Factors influencing methane-derived authigenic carbonate formation at cold seep from southwestern Dongsha area in the northern South China Sea

This paper carried out mineral and geochemical studies on a profile through a diagenetic methane-derived authigenic carbonate sample that was collected from southwestern Dongsha area of the northern South China Sea. Five samples locating in the cross-sectional middle mainly consist of dolomite and quartz, and two samples close to the surface have a small amount of Mg-calcite. The δ¹³C values of the samples vary between ?30.59 and ?0.30 % VPDB, with δ¹⁸O values ranging from 3.07 to 3.59 % VPDB, δ^44/40Ca values ranging from 1.35 to 1.47 % SRM915a, indicating a contribution of methane to the carbon pool where the precipitation of authigenic carbonates occurred. Based on the isotope values alone, it can not be distinguished if the carbon source is thermogenic gas or a mixture of biogenic methane and marine dissolved inorganic carbon. The δ¹⁸O values are in general consistent with dolomite precipitation from a fluid similar to present seawater. The observed small variation might be related to the oxygen isotope composition of seep fluid. The relative small range in calcium isotope values suggests that relatively constant growth conditions and precipitation from seawater. The central part of the carbonate nodule formed under the strong influence of methane seepage, and the external part is less influenced by methane, either due to reduced methane flux to the surface or caused by erosional exhumation of the carbonate nodule from greater depth to the sediment surface.     

A large epeiric methanogenic Bambuí sea in the core of Gondwana supercontinent?

Carbon isotope compositions of both sedimentary carbonate and organic matter can be used as key proxies of the global carbon cycle and of its evolution through time,as long as they are acquired from waters where the dissolved inorganic carbon(DIC)is in isotope equilibrium with the atmospheric CO2.However,in shallow water platforms and epeiric settings,the influence of local to regional parameters on carbon cycling may lead to DIG isotope variations unrelated to the global carbon cycle.This may be especially true for the terminal Neoproterozoic,when Gondwana assembly isolated waters masses from the global ocean,and extreme positive and negative carbon isotope excursions are recorded,potentially decoupled from global signals.To improve our understanding on the type of information recorded by these excursions,we investigate the pairedδ^13Ccarb andδ^13Corg evolution for an increasingly restricted late Ediacaran-Cambrian foreland system in the West Gondwana interior:the basal Bambui Group.This succession represents a 1~(st)-order sedimentary sequence and records two majorδ^13Ccarb excursions in its two lowermost lower-rank sequences.The basal cap carbonate interval at the base of the first sequence,deposited when the basin was connected to the ocean,hosts antithetical negative and positive excursions forδ^13Ccarb andδ^13Corg,respectively,resulting inΔ^13C values lower than 25‰.From the top of the basal sequence upwards,an extremely positiveδ^13Ccarb excursion is coupled toδ^13Corg,reaching values of+14‰and-14‰,respectively.This positive excursion represents a remarkable basin-wide carbon isotope feature of the Bambui Group that occurs with only minor changes inΔ^13C values,suggesting change in the DIC isotope composition.We argue that this regional isotopic excursion is related to a disconnection between the intrabasinal and the global carbon cycles.This extreme carbon isotope excursion may have been a product of a disequilibria between the basin DIC and atmospheric CO2 induced by an active methanogenesis,favored by the basin restriction.The drawdown of sulfate reservoir by microbial sulfate reduction in a poorly ventilated and dominantly anoxic basin would have triggered methanogenesis and ultimately methane escape to the atmosphere,resulting in a^13C-enriched DIC influenced by methanogenic CO2.Isolated basins in the interior of the Gondwana supercontinent may have represented a significant source of methane inputs to the atmosphere,potentially affecting both the global carbon cycle and the climate.     

Introducing new design spectra derived from Italian recorded ground motions 1972 to 2017

The shape of design spectra, traditionally based on regions characterized by constant displacement, constant velocity, and constant acceleration, has been discussed from a conceptual point of view by Calvi (2018). In the same study, a formulation for the definition of the design spectra relying on four parameters was proposed. Predictive models are proposed herein to calculate these four parameters, conditional on magnitude and distance. These models were developed using a large number of recorded ground motions in Italy, and they allow defining combined spectral acceleration versus spectral displacement plots. Such design spectra are shown to reasonably interpolate the experimental data, resulting in acceleration and displacement demand that approximate the response spectra resulting from +1σ results obtained from recorded ground motions. While it is recognized that numerous additional parameter should be considered (eg, focal depth and fault distance, site amplification), it is also concluded that this approach to define the seismic demand is promising toward a rationalization of seismic design. A thorough application of the approach developed and preliminary tested in this work may result in a re‐visitation of seismic design approaches and, ultimately, in a more efficient use of the available resources.     

Evaluation of the seismic risk of the unreinforced masonry building stock in Antioquia,Colombia

This work focuses on the exploitation of very high-resolution (VHR) satellite imagery coupled with multi-criteria analysis (MCA) to produce flood hazard maps. The methodology was tested over a portion of the Yialias river watershed basin (Nicosia, Cyprus). The MCA methodology was performed selecting five flood-conditioning factors: slope, distance to channels, drainage texture, geology and land cover. Among MCA methods, the analytic hierarchy process technique was chosen to derive the weight of each criterion in the computation of the flood hazard index (FHI). The required information layers were obtained by processing a VHR GeoEye-1 image and a digital elevation model. The satellite image was classified using an object-based technique to extract land use/cover data, while GIS geoprocessing of the DEM provided slope, stream network and drainage texture data. Using the FHI, the study area was finally classified into seven hazard categories ranging from very low to very high in order to generate an easily readable map. The hazard seems to be severe, in particular, in some urban areas, where extensive anthropogenic interventions can be observed. This work confirms the benefits of using remote sensing data coupled with MCA approach to provide fast and cost-effective information concerning the hazard assessment, especially when reliable data are not available.     

Modeling Geospatial Uncertainty of Geometallurgical Variables with Bayesian Models and Hilbert–Kriging

Mathematical Geosciences - In mine planning, geospatial estimates of variables such as comminution indexes and metallurgical recovery are extremely important to locate blocks for which the energy...     

Tebuthiuron leaching in three Brazilian soils as affected by soil pH

Underground contamination water by herbicides depends on the interactions between their molecules with physical and chemical soil characteristics and climatic conditions. Studies with columns can estimate the leaching potential of herbicides in soils. This study aimed to determine the effect of soil pH on tebuthiuron leaching, and capacity of bioindicators to detect tebuthiuron residues in three Brazilian soils. Cucumber plants (Cucumis sativus) were more negatively affected when grown in soils with lower amounts of organic matter and clay, and in these soils, the tebuthiuron levels reached greater depths in the column. There was a positive correlation between tebuthiuron concentration and cucumber intoxication, and a negative correlation between tebuthiuron concentration and dry matter cucumber in all soils. The tebuthiuron leached up to 50 cm depth even in soils with higher organic matter and clay content. The increasing of soil pH can affect the leaching of nonionic herbicides, and liming practice may elevate the environmental contamination risk by tebuthiuron. The bioindicator method using Cucumis sativus is viable and can be recommended to detect tebuthiuron concentrations above 0.2 mg kg^?1.     

Modeling the built environment for local to global earthquake risk assessment

Carbonation-induced corrosion of the steel reinforcement is the major deterioration factor of the RC infrastructures in urban areas. Carbonation progress in concrete is influenced by the exposure and environmental conditions prevailing at each area. Therefore, the rate of deterioration due to carbonation varies at different areas. Field measurements can quantify this carbonation progress for specific structures and areas. However, the scattered nature of individual field data offers little information to be considered for the assessment of existing structures or the design of new structures. This study aims to bridge this gap and shows that individual field data can be combined to characterise an area using GIS mapping tools. A generated map can depict the variability of carbonation progress with the geographical location. Measurements of the carbonation depth of several buildings at different locations in the Limassol district have been provided by a construction laboratory. Such information can be used to depict the carbonation progress on each structure through the calculation of the carbonation factor and then portray its value using mapping techniques. The result is a corrosion risk map of the Limassol district depicting the variability of carbonation progress with geographical locations. This can be used by engineers and managing authorities as a prediction tool for the initiation of carbonation-induced corrosion in existing structures and also at design stage to set the durability requirements of the concrete cover depth.     

A large epeiric methanogenic Bambui sea in the core of Gondwana supercontinent?

Carbon isotope compositions of both sedimentary carbonate and organic matter can be used as key proxies of the global carbon cycle and of its evolution through ...     

Effects on runoff caused by changes in land cover in a Brazilian southeast basin: evaluation by HEC-HMS and HEC-GEOHMS

The Southeast Region of Brazil has undergone major changes in land cover, especially after the eighteenth century. It is currently the most populous region of the country, highly urbanized, with a high degree of industrial and agricultural development. Extensive areas of native vegetation have been replaced by pastures, crops and urban areas, which have increased runoff, causing environmental, economic and social problems related to flooding. The objective of this study was to analyze effects of land cover changes in a basin with rural and urban characteristics on the flow of its main river. Hydrological data, orbital images, soils and topographical maps were used for this purpose. Based on the land cover maps for the years of 1989, 2001 and 2015, and on the hydrological modeling performed using the Hec-HMS 4.1 software, scenarios were simulated and showed that the land cover changes in this basin significantly affect the flow behavior of the main river. The simulated runoff was calibrated using the data observed in the field during 2001, and validation was performed using data from 1989. After the calibration and validation processes, a scenario was simulated where the rainiest month of the whole series measured by the rainfall station (during December 1989) acted on the land cover of 2015. There was an increase in pasture areas and impermeable spaces in the basin, which caused a decrease in infiltration and an increase in surface runoff, and also an increase in the flow peaks and a reduction in the time of concentration. The hydrological modeling was satisfactory, since the uncertainties related to the simulation were low.     

Earthquake early warning for Portugal: part 1 - Where does it matter?

Bulletin of Earthquake Engineering - In the last five centuries, Portugal was affected by several earthquakes of strong magnitude (M > 7) that caused widespread destruction and a...