Geochronology,stratigraphy and geochemistry of Cambro-Ordovician,Silurian and Devonian volcanic rocks of the Saxothuringian Zone in NE Bavaria (Germany)—new constraints for Gondwana break up and ocean–island magmatism

International Journal of Earth Sciences - Stratigraphically well-defined volcanic rocks in Palaeozoic volcano-sedimentary units of the Frankenwald area (Saxothuringian Zone, Variscan Orogen) were...     

Hot Spots of Nitrification in the Elbe Estuary and Their Impact on Nitrate Regeneration

Estuaries act as an organic matter and nutrient filter in the transition between the land, rivers and the ocean. In the past, high nutrient and organic carbon load and low oxygen concentration made the Elbe River estuary (NW Europe) a sink for dissolved inorganic nitrogen. A recent reduction in loads and subsequent recovery of the estuary changed its biogeochemical function, so that nitrate is no longer removed on its transition towards the coastal North Sea. Nowadays in the estuary, nitrification appears to be a significant nitrate source. To quantify nitrification and determine actively nitrifying regions in the estuary, we measured the concentrations of ammonium, nitrite and nitrate, the dual stable isotopes of nitrate and net nitrification rates in the estuary on five cruises from August 2012 to August 2013. The nitrate concentration increased markedly downstream of the port of Hamburg in summer and spring, accompanied by a decrease of nitrate isotope values that was clearest in summer exactly at the location where nitrate concentration started to increase. Ammonium and nitrite peaked in the Hamburg port region (up to 18 and 8 μmol L^?1, respectively), and nitrification rates in this region were up to 7 μmol L^?1 day^?1. Our data show that coupled re-mineralization and nitrification are significant internal nitrate sources that almost double the estuary’s summer nitrate concentration. Furthermore, we find that the port of Hamburg is a hot spot of nitrification, whereas the maximum turbidity zone (MTZ) only plays a subordinate role in turnover of nitrate.     

The Oeschinensee rock avalanche,Bernese Alps,Switzerland: a co-seismic failure 2300 years ago?

Landslide deposits dam Lake Oeschinen (Oeschinensee), located above Kandersteg, Switzerland. However, past confusion differentiating deposits of multiple landslide events has confounded efforts to quantify the volume, age, and failure dynamics of the Oeschinensee rock avalanche. Here we combine field and remote mapping, topographic reconstruction, cosmogenic surface exposure dating, and numerical runout modeling to quantify salient parameters of the event. Differences in boulder lithology and deposit morphology reveal that the landslide body damming Oeschinensee consists of debris from both an older rock avalanche, possibly Kandertal, as well as the Oeschinensee rock avalanche. We distinguish a source volume for the Oeschinensee event of 37 Mm³, resulting in an estimated deposit volume of 46 Mm³, smaller than previous estimates that included portions of the Kandertal mass. Runout modeling revealed peak and average rock avalanche velocities of 65 and 45 m/s, respectively, and support a single-event failure scenario. ³⁶Cl surface exposure dating of deposited boulders indicates a mean age for the rock avalanche of 2.3 ± 0.2 kyr. This age coincides with the timing of a paleo-seismic event identified from lacustrine sediments in Swiss lakes, suggesting an earthquake trigger. Our results help clarify the hazard and geomorphic effects of rare, large rock avalanches in alpine settings.     

Experimental calibration of vanadium partitioning and stable isotope fractionation between hydrous granitic melt and magnetite at 800 °C and 0.5 GPa

Vanadium has multiple oxidation states in silicate melts and minerals, a property that also promotes fractionation of its isotopes. As a result, vanadium isotopes vary during magmatic differentiation, and can be powerful indicators of redox processes at high temperatures if their partitioning behaviour can be determined. To quantify the partitioning and isotope fractionation factor of V between magnetite and melt, piston cylinder experiments were performed in which magnetite and a hydrous, haplogranitic melt were equilibrated at 800 °C and 0.5 GPa over a range of oxygen fugacities (\({f_{{{\text{O}}_{\text{2}}}}}\)), bracketing those of terrestrial magmas. Magnetite is isotopically light with respect to the coexisting melt, a tendency ascribed to the VI-fold V³⁺ and V⁴⁺ in magnetite, and a mixture of IV- and VI-fold V⁵⁺ and V⁴⁺ in the melt. The magnitude of the fractionation factor systematically increases with increasing log\({f_{{{\text{O}}_{\text{2}}}}}\) relative to the Fayalite–Magnetite–Quartz buffer (FMQ), from ?⁵¹V_mag-gl = ? 0.63?±?0.09‰ at FMQ ? 1 to ? 0.92?±?0.11‰ (SD) at ≈?FMQ?+?5, reflecting constant V³⁺/V⁴⁺ in magnetite but increasing V⁵⁺/V⁴⁺ in the melt with increasing log\({f_{{{\text{O}}_{\text{2}}}}}\). These first mineral-melt measurements of V isotope fractionation factors underline the importance of both oxidation state and co-ordination environment in controlling isotopic fractionation. The fractionation factors determined experimentally are in excellent agreement with those needed to explain natural isotope variations in magmatic suites. Furthermore, these experiments provide a useful framework in which to interpret vanadium isotope variations in natural rocks and magnetites, and may be used as a potential fingerprint the redox state of the magma from which they crystallise.     

Extreme waves induced by cyclone Nargis at Myanmar coast: numerical modeling versus satellite observations

Natural Hazards - The deltaic coast of Myanmar was severely hit by tropical cyclone Nargis in May 2008. In the present study, a top-down numerical simulation approach using the Weather Research and...     

Microbial photosynthesis in coral reef sediments (Heron Reef, Australia)

We investigated microphytobenthic photosynthesis at four stations in the coral reef sediments at Heron Reef, Australia. The microphytobenthos was dominated by diatoms, dinoflagellates and cyanobacteria, as indicated by biomarker pigment analysis. Conspicuous algae firmly attached to the sand grains (ca. 100 μm in diameter, surrounded by a hard transparent wall) were rich in peridinin, a marker pigment for dinoflagellates, but also showed a high diversity based on cyanobacterial 16S rDNA gene sequence analysis. Specimens of these algae that were buried below the photic zone exhibited an unexpected stimulation of respiration by light, resulting in an increase of local oxygen concentrations upon darkening. Net photosynthesis of the sediments varied between 1.9 and 8.5 mmol O₂ m⁻² h⁻¹ and was strongly correlated with Chl a content, which lay between 31 and 84 mg m⁻². An estimate based on our spatially limited dataset indicates that the microphytobenthic production for the entire reef is in the order of magnitude of the production estimated for corals. Photosynthesis stimulated calcification at all investigated sites (0.2–1.0 mmol Ca²⁺ m⁻² h⁻¹). The sediments of at least three stations were net calcifying. Sedimentary N₂-fixation rates (measured by acetylene reduction assays at two sites) ranged between 0.9 to 3.9 mmol N₂ m⁻² h⁻¹ and were highest in the light, indicating the importance of heterocystous cyanobacteria. In coral fingers no N₂-fixation was measurable, which stresses the importance of the sediment compartment for reef nitrogen cycling.     

Using Statistical Downscaling to Quantify the GCM-Related Uncertainty in Regional Climate Change Scenarios： A Case Study of Swedish Precipitation

There are a number of sources of uncertainty in regional climate change scenarios. When statistical downscaling is used to obtain regional climate change scenarios, the uncertainty may originate from the uncertainties in the global climate models used, the skill of the statistical model, and the forcing scenarios applied to the global climate model. The uncertainty associated with global climate models can be evaluated by examining the differences in the predictors and in the downscaled climate change scenarios based on a set of different global climate models. When standardized global climate model simulations such as the second phase of the Coupled Model Intercomparison Project （CMIP2） are used, the difference in the downscaled variables mainly reflects differences in the climate models and the natural variability in the simulated climates. It is proposed that the spread of the estimates can be taken as a measure of the uncertainty associated with global climate models. The proposed method is applied to the estimation of global-climate-model-related uncertainty in regional precipitation change scenarios in Sweden. Results from statistical downscaling based on 17 global climate models show that there is an overall increase in annual precipitation all over Sweden although a considerable spread of the changes in the precipitation exists. The general increase can be attributed to the increased large-scale precipitation and the enhanced westerly wind. The estimated uncertainty is nearly independent of region. However, there is a seasonal dependence. The estimates for winter show the highest level of confidence, while the estimates for summer show the least.