Formation of carbonate concretions in surface sediments of two mud mounds,offshore Costa Rica: a stable isotope study

The surface sediments of two mud mounds (“Mound 11” and “Mound 12”) offshore southwest Costa Rica contain abundant authigenic carbonate concretions dominated by high-Mg calcite (14–20 mol-% MgCO₃). Pore fluid geochemical profiles (sulfate, sulfide, methane, alkalinity, Ca and Mg) indicate recent carbonate precipitation within the zone of anaerobic oxidation of methane (AOM) at variable depths. The current location of the authigenic carbonate concretions is, however, not related to the present location of the AOM zone, suggesting mineral precipitation under past geochemical conditions as well as changes in the flow rates of upward migrating fluids. Stable oxygen and carbon isotope analysis of authigenic carbonate concretions yielded δ¹⁸O_carbonate values ranging between 34.0 and 37.7 ‰ Vienna standard mean ocean water (VSMOW) and δ¹³C_carbonate values from ?52.2 to ?14.2 ‰ Vienna Pee Dee belemnite (VPDB). Assuming that no temperature changes occurred during mineral formation, the authigenic carbonate concretions have been formed at in situ temperature of 4–5 °C. The δ¹⁸O_carbonate values suggest mineral formation from seawater-derived pore fluid (δ¹⁸O_porefluid = 0 ‰ VSMOW) for Mound 12 carbonate concretions but also the presence of an emanating diagenetic fluid (δ¹⁸O_porefluid ≈5 ‰) in Mound 11. A positive correlation between δ¹³C_carbonate and δ¹⁸O_carbonate is observed, indicating the admixing of two different sources of dissolved carbon and oxygen in the sediments of the two mounds. The carbon of these sources are (1) marine bicarbonate (δ¹³C_porefluid ≈0 ‰) and (2) bicarbonate which formed during the AOM (δ¹³C_porefluid ≈?70 ‰). Furthermore, the δ¹⁸O_porefluid composition, with values up to +4.7 ‰ Vienna standard mean ocean water (VSMOW), is interpreted to be affected by the presence of emanating, freshened and boron-enriched fluids. Earlier, it has been shown that the origin of ¹⁸O-enriched fluids are deep diagenetic processes as it was indicated by the presence of methane with thermogenic signature (δ¹³C_CH4 = ?38 ‰). A combination of present geochemical data with geophysical observations indicates that Mounds 11 and 12 represent a single fluid system interconnected by deep-seated fault(s).     

Assessing Possibilities and Limitations for Biomarker Analyses on Outcrop Samples: A Case Study on Carbonates of the Shibantan Member (Ediacaran Period,Dengying Formation,South China)

Abstract: The Shibantan Member (Dengying Formation, South China) represents one of only two carbonate settings with Ediacara-type organisms and offers a rare opportunity to study the biogeochemistry of these ecosystems. To evaluate possibilities and limitations for future biomarker studies on fossil-bearing outcrop samples of the Shibantan Member, we analysed the spatial distribution of hydrocarbons in extractable organic matter (i.e. bitumen) on a millimetre scale. Our study demonstrates that the sample and most likely also other rocks from the same setting are contaminated with petroleum-derived compounds that bear the potential for erroneous interpretations in palaeo-reconstructions. The contamination was revealed by distribution patterns and amounts of extractable n-alkanes and acyclic isoprenoids. The contamination is linked to the external weathering surfaces but also to cracks within the rock, and the extent most likely depends on concentration gradients between these contamination sources. Here we show that contamination can successfully be distinguished from syngenetic signals obtained from non-extractable organic matter (i.e. kerogen) using catalytic hydropyrolysis (HyPy). However, we observed that decalcification is necessary to achieve sufficient yields of kerogen-bound hydrocarbons and to avoid artificial alteration of the biomarker signals due to matrix effects.     

Economic evaluation of structural and non-structural flood risk management measures: examples from the Mulde River

The concept of flood risk management, promoted by the EU Floods Directive, tries to mitigate flood risks not only by structural, hydraulic engineering measures, but also by non-structural measures, like, e.g., land-use planning, warning and evacuation systems. However, few methods currently exist for the economic evaluation of such non-structural measures and, hence, their comparison with structural measures. The objective of this paper is to demonstrate the potential benefits of employing a wider range of economic appraisal methods for flood projects, in particular, it provides examples and applications of methodologies which may be employed to evaluate non-structural measures and their transaction costs. In two case studies at the Mulde River, Germany, two non-structural measures, a resettlement option and a warning system, are evaluated and compared with structural alternatives with regard to their effectiveness, cost-effectiveness and efficiency. Furthermore, a simple approach is tested in order to show the transaction costs of these measures. Case study results show that the choice of evaluation criteria can have a major impact on the assessment results. In this regard, efficiency as an evaluation criterion can be considered as superior to cost-effectiveness and effectiveness as it is also able to consider sufficiently the impacts of non-structural measures. Furthermore, case study results indicate that transaction costs could play an important role, especially with non-structural measures associated with land-use changes. This could explain why currently these kinds of measures are rarely selected by decision makers.     

Stable carbon isotopic ratios of CH4-CO2-bearing fluid inclusions in fracture-fill mineralization from the Lower Saxony Basin (Germany) - A tool for tracing gas sources and maturity

The stable carbon isotopic ratios (δ¹³C) of methane (CH₄) and carbon dioxide (CO₂) of gas-rich fluid inclusions hosted in fracture-fill mineralization from the southern part of the Lower Saxony Basin, Germany have been measured online using a crushing device interfaced to an isotopic ratio mass spectrometer (IRMS). The data reveal that CH₄ trapped in inclusions seems to be derived from different source rocks with different organic matter types. The δ¹³C values of CH₄ in inclusions in quartz hosted by Carboniferous rocks range between −25 and −19‰, suggesting high-maturity coals as the source of methane. Methane in fluid inclusions in minerals hosted by Mesozoic strata has more negative carbon isotope ratios (−45 to −31‰) and appears to represent primary cracking products from type II kerogens, i.e., marine shales. There is a positive correlation between increasing homogenization temperatures of aqueous fluid inclusions and less negative δ¹³C(CH₄) values of in co-genetic gas inclusions probably indicating different mtaturity of the potential source rocks at the time the fluids were released. The CO₂ isotopic composition of CH₄-CO₂-bearing inclusions shows slight negative or even positive δ¹³C values indicating an inorganic source (e.g., water-rock interaction and dissolution of detrital, marine calcite) for CO₂ in inclusions. We conclude that the δ¹³C isotopic ratios of CH₄-CO₂-bearing fluid inclusions can be used to trace migration pathways, sources of gases, and alteration processes. Furthermore, the δ¹³C values of methane can be used to estimate the maturity of the rocks from which it was sourced. Results presented here are further supported by organic geochemical analysis of surface bitumens which coexist with the gas inclusion-rich fracture-fill mineralization and confirm the isotopic interpretations with respect to fluid source, type and maturity.     

Observing Gravity Change in the Fennoscandian Uplift Area with the Hanover Absolute Gravimeter

The Nordic countries Norway, Sweden, Finland and Denmark are a key study region for research of glacial isostasy. In addition, such research offers a unique opportunity for absolute gravimetry to show its capability as a geodetic tool for geophysical research. Within a multi-national cooperation, annual absolute gravity measurements have been performed in Fennoscandia by IfE since 2003. For the Hanover gravimeter FG5-220, overall accuracy of ±30?nm/s² is indicated for a single station determination. First results of linear gravity changes are derived for ten stations in the central and southern part of the uplift area. Comparing with the rates predicted by glacial rebound modelling, the gravity trends of the absolute measurements differ by 3.8?nm/s² per year (root-mean-square discrepancy) from the uplift model. The mean difference between observed and predicted rates is 0.8?nm/s² per year only. A proportionality factor of ?1.63?±?0.20?nm/s² per mm has been obtained, which describes the mean ratio between the observational gravity and height rates.     

The fine-grained phase-space structure of cold dark matter haloes

We present a new and completely general technique for calculating the fine-grained phase-space structure of dark matter (DM) throughout the Galactic halo. Our goal is to understand this structure on the scales relevant for direct and indirect detection experiments. Our method is based on evaluating the geodesic deviation equation along the trajectories of individual DM particles. It requires no assumptions about the symmetry or stationarity of the halo formation process. In this paper we study general static potentials which exhibit more complex behaviour than the separable potentials studied previously. For ellipsoidal logarithmic potentials with a core, phase mixing is sensitive to the resonance structure, as indicated by the number of independent orbital frequencies. Regions of chaotic mixing can be identified by the very rapid decrease in the real-space density of the associated DM streams. We also study the evolution of stream-density in ellipsoidal NFW haloes with radially varying isopotential shape, showing that if such a model is applied to the Galactic halo, at least 10⁵ streams are expected near the Sun. The most novel aspect of our approach is that general non-static systems can be studied through implementation in a cosmological N -body code. Such an implementation allows a robust and accurate evaluation of the enhancements in annihilation radiation due to fine-scale structure such as caustics. We embed the scheme in the current state-of-the-art code gadget -3 and present tests which demonstrate that N -body discreteness effects can be kept under control in realistic configurations.     

The Aspen–Amsterdam void finder comparison project

Despite a history that dates back at least a quarter of a century, studies of voids in the large-scale structure of the Universe are bedevilled by a major problem: there exist a large number of quite different void-finding algorithms, a fact that has so far got in the way of groups comparing their results without worrying about whether such a comparison in fact makes sense. Because of the recent increased interest in voids, both in very large galaxy surveys and in detailed simulations of cosmic structure formation, this situation is very unfortunate. We here present the first systematic comparison study of 13 different void finders constructed using particles, haloes, and semi-analytical model galaxies extracted from a subvolume of the Millennium simulation. This study includes many groups that have studied voids over the past decade. We show their results and discuss their differences and agreements. As it turns out, the basic results of the various methods agree very well with each other in that they all locate a major void near the centre of our volume. Voids have very underdense centres, reaching below 10 per cent of the mean cosmic density. In addition, those void finders that allow for void galaxies show that those galaxies follow similar trends. For example, the overdensity of void galaxies brighter than   m _B =−20  is found to be smaller than about −0.8 by all our void finding algorithms.     

The fossil phase in the life of a galaxy group

We investigate the origin and evolution of fossil groups in a concordance ΛCDM cosmological simulation. We consider haloes with masses between  1 × 10¹³  and  5 × 10¹³  h ⁻¹ M_⊙  , and study the physical mechanisms that lead to the formation of the large gap in magnitude between the brightest and the second most bright group member, which is typical for these fossil systems. Fossil groups are found to have high dark matter concentrations, which we can relate to their early formation time. The large magnitude gaps arise after the groups have built up half of their final mass, due to merging of massive group members. We show that the existence of fossil systems is primarily driven by the relatively early infall of massive satellites, and that we do not find a strong environmental dependence for these systems. In addition, we find tentative evidence for fossil group satellites falling in on orbits with typically lower angular momentum, which might lead to a more efficient merger on to the host. We find a population of groups at higher redshifts that go through a 'fossil phase': a stage where they show a large magnitude gap, which is terminated by renewed infall from their environment.     

Application of a Numerical Inverse Laplace Integration Method to Surface Loading on a Viscoelastic Compressible Earth Model

Normal mode approaches for calculating viscoelastic responses of self-gravitating and compressible spherical earth models have an intrinsic problem of determining the roots of the secular equation and the associated residues in the Laplace domain. To bypass this problem, a method based on numerical inverse Laplace integration was developed by Tanaka et al. (2006, 2007) for computations of viscoelastic deformation caused by an internal dislocation. The advantage of this approach is that the root-finding problem is avoided without imposing additional constraints on the governing equations and earth models. In this study, we apply the same algorithm to computations of viscoelastic responses to a surface load and show that the results obtained by this approach agree well with those obtained by a time-domain approach that does not need determinations of the normal modes in the Laplace domain. Using the elastic earth model PREM and a convex viscosity profile, we calculate viscoelastic load Love numbers (h, l, k) for compressible and incompressible models. Comparisons between the results show that effects due to compressibility are consistent with results obtained by previous studies and that the rate differences between the two models total 10–40%. This will serve as an independent method to confirm results obtained by time-domain approaches and will usefully increase the reliability when modeling postglacial rebound.