Kinematics in the z = 2.81 Galaxy and the Evidence for Rotation

The existence of rotation signatures in damped Lyαabsorption systems represents a crucial test of the hypothesis that these features arise in disks of normal spiral galaxies. We apply the method for evaluating such signatures to the metal absorption lines in QSO 0528-250. In particular, the systemic redshift of the absorber is inferred from the recent detection of emission in the absorber by Möller and Warren. The kinematics of this absorber are particularly interesting because molecular hydrogen, the densest ISM component of the assumed foreground absorbing galaxy, is detected. Contrary to a recent claim, the method yields a satisfactory value for the assumed rotation velocity of the absorber.     

Studying of liquid thermolysis products of various types of immature kerogen in sedimentary lacustrine rocks from the valjevo-Mionica basin,Serbia, and the effect of Pt<Superscript>4+</Superscript> and Ru<Superscript>3+</Superscript> ions on their yield and the hydrocarbon composition

Liquid thermolysis products of various types of immature kerogen from sedimentary lacustrine rocks from the Valjevo-Mionica basin in Serbia were studied to evaluate the generation potential of kerogen contained in the organic matter (OM) of the rocks, determine the composition of the biomarkers and alkylaromatics in the liquid thermolysis products, and elucidate the effect of Pt⁴⁺ and Ru³⁺ ions (which were added in the form of inorganic salts) on the yield and hydrocarbon composition of the liquid thermolysis products. For this purpose, representative bitumen-free samples A and B of the sedimentary rocks were subjected to thermolysis under various conditions. Rock A contains high amount of immature organic matter, which is dominated by kerogen type I/II and was generated under strongly reduced sedimentation conditions at a high salinity. Sample B is poorer in immature OM than sample A, and the OM of the former contains kerogen type II/III and was generated predominantly in a reduced environment. The content of the liquid products and the concentrations of hydrocarbons obtained in the course of thermolysis of bitumen-free sample A and the typical oil distribution of the biomarkers and alkylaromatics in the thermolysis products confirm a high generation potential of OM in this rock. In all of our experiments on the thermolysis of bitumen-free sample B, the yield of liquid products and hydrocarbons is low. According to the kerogen type, the thermolysis of this rock generates much gases. The Pt⁴⁺ and Ru³⁺ ions (added in the form of simple inorganic salts) increased the yield of liquid (kerogen type I/II) and gaseous (kerogen type II/III) products. During the thermolysis of various type of immature kerogen in the lacustrine sedimentary rocks at a temperature of 400°C, the OM attained maturation corresponding to the early catagenesis level. Saturated biomarkers and alkylaomatics in the thermolysis products of both samples display typical oil distributions. The type of the source OM most strongly affects the composition of n-alkanes and alkylnaphthalenes. The metal ions used in this research served as catalysts for the methylation process during the thermolysis of immature kerogen, regardless of its type. The effect of the Pt⁴⁺ and Ru³⁺ ions on other transformations of the hydrocarbons, for example, the destruction of high-molecular n-alkanes to low-molecular ones and on isomerization reactions in molecules of polycyclic biomarkers and alkylaromatics to thermodynamically more stable isomers in the thermolysis products is controlled, first of all, by the type of the source OM.     

On forecasting of cyclogenesis in the West Mediterranean and other areas bounded by mountain ranges by baroclinic model

Summary Changes occurring in the thermal structure of air masses in the Alps area and the West Mediterranean region, during cyclonic developments in the Gulf of Genoa, have been considered. The effect of the height and the form of the mountain ranges as well as that of the nonadiabatic processes, on the deformation of the thickness pattern, have been discussed. These factors have been further taken into consideration for a modification of the equations used inEstoque's method for the baroclinic model, and a new method has been developed for forecasting cyclogenesis in regions bounded by mountain ranges.

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Zusasmmenfassung Es werden die Änderungen der thermischen Struktur der Luftmassen im Alpengebiet und im westlichen Mittelmeerraum bei der Entwicklung von Zyklonen im Golf von Genua aufgezeigt und die Einflüsse von Höhe und Form der Gebirgszüge sowie von nichtadiabatischen Vorgängen auf die Deformation der relativen Topographie besprochen. Diese Faktoren werden auch zur Modifikation der in der Methode vonEstoque für ein baroklines Modell verwendeten Gleichungen in Betracht gezogen und damit wird eine neue Methode zur Vorhersage der Zyklogenese unter dem Einfluß von Gebirgszügen entwickelt.

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Résumé On expose dans ce mémoire à quelles modifications la structure thermique des masses d'air est soumise dans la région des Alpes et dans le bassin occidental de la Méditerranée lors du développement de dépressions sur le Golfe de Gênes. On y discute en outre l'influence de la hauteur et de la forme des chaînes de montagnes ainsi que celle des processus non-adiabatiques sur des déformations de la topographie relative. Tous ces éléments sont pris en considération pour leur adapter les équations utilisées dans le modèle baroclined'Estoque. Par là, on accède à une nouvelle méthode de prévision de la cyclogénèse, méthode qui tient compte de l'influence des chaînes de montagnes.

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With 5 Figures     

Factors that contributed to recent eutrophication of two Slovenian mountain lakes

Increased eutrophication was recently observed in the 5th (5J) and 6th (6J) Triglav Lakes, two remote Slovenian mountain lakes. Sediment phosphorus (P) pools were analysed and potential external P sources affecting the lakes (atmospheric deposition, terrestrial export and nearby hut) evaluated, to assess the effects of internal and external changes on the lakes. A sequential extraction procedure was used to quantify five P fractions from the sediments: adsorbed (NH₄Cl–P), redox-sensitive (BD–P), aluminium- (NaOH–P) and calcium- (HCl–P) bound, and refractory organic (Res–P) P. Total phosphorus (TP) contents in surface sediment of 5J and 6J were 1430 and 641 µg P g^?1 dry weight sediment (dw), respectively. TP varied with depth in 5J sediments, but displayed no discernible pattern, whereas it decreased steadily downcore in 6J. Contents of all P forms were distinctly higher in 5J than 6J, but their rank order and relative abundances were similar in the two lakes. Res–P was the most abundant P fraction, followed by HCl–P. Together, the two P forms accounted for nearly 80 and 90% of TP in 5J and 6J sediments, respectively. BD–P and NaOH–P were less abundant, with each fraction accounting for 3 to 9% of TP, whereas NH₄Cl–P was least abundant. Atmospheric deposition and terrestrial export were substantial sources of P for the lakes. Delivery of the former was estimated to be at least 7.5 mg P m^?2 yr^?1 and the latter around 20 mg P m^?2 yr^?1. We concluded that P was not retained in the catchment effectively, likely because of only slightly acidic soil pH (5.9), relatively low aluminium content and high organic matter content (53%) in soils, resulting in higher vulnerability of the studied lakes to eutrophication. The mountain hut could also be a significant source of P for the lakes. Each year, it could potentially contribute ~12 kg of soluble P to the environment, but the true impact of the hut on lake trophic status remains unclear.     

The photoelectron spectra of some Tl-Sb sulphosalts

The results of X-ray induced photoelectron spectroscopy (XPS) experiments on several phases of the ternary system Tl-Sb-S are reported. The binding energies of the inner S, Sb and Tl electrons increase with increasing quantities of Sb and decreasing amounts of Tl in these compounds. This is explained by the influences of the proportions of the bonded metals on the effective electron affinity of S. The higher proportions of the more electronegative element bonded to S cause the increase of its effective electron affinity. The results for Tl₂S (carlinite), Tl₃SbS₃, TlSbS₂ (weissbergite), TlAsS₂ (lorandite) and Sb₂S₃ (antimonite) can be interpreted in this way. The results for Tl₄S₃ suggest a predominantly covalent character of bonding for both Tl(III) and Tl(I), which are present in this sulfide. From comparison with Tl₃SbS₄ it could be supposed that Tl(III)-S bond has a more covalent character than Sb(V)-S bond. The results for Tl₃SbS₄ are in agreement with crystal structure data and the results of Moessbauer spectroscopy. For AsS (realgar) the binding energies of the inner electrons of As and S significantly increase, showing that the electrons in molecular orbitals are less strongly bonded to individual atoms, as compared to pure elements. The results for the amorphous TlSb₅S₈ (corresponding in composition to parapierrotite) suggest that in amorphous compound the Tl-S bonding is stronger and the coordination of Tl more regular than in a crystalline one.     

Formation Of Coronal Mhd Shock Waves – I. The Basic Mechanism

The formation and evolution of a large amplitude MHD perturbation propagating perpendicular to the magnetic field in a perfectly conducting low plasma is studied. The perturbation is generated by an abrupt expansion of the source region. Explicit expressions for the time and the distance needed for the transformation of the perturbation's leading edge into a shock wave are derived. The results are applied to coronal conditions and the dynamic spectra of the radio emission excited by the shock are synthesized, reproducing metric and kilometric type II bursts. The features corresponding to the metric type II burst precursor and the moving type IV burst in the case of kilometric type II bursts are identified. A specific radio signature that is sometimes observed at the onset of a metric type II burst is found to appear immediately before the shock wave formation due to the associated growth of the magnetic field gradient. Time delays and starting frequencies of bursts' onsets are calculated and presented as a function of the impulsiveness of the source-region expansion, using different values of the ambient Alfvén velocity and various time profiles of the expansion velocity. The results are confronted with the observations of metric and kilometric type II solar radio bursts.     

Correlations of natural radionuclides in sediment from Danube

The correlation between specific activities of some natural radionuclides (²³⁸U, ²²⁶Ra, ²³²Th, ⁴⁰K) measured in sediment taken from river bottom was studied. The sediment was taken from the Serbian part of the Danube River. Good correlation between some of the isotopes is observed, so that their specific activity ratios are spread over a lower range than specific activities themselves. This suggests that evaluation of specific activity ratios of some natural radionuclides could be a more sensitive method for the determination of increased levels of some of them than the straightforward analysis of specific activities.     

The role of water mass dynamics in controlling bacterial abundance and production in the middle Adriatic Sea

Month-to-month fluctuations in the abundance of bacteria and heterotrophic nanoflagellates (HNF) and bacterial production, as well as various chemical (nutrients, oxygen) and physical (salinity, temperature) parameters were analysed at a station located in the open middle Adriatic Sea during one decade (1997-2006). Being influenced by both coastal waters and open Adriatic circulation in the surface layer, and by the deep Adriatic water masses in the deep layers (100 m), this station is quite suitable for detecting the environmental changes occurring in the open Adriatic Sea with respect to the circulation of its water masses and their long-term changes and anomalies. Multivariate methods were used to identify seasonal and inter-annual changes of the investigated parameters, associating observed changes to the changes in Adriatic water masses and circulation regimes. The analyses showed that bacterial abundance and production were controlled by different water mass dynamics during 1997-2001 compared to 2002-2006 period, particularly noticeable in different seasonal patterns of biological parameters. The interplay between North Adriatic Dense Water (NAdDW) and Levantine Intermediate Water (LIW) resulted in a change in the available nutrients (NAdDW is poor in orthophosphates), and as a consequence different bacterial abundance and production. A few periods were examined in detail, such as 2004, when LIW inflow was particularly strong and was accompanied by an increase of bacterial and HNF abundances, as well as of bacterial production.     

A parallel mesh-free contaminant transport model based on the Analytic Element and Streamline Methods

This paper introduces a new method for simulating large-scale subsurface contaminant transport that combines an Analytic Element Method (AEM) groundwater flow solution with a split-operator Streamline Method for modeling reactive transport. The key feature of the method is the manner in which the vertically integrated AEM flow solution is used to construct three-dimensional particle tracks that define the geometry of the Streamline Method. The inherently parallel nature of the algorithm supports the development of reactive transport models for spatial domains much larger than current grid-based methods. The applicability of the new approach is verified for cases with negligible transverse dispersion through comparisons to analytic solutions and existing numerical solutions, and parallel performance is demonstrated through a realistic test problem based on the regional-scale transport of agricultural contaminants from spatially distributed sources.