Simultaneous determination of dissolved organic carbon and total dissolved nitrogen in seawater by high temperature catalytic oxidation: conditions for precise shipboard measurements

Appropriate conditions have been achieved for the accurate, rapid, and highly precise shipboard simultaneous determination of dissolved organic carbon and total dissolved nitrogen in seawater by high temperature catalytic oxidation. A nitrogen-specific Antek 705D chemiluminescence detector and a CO₂-specific LiCor Li6252 IRGA have been coupled in-series with a Shimadzu TOC-5000 organic carbon analyser. Precision of both simultaneous measurements is ≤1.5%, i.e. ±1 μmol C l⁻¹ and ±0.3 μmol N l⁻¹, respectively. Quality of analysis is not compromised by vibrations associated with ocean going research vessels.     

Validation and Application of Plants as Biomonitors of Trace Element Atmospheric Pollution – A Co-Ordinated Effort in 14 Countries

The International Atomic Energy Agency (IAEA) organized a co-ordinated research project (CRP) on Validation and application of plants as biomonitors of trace element atmospheric pollution analysed by nuclear and related techniques involving 14 participating countries. The CRPs objective was to identify appropriate bioindicators for local and/or regional application and validate them for general air pollution monitoring. Activities included quantification studies, research into spatial and time resolution for particular organisms, and physiological studies. A number of suitable bioindicators were identified in different parts of the globe and tested during the CRP. Sampling strategies were reviewed and the recommended approach adopted by the group. Appropriate sample preparation procedures were assessed and harmonised to the degree allowed by different geographic and climatic conditions in the participating countries. Two interlaboratory comparison exercises were carried out on lichen and moss materials. Results confirmed definite improvement in analytical performance of the participating laboratories, but also revealed possible inconsistencies due to different sample processing procedures. Several monitoring surveys were carried out and consequently pollution maps drawn for extended areas or countries. Overall results confirmed applicability of lower plants for assessing the degree of atmospheric pollution and provided several countries with effective monitoring tools not used before.     

Kema terrane: A fragment of a back-arc basin of the early Cretaceous Moneron–Samarga island-arc system, East Sikhote–Alin range, Russian Far East

Abstract The Kema terrane is a suite of Barremian(?)–Aptian to Albian volcano-sedimentary rocks of Sikhote–Alin that are interpreted as deposits of the back-arc basin of the Moneron–Samarga island-arc system. Compositional features of the different-type deposits indicate a near-slope depositional environment influenced by volcanic processes. Studies of slump fold orientation testify to the accumulation of material from southeast to northwest by gravitational sliding. Compositional characteristics of terrigenous rocks suggest the major provenance for detrital material was an ensialic volcanic island arc. Petrochemical characteristics of basaltic rocks indicate that the formations studied were confined to the back part of the arc.     

Volcanogenic massive sulfide deposits of ophiolite associations

Volcanogenic massive sulfide deposits in ophiolite complexes are usually attributed to the Cyprus type. They associate with basaltic volcanics that are formed in mid-ocean or back-arc spreading centers and much less frequently in intra-plate settings. The deposits are characterized by copper or copper-zinc ores that are enriched in Ni, Co, and in places Mn and As, but are very poor in Pb and demonstrate a low to moderate content of Ag and Au. Typically, the deposits are low to very low in ore and metal reserves. Cyprus-type deposits were irregularly distributed during geological history. The most ancient of them were formed in the Neoproterozoic, while the bulk of the deposits are Ordovician or Cretaceous in age. Their possible Paleoproterozoic analogues can be found in the Svecofennian belt (Outokumpu ore district), while modern ones are confined to the Explorer and Endeavour Ridges and southern segment of the Juan de Fuca Ridge.     

Variolitic lavas in the axial rift of the Mid-Atlantic Ridge and their origin (Sierra Leone area, 6°18′N)

Altered variolites described for the first time in the axial zone of the Mid-Atlantic Ridge are represented by rounded globules of andesite (icelandite) composition with light trachyandesite rim embedded in a picrobasaltic matrix. The globules were transferred with picrobasaltic melt and then floated to the surface of lava flow, while formation of leucocratic rims was presumably related to thermodiffusion (Soret effect) in a cooling heterogeneous melt. This heterogeneous melt was formed by penetration of ascending column of picrobasaltic magma in already existing small intracructsal magmatic chamber filled with residual icelanditetype andesite melt and involvement of the latter into a general upward movement. The rapid ascent of the melts in the oceanic spreading zones by means of turbulent flowing caused dispersion of the extragenous melt into small drops in a jet of picrobasaltic magma, without their interaction. Variolites were formed during cooling of such heterogeneous lava flow. No signs of liquid immiscibility were found in the studied variolites.     

Empirical assessment of the role of geospatial technology in delivering governance and strengthening democracy in Nigeria

The paper examined the concept of development in line with the role of geospatial technology applications in governance and geospatial management in Nigeria. It also evaluates the previous efforts made by successive governments in managing governance process through geospatial technology initiatives using Lagos State as a proof-of-concept. It empirically demonstrates the role of monitoring spatial development initiatives using Landsat multi-dates satellite images 1985, 1990, 1995, 2000, 5005, 2010 and 2016 and Geographic Information System technique. The paper then identified, mapped and examined the settlement growth of Lagos using Ikorodu Division as an empirical proof-of-concept. The study reveals a geometric increase in uncoordinated human activities resulting from sporadic spatial development (builtup area) from 27.67 sq km (7.7%) in 1985–313.02 sq km (87.3%) spatial coverage in 2016. Based on the regression line, the study reveals a strong correlation between increasing settlement development and time. Low level of community involvement and lack of sense of ownership of development project initiatives in developing a local “vision” and strategy are identified as a problem. The paper re-emphasized that sustaining democratic processes as well as the fight against poverty will be won or lost mostly in the rural and less in the urban areas. The rural area is home to about 70% of the world’s poor due to lack or inadequate government services and basic amenities. The study suggest that making the future better for the yet unborn requires appreciable fundamental dataset, technologies, human resources and reliable government structures.     

Elastic behavior of weakly cemented contact

We investigate the elastic behavior of weakly cemented contact. We show that the radial distribution of stresses and the stiffnesses of a cemented contact are governed by the ratio a/RΛ, where R, a, and Λ are, respectively, the grain radius, the contact size, and the ratio of the elastic moduli of cement and grains. Moreover, we show that a cemented contact is always less stiff than a Hertzian contact having a similar size. Finally, we propose accurate approximate expressions of the contact stiffnesses. Copyright © 2014 John Wiley & Sons, Ltd.     

Imaging buried Quaternary valleys using the transient electromagnetic method

Buried Quaternary valleys in Denmark are complex structures filled with various deposits consisting primarily of glacio-lacustrine clay, till and meltwater sand, and gravel. The valleys are important geophysical targets, because they often contain significant volumes of groundwater used for public water supply. About 700 km of buried valley structures have been imaged in the western part of Denmark by the transient electromagnetic (TEM) method. The ability to map the valleys depends primarily on valley geometry, infill architecture and the resistivity of the fill sediments as well as the substratum. One-dimensional (1-D) inversion models of the TEM soundings have been used to construct contour maps of 20 m average resistivities and depth to a good conductor, which provide images for geological interpretation. Images of buried valley morphology, fill properties, infill architecture, such as cut-and-fill structures, valley distribution and valley generations, are characterized for case studies from Hornsyld, Holstebro and the Vonsild/Agtrup areas of Denmark.     

Time relationship between regional deformation and fabric development in the Peralimala pluton,South India — Inferences from magnetic fabric

Anisotropy of magnetic susceptibility (AMS) is investigated in samples of Peralimala (PM) pluton (ca. 550 Ma) and adjacent gneiss, gabbro, mylonite and amphibolite from the Moyar Shear Zone (MSZ), Southern Granulite Terrane (SGT) with an aim to decipher the time-relationship between fabric development in the pluton and regional tectonics. Magnetic foliation recorded in the PM pluton is sub-parallel to the WNW-ESE striking MSZ. Magnetic foliation and lineation trajectories are sigmoidal and curve into the shear zone. A dextral sense of shear is deciphered from the trajectories, which is similar to that reported within the MSZ in some earlier studies. It is inferred that the PM pluton has developed post-emplacement deformation-fabric related to reactivation of the MSZ during Pan-African age. Based on the data and existing information about regional tectonics of the area, the possibility of the (a) PM pluton being a Deformed Alkali Rock and Carbonatite (DARC) and (b) MSZ marking an ancient suture zone, is discussed.