent MeV fluxes (∼16 sources), (3) enhanced MeV emission (2 sources), and (4) constraining MeV flux limits, requiring a spectral break (∼22 sources). In summary, for about 40 of the unidentified EGRET sources we can provide supplementary spectral information in the neighboring gamma-ray band, which – together with other source parameters – might provide clues to the underlying source nature.     

Tributyltin release from harbour sediments--modelling the influence of sedimentation, bio-irrigation and diffusion using data from Bremerhaven

This study describes the potential release of TBT from harbour sediments based on model calculations for different sediment management scenarios applying a numerical one-dimensional FD-model. A conceptual model was developed focussing on the following processes involved in the transport of TBT: sorption equilibrium, diffusion, irrigation and sedimentation. Assuming TBT-concentration of 292 microg/kg in the sediment, the diffusive release of TBT from sediments into the bottom water was calculated to 7.4 x 10(-7)-6.9 x 10(-6)mol m(-2) after 1 year and 7.4 x 10(-6)-1.6 x 10(-4)mol m(-2) after 100 years. In these scenarios, neither sedimentation nor capping were considered. Assuming a sedimentation at a rate of 1cm/a, the polluted sediments will be covered with TBT-free suspended matter. A diffusive release of TBT will be prevented if no bio-irrigation takes place. Capping with a layer of sand of 50 cm thickness will decrease the diffusive release. If a reactive capping could be applied, the release of TBT into the bottom water would be stopped almost completely. The study shows that our model calculations enables us to compare different scenarios in sediment management based on available data. Additionally, it can provide information for risk assessment in the absence of data.     

Numerical investigation of seawater intrusion at Gooburrum,Bundaberg, Queensland,Australia

Seawater intrusion in coastal agricultural areas due to groundwater abstraction is a major environmental problem along the northeastern coast of Australia. Management options are being explored using numerical modelling, however, questions remain concerning the appropriate level of sophistication in models, choice of seaward boundary conditions, and how to accommodate heterogeneity and data uncertainty. The choice of seaward boundary condition is important since it affects the amount of salt transported into the aquifers and forms the focus of the present study. The impact of this boundary condition is illustrated for the seawater-intrusion problem in the Gooburrum aquifers, which occur within Tertiary sedimentary strata. A two-dimensional variable-density groundwater and solute-transport model was constructed using the computer code 2DFEMFAT (Cheng et al. 1998). The code was tested against an experiment for a steady-state freshwater-saltwater interface and against the Elder (Elder 1967) free-convection problem. Numerical simulations show that the imposition of the commonly-used equivalent hydrostatic freshwater heads, combined with a constant salt concentration at the seaward boundary, results in overestimated seawater intrusion in the lower Gooburrum aquifer. Since the imposition of this boundary condition allows water flow across the boundary, which subsequently takes salt into the aquifer, a careful check is essential to estimate whether too much mass of salt is introduced.

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Resumen La intrusión de agua salada en áreas agrícolas costeras a causa de la abstracción de aguas subterráneas es un problema medioambiental mayor a lo largo de la costa noreste de Australia. Se están explorando opciones de manejo mediante el uso de modelos numéricos, sin embargo, quedan pendientes cuestionamientos con respecto al nivel apropiado de sofisticación de los modelos, la elección de condiciones de límites hacia el mar y cómo acomodar la heterogeneidad y la incertidumbre de los datos. La elección de límites hacia el mar es importante ya que afecta la cantidad de sal transportada a los acuíferos y forma el centro de interés del presente estudio. Se ilustra el impacto de esta condición de límites para el problema de la intrusión de agua de mar en los acuíferos de Gooburrum, Queensland, Australia. Se construyó un modelo de transporte de solutos y de densidad variable de aguas subterráneas de dos dimensiones mediante el uso del código de computación 2DFEMFAT. El código se probó contra un experimento para una interfase de agua salada-agua dulce de estado constante y contra el problema de Elder de convexión libre. Las simulaciónes numéricas muestran que las cimas de agua dulce hidrostáticas equivalentes utlizadas comúnmente combinadas con una concentración de sal constante en el límite hacia el mar resultan en una sobreestimación de la intrusión de agua de mar en el acuífero bajo de Gooburrum. Puesto que la imposición de esta condición de límites permite flujo de agua a través de los límites, el cual subsecuentemente transporta sal al acuífero, una verificación cuidadosa es esencial para estimar si se introduce demasiada masa de sal.

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Résumé Investigations numériques de lintrusion deau de mer à Gooburrum, Bundaberg, Queensland. Lintrusion deau salée due au captage deau souterraine dans les régions agricoles situées le long de la côte Nord-Est de lAustralie est un grave problème environnemental. Des solutions à ce problème sont présentement étudiées à laide de la modélisation numérique. Cependant des questions subsistent concernant le niveau de sophistication du modèle, le choix des limites le long de lintrusion salée et la manière daccommoder lhétérogénéité et lincertitude des données. Le choix de la limite le long de lintrusion deau salée est important puisque cette limite détermine la quantité de sel transporté dans laquifère et constitue le sujet de la présente étude. Leffet du choix de cette limite est bien illustré par le problème dintrusion deau salée dans les aquifères de Gooburrum, Queensland, Australie. Un modèle bidimensionnel découlement à densité variable et de transport de solutés a été conçu en utilisant le code 2DFEMFAT. Ce code a été testé avec une expérimentation ayant pour objet lécoulement en régime permanent dune interface eau salée/eau douce. Il a aussi été mis à lépreuve par le problème de convection libre de Elder. Les simulations numériques révèlent que limposition de la limite communément utilisée, quon appelle la «charge hydrostatique équivalente deau douce», conduit, dans le cas o lon a une concentration constante en sels le long de lintrusion deau salée, à une surestimation de lintrusion deau salée dans laquifère inférieur de Gooburrum. Puisque que cest limposition de cette limite qui permet lécoulement de leau au-delà de la frontière de laquifère, ce qui introduit subséquemment du sel dans laquifère, une vérification minutieuse doit tre effectuée afin de contrôler la quantité de sel introduit.

     

Nutrient dynamics in the Pomeranian Bay (southern Baltic): Impact of the Oder River outflow

The Pomeranian Bay is a coastal region fed by the Oder River, one of the seven largest Baltic rivers, whose waters flow through a large and complex estuarine system before entering the bay. Nutrients (NO₃ ⁻, NO₂ ⁻, NH₄ ⁺, Ntot, PO₄ ³⁻, P_tot, DSi), chlorophylla concentrations, oxygen content, salinity, and temperature were measured in the Pomeranian Bay in nine seasonally distributed cruises during 1993–1997. Strong spatial and temporal patterns were observed and they were governed by: the seasonally variable riverine water-nutrient discharges, the seasonally variable uptake of nutrients and their cycling in the river estuary and the Bay, the character of water exchange between the Pomeranian Bay and the Szczecin Lagoon, and the water flow patterns in the Bay that are dominated by wind-driven circulation. Easterly winds resulted in water and nutrient transport along the German coastline, while westerly winds confined the nutrient rich riverine waters to the Polish coast and transported them eastward beyond the study area. Two water masses, coastal and open, characterized by different chemical and physical parameters and chla content were found in the Bay independently of the season. The role of the Oder estuary in nutrient transformation, as well as the role of temperature in transformation processes is stressed in the paper. The DIN:DIP:DSi ratio indicated that phosphorus most probably played a limiting role in phytoplankton production in the Bay in spring, while nitrogen did the same in summer. During the spring bloom, predominated by diatoms, the DSi:DIN ratio dropped to 0.1 in the coastal waters and to 0.6 in the open bay waters, pointing to silicon limitation of diatom growth, similar to what is being observed in other Baltic regions.     

Tidal effects on groundwater dynamics in unconfined aquifers

The variation of seawater level resulting from tidal fluctuations is usually neglected in regional groundwater flow studies. Although the tidal oscillation is damped near the shoreline, there is a quasi‐steady‐state rise in the mean water‐table position, which may have an influence on regional groundwater flow. In this paper the effects of tidal fluctuations on groundwater hydraulics are investigated using a variably saturated numerical model that includes the effects of a realistic mild beach slope, seepage face and the unsaturated zone. In particular the impact of these factors on the velocity field in the aquifer is assessed. Simulations show that the tidal fluctuation has substantial consequences for the local velocity field in the vicinity of the exit face, which affects the nearshore migration of contaminant in coastal aquifers. An overheight in the water table as a result of the tidal fluctuation is observed and this has a significant effect on groundwater discharge to the sea when the landward boundary condition is a constant water level. The effect of beach slope is very significant and simplifying the problem by considering a vertical beach face causes serious errors in predicting the water‐table position and the groundwater flux. For media with a high effective capillary fringe, the moisture retained above the water table is important in determining the effects of the tidal fluctuations. Copyright © 2001 John Wiley & Sons, Ltd.