Cation disorder in garnets along the Mg3Al2Si3O12-Mg4Si4O12 join: an infrared,Raman and NMR study

We have obtained infrared and Raman spectra for garnets synthesized at high (static) pressures and temperatures along the join Mg₃Al₂Si₃O₁₂ (pyrope) — Mg₄Si₄O₁₂ (magnesium majorite). The vibrational spectra of Mg-majorite show a large number of additional weak peaks compared with the spectra of cubic pyrope garnet, consistent with tetragonal symmetry for the MgSiO₃ garnet phase. The Raman bands for this phase show no evidence for line broadening, suggesting that Mg and Si are ordered on octahedral sites in the garnet. The bands for the intermediate garnet compositions are significantly broadened compared with the end-members pyrope and Mg-majorite, indicating cation disorder in the intermediate phases. Solid state ²⁷Al NMR spectroscopy for pyrope and two intermediate compositions show that Al is present only on octahedral sites, so the cation disorder is most likely confined to Mg-Al-Si mixing on the octahedral sites. We have also obtained a Raman spectrum for a natural, shock-produced (Fe,Mg) majorite garnet. The sharp Raman peaks suggest little or no cation disorder in this sample.     

Cyclicity in the late Precambrian Elatina Formation,South Australia: Solar or tidal signature?

New observations from two late Precambrian (~800-650 Ma) sedimentary rhythmites in South Australia (Reynella Siltstone and Chambers Bluff Tillite) reveal cycles structurally similar to the ~12-laminae cycles of the ~650-Ma Elatina Formation but which comprise from 15 to 26 or more laminae. The new data are difficult to accomodate in depositional models for the Elatina Formation whereby its laminae are regarded as annual and the cyclicity ascribed to solar variability (Williams and Sonett, 1985) or to the combined influences of the sunspot cycle and the lunar nodal tide (Zahnle and Walker, 1987). If, however, the long-term Elatina Cycle and not the individual lamina is taken as a yearly climatic signal, the Elatina and other rhythmites studied may be interpreted as the deposits of marine ebb-tidal deltas that record variability in the velocity and range of paleo-ebb tides. The basic laminae-cycles would represent lunar fortnightly cycles of diurnal and/or semidiurnal laminae, commonly truncated through non-deposition at neap tides. Despite numerous empirical similarities between the Elatina and sunspot series, the ebb-tidal model for deposition is preferred because it accounts plausibly for observations from all three rhythmites studied.     

Evolution of the early Earth: Constraints from Nd---Nd isotopic systematics

Combined ¹⁴⁷Sm---¹⁴³Nd and the now extinct [τ(1/2)₁₄₆=103×10⁶ yr] ¹⁴⁶Sm---¹⁴²Nd isotopic systematics are reported for early Archean gneisses from Greenland (Amîtsoq and Akilia associations), and Canada (Acasta gneiss). Using both field relationships and high resolution U---Pb SHRIMP ion-probe ages, it has been possible to identify the most ancient rocks in these terrains for isotopic analyses. Preliminary ¹⁴²Nd analyses of a still limited number of samples have failed to identify terrestrial ¹⁴²Nd anomalies. Effects, if present, are limited to < 10 ppm and we have thus been unable to confirm the +33±4 ppm ε₁₄₂ value claimed by Harper and Jacobsen (1992a, b) for a single sample. From the lack of ¹⁴⁶Sm---¹⁴²Nd effects we infer that large-scale fractionation events that may have occurred in the first 200 Ma of Earth history did not leave a significant nor widespread imprint on the early Archean mantle or crust. If a terrestrial magma ocean, with associated LREE fractionation, formed as a result of planetary accretion, then it had a lifetime of at most 250 m.y. before being remixed into the Earth's mantle.

The samples analysed in this study have a range of ε₁₄₃ values including highly positive values of up to +4.2. This requires that the earliest known Archean crust was differentiated from a reservoir that was strongly depleted in the LREE as compared with chondritic compositions. In the early Archean it is proposed that the depletions in LREE are a consequence of extraction of a limited fraction of the Earth's continental crust ( < 10%) from the upper 200 km of the mantle. A three reservoir model, consisting of the continental crust, depleted mantle and a more primitive mantle reservoir can be extended to account for both the present-day, as well as the evolving Nd isotopic composition of the Earth's crust and mantle. In contrast to previous models, the rate of growth of the continental crust is used as an input parameter to constrain the concomitant growth and evolution of the depleted mantle reservoir. Recycling of large volumes of bulk continental crust into the mantle is not considered to be an important process, nor is the existence of an additional major enriched component in the early Archean mantle.     

The common agricultural policy and the general environmental policies concerned with agriculture in the European Community and their implications for fertilizer consumption

This paper traces the major developments in the European Common Agricultural Policy (CAP) and related environmental policy and examines their impact on the use of crop nutrients. The objectives of the CAP were set out in the Treaty of Rome in 1957 and have not been explicitly revised. The Community has, however, progressed from being a significant importer to a major exporter of food. Various changes in the policy measures/reforms, have been implemented, each to control the continuing increase in farm output. The latest of these in May 1992 reduced commodity prices towards world market levels, introduced 15% set aise for arable land, as well as agreeing a number of agri-environmental measures. Further changes are anticipated following the Uruguay Round of the General Agreement on Tariffs and Trade (GATT) and as new trade agreements are reached with the countries of the former Eastern Bloc. Inevitably, existing farm systems will be subject to careful reappraisal. The Community's environmental objectives were added to the Treaty in 1987 with the passing of the European Single Act. The interaction between agriculture and the environment has been a prominent concern. The Directive 91/676, which seeks to protect water against pollution caused by nitrate from agricultural sources, is the first Directive to have a major direct impact on farm practive. The Fifth Environmental Action Plan for 1993–2000 ‘Towards Sustainability’ selects agriculture as one of five industries for specific attention. The plan seeks an extensification of agriculture and a reduction in the use of chemicals. Changes in the amount of plant nutrients from both farmyard manure and mineral fertilizers used in agriculture are quantified. Methods of determining the efficiency with which they are utilized are assessed. New advisory techniques which will improve the efficiency of nutrient use on the farm are considered, as are the implications for the future demand for nutrients from mineral fertilizers. This paper is the view of the European Fertilizer Manufacturers Association.     

Factors Affecting Efficient Aquifer Restoration at In Situ Uranium Mine Sites

In situ mining of uranium typically requires the injection of a reactive leaching solution (lixiviant) such as sodium carbonate/bicarbonate, ammonium carbonate/bicarbonate, or sulfuric acid, and an oxidant such as hydrogen peroxide or oxygen into an ore-bearing, confined aquifer. It also requires the environmental restoration of the source aquifer. The stratigraphy of sandstone uranium deposits typically consists of interbedded layers of poorly consolidated sands and clays and gravels deposited in fluvial or coastal environments. The parameters that influence the migration of lixiviant during mining and restoration in these environments include induced hydraulic gradients, hydrodynamic dispersion, heterogeneity, anisotropy, physicochemical reactions, leakage into and/or through confining layers, and convergence of flow lines due to partial well penetration.
The effectiveness of the various methods of aquifer restoration is sit -specific and is dependent upon the site hydrogeology and hydrogeochemistry, and the chemistry of the lixiviant. Each method of aquifer restoration has advantages and disadvantages. Selection of the most effective and economically feasible method requires detailed knowledge of the site-specific hydrogeologic conditions.     

Time-scale calibration by high-precision UPb zircon dating of interstratified volcanic ashes in the Ordovician and Lower Silurian stratotypes of Britain

High initial parent/daughter element ratios and a unique dual decay scheme make UPb zicron ages more precise and reliable than most isotopic ages, and thus inherently superior for time-scale calibration. Employing improved techniques to the conventional method of UPb dating, we have analyzed microgram-size (2–12 × 10⁻⁸ g) zircon fractions from biostratigraphically controlled volcanic ashes and dated key Paleozoic time-markers with a precision better than 1% (±2Ma). Four of the stratotype samples from Britain for which fission-track ages [1] were previously reported have yielded improved ages of:438.7 ± 2.0Ma for the lower Silurian zone of Coronograptus cyphus from Llandovery strata at Dob's Linn, southern Scotland;457.5 ± 2.2 Ma for a Middle Ordovician Caradoc (Longvillian) ash near Bala, North Wales, and;465.7 ± 2.1and464.6 ± 1.8 Ma for the Didymograptus artus Zone and the type Didymograptus Murchisoni Zone, respectively, of the Llanvirn Series at Arenig Fawr and Abereiddi Bay, Wales. Another sample from the zone of Dicellograptus anceps (P. pacificus Subzone) of the Ashgill Series at Dob's Linn has been dated at445.7 ± 2.4Ma, suggesting placement of the Ordovician-Silurian time boundary at approximately 441 Ma. A sixth bentonite from Caradocian age strata of North America (Spechts Ferry Shale, Decorah Formation, Missouri) is453.7 ± 1.8Ma old, indicating that the Rocklandian Stage of the Mohawkian Series is only slightly younger than the Longvillian Stage of the Caradoc Series in Britain.