Presence and spatial distribution of emerging contaminants (drugs of abuse) in protected agroecological systems (L’Albufera de Valencia Coastal Wetland, Spain)

The Mediterranean wetlands are unique in biological diversity and provide multiple benefits, constituting a great water reserve for the planet and producing biomass and nutrients for the trophic chain. However, the increasing human impact and socio-economic development in recent decades have caused important losses in these ecosystems. This work was carried out in the Natural Park of L’Albufera (Valencia, Spain), which includes a coastal lagoon, marshlands, dunes and pinewoods, surrounded by rice fields and orchard in its non-urbanized part. Despite this great ecological value, it suffers impacts derived from the high human and industrial occupation and the hydrological contributions of the connected irrigation systems. The study focused on the development of a combined methodology, based on environmental forensics principles, with the aim of identifying the presence, flow paths and spatial distribution of illicit drugs entering the Natural Park. It is organized around two major procedures: analysis of 16 water samples and application of Geographical Information Systems (GIS) integrating different sources and data formats, as analysis of 14 drugs of abuse by Liquid Chromatography-Mass Spectrometry techniques, and social and environmental data in either GIS layers or tabular digital formats. Results show that, at present, most analyzed drugs have been identified in all sample points. Besides the population distribution pattern, the traditional irrigation system connected to sewage treatment plant (STP) locations is the way by which illicit substances are introduced into the Natural Park waters.     

Wind influence on surface current variability in the Ibiza Channel from HF Radar

Surface current variability is investigated using 2.5 years of continuous velocity measurements from an high frequency radar (HFR) located in the Ibiza Channel (Western Mediterranean Sea). The Ibiza Channel is identified as a key geographical feature for the exchange of water masses but still poorly documented. Operational, quality controlled, HFR derived velocities are provided by the Balearic Islands Coastal Observing and Forecasting System (SOCIB). They are assessed by performing statistical comparisons with current-meter, ADCP, and surface lagrangian drifters. HFR system does not show significant bias, and its accuracy is in accordance with previous studies performed in other areas. The main surface circulation patterns are deduced from an EOF analysis. The first three modes represent almost 70 % of the total variability. A cross-correlation analysis between zonal and meridional wind components and the temporal amplitudes of the first three modes reveal that the first two modes are mainly driven by local winds, with immediate effects of wind forcing and veering following Ekman effect. The first mode (37 % of total variability) is the response of meridional wind while the second mode (24 % of total variability) is linked primarily with zonal winds. The third and higher order modes are related to mesoscale circulation features. HFR derived surface transport presents a markedly seasonal variability being mostly southwards. Its comparison with Ekman-induced transport shows that wind contribution to the total surface transport is on average around 65 %.     

Growing season expansion and related changes in monthly temperature and growing degree days in the Inter-Montane Desert of the San Luis Valley, Colorado

Most climate change studies on high elevation ecosystems identify changes in biota, while several report abiotic factors. However, very few report expansion of the freeze-free period, or discuss monthly changes of temperature and growing degree days (GDD) during the growing season. This study provides initial data on agriculturally-related aspects of climate change during the growing season (M-J-J-A-S) in the inter-montane desert of the San Luis Valley (SLV), Colorado. Temperature data were gathered from 7 climate stations within the SLV. Based on ordinal days, the last vernal freeze is occurring (p?<?0.05) earlier at 3 stations than in prior years, ranging between 5.52 and 11.86?days during 1981–2007. Significantly-later autumnal freezes are occurring at 5 stations by 5.95–18.10?days, while expansion of the freeze-free period was significantly longer at all stations by 7.20–24.21?days. The freeze-free period averaged about 93?days prior to the 1980s, but now averages about 107?days. Increases (p?<?0.05) in daily mean, maximum, minimum temperature occurred at nearly all stations for each month. Increases in GDD₁₀, GDD_4.4 (potato) and GDD_5.5 (alfalfa) also occurred at nearly all stations for all months during 1994–2007. Higher temperatures increase the number of GDD, quickening crop growth and maturity, and potentially reducing yield and quality unless varieties are adapted to changes and water is available for the season extension and increased evapotranspiration.     

Assessment of pollution risk ascribed to Santa Margarida Military Camp activities (Portugal)

Santa Margarida Military Camp (S.M.M.C.) is the only one Portuguese military training area, including firing ranges for tactical military manoeuvres of mechanised divisions. For this reason, various negative effects on the environment were expected due to the military activities, as the Military Camp’s area is classified as a high vulnerability area to pollution of its multilayer porous aquifers. The aim of this study was to identify and characterise local/regional geochemical impacts caused by the continuing military training activities performed at S.M.M.C. in the course of 52 years. An overview of the geochemical research issues as a basis for risk assessment is presented. A special attention has been put on the quality of local and regional surface waters, shallow groundwaters and groundwaters. Local soils and sediments as well as fragments of shells and bullets were sampled and analysed. The results so far obtained, indicated that none pollution effects were a consequence of the military training activities. Till now, the geochemical signatures such as, high levels of K, Cl and NO₃ in waters, detected in particular sites, should be faced as tracers of diffuse pollution ascribed to urban waste disposal and cattle breading.     

On the tectonic origin of Iberian topography

The present-day topography of the Iberian peninsula can be considered as the result of the Mesozoic–Cenozoic tectonic evolution of the Iberian plate (including rifting and basin formation during the Mesozoic and compression and mountain building processes at the borders and inner part of the plate, during the Tertiary, followed by Neogene rifting on the Mediterranean side) and surface processes acting during the Quaternary. The northern-central part of Iberia (corresponding to the geological units of the Duero Basin, the Iberian Chain, and the Central System) shows a mean elevation close to one thousand meters above sea level in average, some hundreds of meters higher than the southern half of the Iberian plate. This elevated area corresponds to (i) the top of sedimentation in Tertiary terrestrial endorheic sedimentary basins (Paleogene and Neogene) and (ii) planation surfaces developed on Paleozoic and Mesozoic rocks of the mountain chains surrounding the Tertiary sedimentary basins. Both types of surfaces can be found in continuity along the margins of some of the Tertiary basins. The Bouguer anomaly map of the Iberian peninsula indicates negative anomalies related to thickening of the continental crust. Correlations of elevation to crustal thickness and elevation to Bouguer anomalies indicate that the different landscape units within the Iberian plate can be ascribed to different patterns: (1) The negative Bouguer anomaly in the Iberian plate shows a rough correlation with elevation, the most important gravity anomalies being linked to the Iberian Chain. (2) Most part of the so-called Iberian Meseta is linked to intermediate-elevation areas with crustal thickening; this pattern can be applied to the two main intraplate mountain chains (Iberian Chain and Central System) (3) The main mountain chains (Pyrenees and Betics) show a direct correlation between crustal thickness and elevation, with higher elevation/crustal thickness ratio for the Central System vs. the Betics and the Pyrenees. Other features of the Iberian topography, namely the longitudinal profile of the main rivers in the Iberian peninsula and the distribution of present-day endorheic areas, are consistent with the Tertiary tectonic evolution and the change from an endorheic to an exorheic regime during the Late Neogene and the Quaternary. Some of the problems involving the timing and development of the Iberian Meseta can be analysed considering the youngest reference level, constituted by the shallow marine Upper Cretaceous limestones, that indicates strong differences induced by (i) the overall Tertiary and recent compression in the Iberian plate, responsible for differences in elevation of the reference level of more than 6 km between the mountain chains and the endorheic basins and (ii) the effect of Neogene extension in the Mediterranean margin, responsible for lowering several thousands of meters toward the East and uplift of rift shoulders. A part of the recent uplift within the Iberian plate can be attributed of isostatic uplift in zones of crustal thickening.     

X-ray Computed Tomography study of the influence of consolidants on the hydric properties of sandstones for stone conservation studies

X-ray Computed Tomography (X-ray CT) has been used to study the petrophysical characteristics of a Jurassic sandstone from Asturias (Northern Spain) used as building stone in several monuments in the region. CT monitoring of water capillarity tests has made it possible to visualize the movement of water inside the samples, to relate this movement with texture characteristics, and to measure the height reached in successive images, thereby determining the capillary penetration coefficient; based on this coefficient, the effective capillary pore radius has also been estimated. An advantage of the use of CT is that, as the information comes from the sample interior, border effects that can be generated in the external faces can be avoided.The CT was also used to visualize how a commercial organosilicon consolidant penetrates inside the rock by means of capillarity, a usual way of consolidant application in stone restoration processes. The coefficient of capillary penetration of the product, determined on the basis of the measurements made on the tomographic images, is 53% less than that of water. The influence of rock texture characteristics on the capillarity both of the consolidant and the water was also observed.The samples underwent CT water capillarity studies before and after the consolidant application, proving that the treatment improves the rock's hydric properties. The coefficient of capillary penetration decreased by 24% following the application of the consolidant, whereas the effective pore radius decreased by more than 40%.     

Sediment resuspension in two adjacent shallow coastal lakes: controlling factors and consequences on phosphate dynamics

A combination of field measurements, modelling and laboratory experiments was used to evaluate the potential impact of sediment resuspension on phosphorus (P) dynamics. The study was carried out in two adjacent shallow coastal lakes (Lake Honda and Lake Nueva) which, due to their geographic proximity (only 200 m apart), are subject to equal meteorological forcing and represent ideal systems to study how morphometry and sediment properties relate to wind events. The focusing factors (a measure of the fluxes of sediment into the water column through resuspension) estimated by comparing settling fluxes measured in surface sediment traps with those measured in bottom traps, were significantly larger (approximately 34% larger) in Lake Honda (LH; 1.18) than in Lake Nueva (LN; 0.88). Our model estimates of resuspension fluxes (E) were also ca. 40% larger in LH than in LN, in agreement with the observed focusing factors. The larger resuspension fluxes encountered in LH, in comparison with LN, can mainly be explained by differences in lake morphometry. Still, they could arise from differences in grain size distribution or in benthic algae concentration encountered in the lake sediments. By means of adsorption experiments in the laboratory, we show that resuspension events will have different effects on P-dynamics in LH and LN. While the resuspended material from LH tends to adsorb phosphate (PO₄ ³⁻), removing it from the water column, in LN the resuspended sediments tend to increase the availability of PO₄ ³⁻ in solution. These differences arise from (1) higher concentrations of PO₄ ³⁻ in water in LH compared to LN; and (2) larger PO₄ ³⁻adsorption capacity of the LH sediments as a result of the more abundant iron oxyhydroxides and clay.     

A high-resolution Holocene record on the Southern Brazilian shelf: Paleoenvironmental implications

A high-resolution, multi-proxy record has been used to determine the environmental changes during the Holocene on the southern Brazilian shelf. Present oceanographic conditions reveal wind and freshwater input as the determinants of short-term productivity changes in the study area. Magnetic susceptibility and grain-size variations, together with proxies of productivity (organic carbon, carbon accumulation rate, Ba, Sr, and Ca content, Ba/Al, Ba/Ti, and Al/Ti ratios) were analyzed and compared with proxies of redox condition (V/Ti ratio), terrigenous input (Fe/Ca and Ti/Ca ratios), as well as other Element/Ti ratios, to evaluate the paleoceanographic and paleoclimatic changes over the period.The core covers a time interval of about 7650 years, with sedimentation rates varying from 0.025 to 0.250 cm a⁻¹, which represent time intervals of between 8 and 80 a per sample. There is a clear change in the sedimentation rate at about 2800 B.P.All grain-size and elemental results indicate the occurrence of conspicuous changes between 5200 and 5000 cal. B.P., as well as between 3000 and 2800 cal. B.P. A comparison of the results with the palynological information available from the adjacent continental areas suggests that the sedimentary changes in this last interval may be correlated with the onset of modern climatic conditions in South America, and especially, with the onset of the Plata Plume Water, a water mass that carries cold, less saline waters towards the north. However, minor changes are observed at ca. 1500 B.P. and are correlated with an increase in the atmospheric humidity. Furthermore, a time-series analysis undertaken using several proxies indicated the occurrence of Sub-Milankovitch cycles, which may be compared with those reported worldwide.