Hydrogeological characterization of groundwater storage and drainage in an alpine karst aquifer (the Kanin massif,Julian Alps)

The Kanin massif is an important trans‐boundary aquifer, which stretches between Slovenia and Italy. The groundwater is only partially exploited, mainly for water supply, but the aquifer exhibits great potential for future exploitation. Since no consistent regional overview of the hydrogeological functioning of the Kanin massif was available, the decision was made to perform a study of this area, using a pragmatic approach based on 3D geological and hydrogeological modelling. The so‐called KARSYS approach was applied, with the aim of characterizing the groundwater reserves within this karst massif and of locating the main drainage axes that carry groundwater from the recharge areas to the respective springs. Delineation of the catchment areas of the corresponding springs was carried out, and some new explanations were obtained, especially with regard to the Mo?nica spring, which is located in Slovenia and forms a potential source of drinking water. It was found that this spring's catchment area extends as far as the Italian ski resort of Sella Nevea. The conceptual model also provides a possible explanation about the underground drainage towards the Boka spring and waterfall, which has been a challenge for decades. This new explanation is based on the existence of a perched groundwater body that feeds the Boka spring via a system of conduits. Despite some limitations, the results, which consist of a visualization of the underground drainage and groundwater storage within the Kanin massif, can be used as a basis for planning the sustainable management of karst waters in the studied area. Copyright © 2014 John Wiley & Sons, Ltd.     

Architecture of growth basins in a tidally influenced,prodelta to delta-front setting: The Triassic succession of Kvalpynten,East Svalbard

World-class examples of fault-controlled growth basins with associated syn-kinematic sedimentary fill are developed in Upper Triassic prodelta to delta-front deposits exposed at Kvalpynten, SW Edgeøya in East Svalbard. They are interpreted to have interacted with north-westerly progradation of a regional delta system. The syn-kinematic successions consist of 4 to 5 coarsening-upward units spanning from offshore mudstones to subtidal heterolithic bars and compound tidal dunes, which were blanketed by regional, post-kinematic sandstone sheets deposited as laterally continuous, subaqueous tidal dune fields. The rate of growth faulting is reflected in the distribution of accommodation, which governs sedimentary architecture and stacking patterns within the coarsening-upward units. Fully compartmentalized basins (12, 200–800 m wide and c. 150 m high grabens and half grabens) are characterized by syn-kinematic sedimentary infill. These grabens and half-grabens are separated by 60–150 m high horsts composed of pro-delta to distal delta-front mudstones. Grabens host tabular tidal dunes (sandwaves), whereas half-grabens bound by listric faults (mainly south-dipping) consist of wedge-shaped, rotated strata with erosive boundaries proximal to the uplifted fault block crests. Heterolithic tidal bars (sand ridges) occur in narrow half-grabens, showing migration oblique to the faults, up the dipslope. Structureless sandstone wedges and localized subaqueous slumps that formed in response to collapse of the block crests were only documented in half-grabens. Late-kinematic deposition during the final stages of faulting occurred in partly compartmentalized basins, filled with variably thick sets of continuous sandstone belts (compound tidal dunes).     

The Multiscale TROPIcal CatchmentS critical zone observatory M-TROPICS dataset II: Land use,hydrology and sediment production monitoring in Houay Pano,northern Lao PDR

Mountain regions of the humid tropics are characterized by steep slopes and heavy rains. These regions are thus prone to both high surface runoff and soil erosion. In Southeast Asia, uplands are also subject to rapid land-use change, predominantly as a result of increased population pressure and market forces. Since 1998, the Houay Pano site, located in northern Lao PDR (19.85°N 102.17°E) within the Mekong basin, aims at assessing the long-term impact of the conversion of traditional slash-and-burn cultivation systems to commercial perennial monocultures such as teak tree plantations, on the catchment hydrological response and sediment yield. The instrumented site monitors hydro-meteorological and soil loss parameters at both microplot (1 m²) and small catchment (0.6 km²) scales. The monitored catchment is part of the network of critical zone observatories named Multiscale TROPIcal CatchmentS (M-TROPICS). The data shared by M-TROPICS in Houay Pano are (1) rainfall, (2) air temperature, air relative humidity, wind speed, and global radiation, (3) catchment land use, (4) stream water level, suspended particulate matter, bed particulate matter and stones, (5) soil surface features, and (6) soil surface runoff and soil detachment. The dataset has already been used to interpret suspended particulate matter and bed particulate matter sources and dynamics, to assess the impact of land-use change on catchment hydrology, soil erosion, and sediment yields, to understand bacteria fate and weed seed transport across the catchment, and to build catchment-scale models focused on hydrology and water quality issues. The dataset may be further used to, for example, assess the role of headwater catchments in large tropical river basin hydrology, support the interpretation of new variables measured in the catchment (e.g., contaminants other than faecal bacteria), and assess the relative impacts of both climate and land-use change on the catchment.     

Exhumation of eclogite and blueschist (Cyclades,Greece): Pressure–temperature evolution determined by thermobarometry and garnet equilibrium modelling

High‐P rocks such as eclogite and blueschist are metamorphic markers of palaeo‐subduction zones, and their formation at high‐P and low‐T (HP–LT) conditions is relatively well understood since it has been the focus of numerous petrological investigations in the past 40 years. The tectonic mechanisms controlling their exhumation back to the surface are, however, diverse, complex and still actively debated. Although the Cycladic Blueschist Unit (CBU, Greece) is among the best worldwide examples for the preservation of eclogite and blueschist, the proposed P–T evolution followed by this unit within the Hellenic subduction zone is quite different from one study to another, hindering the comprehension of exhumation processes. In this study, we present an extensive petrological data set that permits refinement of the shape of the P–T trajectory for different subunits of the CBU on Syros. High‐resolution quantitative compositional mapping has been applied to support the thermobarometric investigations, which involve semi‐empirical thermobarometry, garnet equilibrium modelling and P–T isochemical phase diagrams. The thermodynamic models highlight the powerful use of reactive bulk compositions approximated from local bulk compositions. The results are also combined with Raman spectrometry of carbonaceous material (RSCM) to retrieve the metamorphic peak temperature distribution at the scale of the island. A major result of this study is the good agreement between all the independent thermobarometric methods, permitting reconstruction of the prograde and retrograde P–T trajectories. Garnet compositional zoning was used to retrieve prograde, peak and retrograde growth stages in line with the results of the P–T isochemical phase diagrams, RSCM temperature and peak‐pressure crystallization of the garnet–omphacite–phengite assemblage. Our results are consistent with previous thermobarometric estimates from other occurrences of CBU rocks (Tinos, Andros), suggesting a multistage exhumation process with (1) early syn‐orogenic exhumation within the subduction channel, (2) isobaric heating at mid‐crustal depths (~10–12 kbar) following thermal re‐equilibration of the lithosphere from a cold syn‐orogenic regime in the subduction zone to a warmer post‐orogenic regime in the back‐arc domain and (3) exhumation and cooling related to a post‐orogenic phase of extension following slab retreat. Expanding to the general aspects of subduction zones, we suggest that such metamorphic evolution of HP–LT units should be regarded as a characteristic feature of exhumation driven by slab rollback.     

Sorption behavior of the sandy residual unconsolidated materials from the sandstones of the Botucatu Formation,the main aquifer of Brazil

Pollutant transport through porous geological materials depends on the intrinsic characteristics of the materials that define the sorption behavior. This is the main environmental aspect that must be evaluated in terms of natural attenuation and retardation factor of the pollutants. Sorption is directly related to the electrostatic charge of the mineral, the organic matter, and the oxide and hydroxide contents. We assessed the sorption characteristics of the sandy residual unconsolidated material of the Botucatu Formation, which is part of the main aquifer of Brazil, using Batch Equilibrium Tests. The tests used multicomponent solutions of NaCl, KCl, ZnCl₂, and CuCl₂·H₂O with a total concentration that varied from 20 to 1,000 ppm. Different plotting systems were applied so that the isotherms better reflected the sorption behavior of the studied cations onto the unconsolidated materials. The cation Na⁺ was not sorbed. The Langmuir I and Freundlich equations adequately represent the behavior of Cu⁺⁺, the Langmuir II approximation better represented K⁺, and the Langmuir I and Freundlich equations were reasonably fitted Zn⁺⁺.     

Sources of δ18O Concentration Variability in Greenland Ice Cores: Temperature, North Atlantic Oscillation and Solar Activity

This work concerns possible connection between variations of δ¹⁸O in Greenland ice, temperature, precipitation amount, NAO indices and relative sunspot numbers. The relationships between 10-year averaged values of this data were derived making use of regression analysis methods. It was discovered that February temperature yields the main contribution in variability of δ¹⁸O. The multiple correlation coefficient between weighted night temperature of the most important months and δ¹⁸O equals 0.95±0.01. Besides the local source of δ¹⁸O changes, defined by the amount of precipitation and temperature, an additional source correlated with the level of solar activity has been revealed. The relative contribution of this source in the δ¹⁸O variance is about 0.1. It has been shown that the multiple correlation coefficient between δ¹⁸O and NAO indices is equal to 0.85. Therefore the NAO yields more than 2/3 of the variances of climatic change in Greenland. An independent contribution of solar activity in climatic changes is about 1/3.     

Review of the experience with monitoring uncertainty requirements in the Clean Development Mechanism

In order to ensure the environmental integrity of carbon offset projects, emission reductions certified under the Clean Development Mechanism (CDM) have to be ‘real, measurable and additional’, which is ensured, inter alia, through the monitoring, reporting and verification (MRV) process. MRV, however, comes at a cost that ranges from several cents to €1.20 and above per tCO₂e depending on the project type. This article analyses monitoring uncertainty requirements for carbon offset projects with a particular focus on the trade-off between monitoring stringency and cost. To this end, existing literature is reviewed, overarching monitoring guidelines, as well as the ten most-used methodologies are scrutinized, and finally three case studies are analysed. It is shown that there is indeed a trade-off between the stringency and the cost of monitoring, which if not addressed properly may become a major barrier for the implementation of offset projects in some sectors. It is then demonstrated that this trade-off has not been systematically addressed in the overarching CDM guidelines and that there are only limited incentives to reduce monitoring uncertainty. Some methodologies and calculation tools as well as some other offset standards, however, do incorporate provisions for a trade-off between monitoring costs and stringency. These provisions may take the form of discounting emissions reductions based on the level of monitoring uncertainty – or more implicitly through allowing a project developer to choose between monitoring a given parameter and using a conservative default value.

Policy relevance

The CDM Executive Board acknowledged that monitoring uncertainty has not been treated in a consistent manner and the draft standard on uncertainty was subsequently presented in May 2013. This article supports the implementation of this standard for more comprehensive, yet cost-efficient accounting for monitoring uncertainty in carbon offset projects. Moreover, in the light of the ongoing discussions on the New Market Mechanisms as well as the operationalization of the Green Climate Fund and different national mitigation policies, the CDM experience provides valuable insights with regards to the treatment of monitoring uncertainty and constitutes a solid basis for designing uncertainty requirements for new mechanisms to mitigate climate change.     

Use of terrestrial photosieving and airborne topographic LiDAR to assess bed grain size in large rivers: a study on the Rhine River

Most grain size monitoring is still being conducted by manual sampling in the field, which is time consuming and has low spatial representation. Due to new remote sensing methods, some limitations have been partly overcome, but methodological progress is still needed for large rivers as well as in underwater conditions. In this article, we tested the reliability of two methods along the Old Rhine River (France/Germany) to estimate the grain size distribution (GSD) in above-water conditions: (i) a low-cost terrestrial photosieving method based on an automatic procedure using Digital Grain Size (DGS) software and (ii) an airborne LiDAR topo-bathymetric survey. We also tested the ability of terrestrial photosieving to estimate the GSD in underwater conditions. Field pebble counts were performed to compare and calibrate both methods. The results showed that the automatic procedure of terrestrial photosieving is a reliable method to estimate the GSD of sediment patches in both above-water and underwater conditions with clean substrates. Sensitivity analyses showed that environmental conditions, including solar lighting conditions and petrographic variability, significantly influence the GSD from the automatic procedure in above-water conditions. The presence of biofilm in underwater conditions significantly altered the GSD estimation using the automatic procedure, but the proposed manual procedure overcame this problem. The airborne LiDAR topographic survey is an accurate method to estimate the GSD of above-water bedforms and is able to generate grain size maps. The combination of terrestrial photosieving and airborne topographic LiDAR methods is adapted to assess the GSD over several kilometers long reaches of large rivers. © 2020 John Wiley & Sons, Ltd.