Measurements of Rare Earth Element and Other Element Mass Fractions in Environmental Reference Materials (NIST SRM 1646a,NIST SRM 1400, IAEA‐395 and IAEA‐450) by INAA,ICP‐AES and ICP‐MS

INAA, ICP‐AES and ICP‐MS were used to elementally characterise four environmental reference materials – NIST SRM 1646a (Estuarine Sediment), NIST SRM 1400 (Bone Ash), IAEA‐395 (Urban Dust) and IAEA‐450 (Algae). An analytical scheme consisting of the three methods was first applied to NIST SRM 1646a to validate the methodology because it has been extensively analysed and has certified values for many elements. With repeated analyses of NIST SRM 1646a, the accuracy and measurement repeatability of the data obtained were evaluated based on two statistical calculations (zeta‐score and Horwitz ratio) and were observed to be good enough for the analytical scheme to be applied to similar sorts of environmental/geochemical samples. Applying the same approach to NIST SRM 1400, IAEA‐395 and IAEA‐450, enabled mass fractions of 29, 38 and 28 elements to be determined, respectively. Among these results, the data for rare earth elements are of particular interest, not only for IAEA‐450 but also for the other three reference samples. The data for Pr, Gd, Dy, Ho, Er and Tm in NIST SRM 1646a are newly reported in this study. By using small test portions (< 100 mg) for NIST SRM 1646a and IAEA‐395, and recommended minimum amounts for NIST SRM 1400 and IAEA‐450, sample homogeneity was evaluated.     

Synoptic-scale physical mechanisms associated with the Mei-yu front: A numerical case study in 1999

The Mei-yu front system occurring from 23 to 27 June 1999 consists of the Mei-yu front and the dewpoint front, which confine a warm core extending from the eastern flank of the Tibetan Plateau to the west of 145°E. To further understand the synopticscale physical mechanisms associated with the Mei-yu front system, the present study proposes another insight into the physical significance of the x-component relative vorticity (XRV) whose vertical circulation is expected to tilt isentropic surfaces. The XRV equation diagnoses exhibit that the twisting effect of the planetary vorticity (TEPV) is positive along the Mei-yu front and negative in the dewpoint front region, and tilts isentropic surfaces from south to north in the Mei-yu frontal zone. Conversely, the meridional gradient of the atmospheric buoyancy (MGAB) tilts isentropic surfaces in the opposite direction and maintains negative in the regions where the TEPV is positive and vice versa. Thus, the TEPV plays the role of the Mei-yu frontogenesis, whereas the MGAB demonstrates the Meiyu frontolysis factor. Both terms control the evolution of the cross-front circulation. The other terms show much minor contributions in this case study. The present simulations also indicate that the weakening of the upper-level jet evidently induces the weakening of the Mei-yu front and reduces the amplitude of the East Asia cold trough. Furthermore, the impact can also penetrate into the lower troposphere in terms of mesoscale disturbances and precipitation, proving that the upper-level jet imposes a noticeable top-down influence on the Mei-yu front system.     

A k - *epsiv Turbulence Closure Model For The Atmospheric Boundary Layer Including Urban Canopy

A numerical model for the computation of the wind field,air temperature and humidity in the atmospheric boundary layer (ABL) including the urbancanopy was developed for urban climate simulation. The governing equations of the modelare derived by applying ensemble and spatial averages to the Navier–Stokes equation, continuityequation and equations for heat and water vapour transfer in the air. With the spatial averagingprocedure, effects of buildings and other urban structures in the urban canopy can be accounted for byintroducing an effective volume function, defined as the ratio between the volume of air in acomputational mesh over the total volume of the mesh. The improved k - model accounts for the anisotropyof the turbulence field under density stratification. In the improved k - model, the transportof momentum and heat in the vertical direction under density stratification is evaluated based onthe assumption of a near-equilibrium shear flow where transport effects on the stresses andheat fluxes are negligible. The heating processes at surfaces of buildings and ground are alsomodelled. The comparison of the computational results obtained with the present modeland existing observational data and numerical models shows that the present model is capableof predicting the structure of turbulence in the urban canopy layer under density stratification.Numerical experiments with the new model show that the flow behaviour of the air in the urbancanopy layer is strongly affected by the existence of buildings and density stratification.     

Determination des demi-grands axes des satellites galileens de Jupiter

In non-resonant cases, a constant part coming from the perturbations can be easily separated from the observed mean mean motion, which can be called the perturbed part. An another part created by resonance must be separated from the observed mean motion in the case of the first three Galilean satellites. The determination of it gives better value of the semi-major axis.In this investigation, the analytical process is chosen to avoid a mixture of orders in successive expansions and integrations.The main terms entering in the computation of the libration are the great inequalities of the first three satellites. Each of them is introduced in the development by its eight components; while in Sampson's theory, only the great inequality of Satellite 2 is given by two components.The equations of motion used in this work are derived from Sagnier's theory.

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Proceedings of the Conference on Analytical Methods and Ephemerides: Theory and Observations of the Moon and Planets. Facultés universitaires Notre Dame de la Paix, Namur, Belgium, 28–31 July, 1980.     

Modelling of steady‐state fluid flow in 3D fractured isotropic porous media: application to effective permeability calculation

In this paper, 3D steady‐state fluid flow in a porous medium with a large number of intersecting fractures is derived numerically by using collocation method. Fluid flow in the matrix and fractures is described by Darcy's law and Poiseuille's law, respectively. The recent theoretical development presented a general potential solution to model the steady‐state flow in fractured porous media under a far‐field condition. This solution is a hypersingular integral equation with pressure field in the fracture surfaces as the main unknown. The numerical procedure can resolve the problem for any form of fractures and also takes into account the interactions and the intersection between fractures. Once the pressure field and then the flux field in fractures have been determined, the pressure field in the porous matrix is computed completely. The basic problem of a single fracture is investigated, and a semi‐analytical solution is presented. Using the solution obtained for a single fracture, Mori‐Tanaka and self‐consistent schemes are employed for upscaling the effective permeability of 3D fractured porous media. Copyright © 2012 John Wiley & Sons, Ltd.     

Theoretical and numerical study of the steady‐state flow through finite fractured porous media

This paper investigates the two‐dimensional flow problem through an anisotropic porous medium containing several intersecting curved fractures. First, the governing equations of steady‐state fluid flow in a fractured porous body are summarized. The flow follows Darcy's law in matrix and Poiseuille's law in fractures. An infinite transversal permeability is considered for the fractures. A multi‐region boundary element method is used to derive a general pressure solution as a function of discharge through the fractures and the pressure and the normal flux on the domain boundary. The obtained solution fully accounts for the interaction and the intersection between fractures. A numerical procedure based on collocation method is presented to compute the unknowns on the boundaries and on the fractures. The numerical solution is validated by comparing with finite element solution or the results obtained for an infinite matrix. Pressure fields in the matrix are illustrated for domains containing several interconnected fractures, and mass balance at the intersection points is also checked. Copyright © 2013 John Wiley & Sons, Ltd.     

Regional effects of natural disasters in China: investing in post-disaster recovery

We examine the effects of natural disasters on income and investment in China. Using macroeconomic province-level data and the provincial history of disaster exposure over the past two decades, we describe the relationship between disaster mortality and morbidity, disasters’ economic damages, government investment and regional economic activity, and infrastructure development. The Chinese government’s aggressive investment in post-disaster reconstruction is discussed, and the implications of this investment for post-disaster private sector economic activity are analyzed empirically. We further investigate the differential effects of natural disasters on economic activity in China’s diverse geographical regions.

     

Three-dimensional hydrostratigraphical modelling to support evaluation of recharge and saltwater intrusion in a coastal groundwater system in Vietnam

Saltwater intrusion is generally related to seawater-level rise or induced intrusion due to excessive groundwater extraction in coastal aquifers. However, the hydrogeological heterogeneity of the subsurface plays an important role in (non-)intrusion as well. Local hydrogeological conditions for recharge and saltwater intrusion are studied in a coastal groundwater system in Vietnam where geological formations exhibit highly heterogeneous lithologies. A three-dimensional (3D) hydrostratigraphical solid model of the study area is constructed by way of a recursive classification procedure. The procedure includes a cluster analysis which uses as parameters geological formation, lithological composition, distribution depth and thickness of each lithologically distinctive drilling interval of 47 boreholes, to distinguish and map well-log intervals of similar lithological properties in different geological formations. A 3D hydrostratigraphical fence diagram is then generated from the constructed solid model and is used as a tool to evaluate recharge paths and saltwater intrusion to the groundwater system. Groundwater level and chemistry, and geophysical direct current (DC) resistivity measurements, are used to support the hydrostratigraphical model. Results of this research contribute to the explanation of why the aquifer system of the study area is almost uninfluenced by saltwater intrusion, which is otherwise relatively common in coastal aquifers of Vietnam.