Dating the exhumation of UHP rocks and associated crustal melting in the Norwegian Caledonides

U–Pb and Rb–Sr dating was undertaken in combination with P–T estimates to (1) constrain the time of ultrahigh-pressure (UHP) eclogite formation in the Stadlandet UHP province of Norway, (2) date later crustal melting–migmatization of the eclogite country gneisses, and (3) temporally trace post-migmatite cooling and retrogression under amphibolite facies metamorphic conditions. In contrast to earlier U–Pb studies which used accessory minerals from the gneisses, we focused on the direct dating of minerals defining the HP assemblage. For the eclogite, rutile and omphacite fractions were analyzed for U–Pb, and from an adjacent migmatite leucosome titanites and K-feldspar. For Rb–Sr dating, phengite was measured for the eclogite, and biotite for two leucosome layers of the migmatite–eclogite complex. A U–Pb age of 389±7 (2σ) Ma is obtained if the full set of 12 rutile and five omphacite analyses is regressed (MSWD: 16), and 389±2 Ma for those nine data which strictly satisfy isochron conditions (MSWD: 0.78). The 389-Ma age is interpreted to date equilibration and freezing of the eclogite paragenesis at maximum temperatures of 770 °C, reached during decompression to 1.8 GPa. Decompression from 2.8 to 1.8 GPa occurred in the partial melting domain of granitic crust, with the migmatites being dated at 375±6 Ma by titanite and K-feldspar from an eclogite-adjacent granitic leucosome. This titanite age also shows that the U–Pb chronometer in rutile is very robust to high temperatures—it remained a closed system for at least 14 million years, at temperatures in excess to 650 °C. After decompression and migmatization, exhumation is accompanied by rapid cooling to reach the 300 °C isograde by 357± 9 Ma, determined by a biotite isochron for a leucosome in a slightly shallower structural level. In considering that the time of maximum pressure is bracketed by early zircon crystallization during subduction and later omphacite–rutile equilibration in the eclogites, an exhumation rate of 5 mm/year is deduced for initial exhumation, occurring between 394 and 389 Ma. For subsequent cooling from 770 to 600 °C, we obtain a rate of 2.3±1.3 mm/year. First stages of exhumation most likely occurred under an overall compressional regime, whereas Devonian basin formation is associated to detachment movements during 389–375 Ma exhumation. This period of extension is followed by a much younger, decoupled thermal phase at 327±5 Ma, occurring under static conditions within very restricted zones, most likely in association with the circulation of fluid phases along old discontinuities. Initial isotopic signatures of Sr and Pb substantiate Paleo- to Meso-Proterozoic crust formation times of the Stadlandet UHP province precursor lithologies.     

Luna 20 soil: abundance of 17 trace elements

Luna 20 soil is remarkably similar to Apollo 16 soil, in its content of 17 mainly volatile or siderophile elements: Ag, Au, Bi, Br, Cd, Cs, Ge, In, Ir, Rb, Re, Sb, Se, Te, Tl, U, and Zn. Like other highland soils, it seems to contain an ancient meteoritic component of fractionated, volatile-poor composition. The bulk soil has a high $\text{Tl}\text{Cs}$ ratio (9.4 × 10^?2), similar to that in Apollo 16 soils (5.4 × 10^?2), but higher than that in samples from other sites (1.1 × 10^?2). It is severely contaminated with Ag, Cd, Re, and Sb, judging from a comparison with a 1.7 mg soil breccia sample from the coarse fraction of the soil.     

Survey and monitoring of landslide displacements by means of L-band satellite SAR interferometry

This paper illustrates the capabilities of L-band satellite SAR interferometry for the investigation of landslide displacements. SAR data acquired by the L-band JERS satellite over the Italian and Swiss Alps have been analyzed together with C-band ERS-1/2 SAR data and in situ information. The use of L-band SAR data with a wavelength larger than the usual C-band, generally considered for ground motion measurements, reduces some of the limitations of differential SAR interferometry, in particular, signal decorrelation induced by vegetation cover and rapid displacements. The sites of the Alta Val Badia region in South Tyrol (Italy), Ruinon in Lombardia (Italy), Saas Grund in Valais (Switzerland) and Campo Vallemaggia in Ticino (Switzerland), representing a comprehensive set of different mass wasting phenomena in various environments, are considered. The landslides in the Alta Val Badia region are good examples for presenting the improved performance of L-band in comparison to C-band for vegetated areas, in particular concerning open forest. The landslides of Ruinon, Saas Grund, and Campo Vallemaggia demonstrate the strength of L-band in observing moderately fast displacements in comparison to C-band. This work, performed with historical SAR data from a satellite which operated until 1998, demonstrates the capabilities of future planned L-band SAR missions, like ALOS and TerraSAR-L, for landslide studies.     

Gabbro and related rock emplacement beneath rifting continental crust: UPb geochronological and geochemical constraints for the Galicia passive margin (Spain)

The thinned continental crust of the west Galicia margin is bound by a belt of serpentinized peridotites (‘peridotite ridge’) lying about 300 km off the coast in the North Atlantic ocean. From this ridge, a gabbro and a chlorite rock were studied in an attempt to substantiate rift-related subcontinental magmatism, occurring prior to sea-floor spreading. U-Pb dating of 13 different zircon fractions yields a precise age of 122.1 ± 0.3 Ma (2σ) for the emplacement of the chlorite rock protolith, from which more than 50% of Si and alkali-calc-alkali elements were lost during greenschist facies tectonometamorphism. Sr and Nd isotope signatures suggest that the gabbro and chlorite rock protoliths were derived from mantle sources that were moderately depleted in LILE, relative to a chondritic reservoir. No evidence for the presence of continental material in the magma source regions can be observed. From the new zircon age of 122.1 ± 0.3 Ma, and earlier determined³⁹Ar⁴⁰Ar age of 122.0 ± 0.6 Ma for amphibole from the same locality, it can be documented that magma formation, solidification and unroofing of the mantle rocks occurred during a short period of time of about 3.4 Ma, which means that the peridotite ridge detached from the continent and rose to the surface immediately after, or even coevally with mantle melting.     

Halogen contamination in Antarctic H5 and H6 chondrites and relation to sites of recovery

The distribution of the elements F, Cl, Br and I was analysed in layers removed stepwise from Antarctic H5 and H6 chondrites. All meteorites show higher concentrations of these elements on their surfaces than in their interiors. The degree of halogen enrichment cannot be correlated with the degree of visual weathering and is proportional to the time the meteorites were residing on the surface of the Antarctic ice. During this period, aerosols, salts and gaseous components are deposited on the surfaces of the meteorites and diffuse into their interior. The observed contamination level of the meteorites is influenced by leaching properties and diffusion behaviour of the individual halogens. The major contamination source for F, Cl and probably Br is air-borne seaspray; for I it is the gaseous compound methyl iodide (CH₃I) produced by biological processes in the sea. Methyl iodide and its oxidation products formed in the Antarctic atmosphere (e.g., I₂) can be transported over longer distances to the interior of Antarctica than air-borne seaspray. Therefore, the ratio of the halogen contamination is related to the collection site of the meteorites. All meteorites that were found in the Antarctic interior are contaminated to a lesser degree by F, Cl and Br relative to I than those found near the coast. The measured enrichment ratio of I/F is a function of the distance between the collection site and the open sea, and increases from the Allan Hills to the Thiel Mountains. By revealing the degree of contamination of a meteorite it is possible to determine its maximum surface residence time on the Antarctic ice.     

U(Th)Pb systematics and ages of Himalayan leucogranites, South Tibet

The age and origin of five leucogranites from the High and Tethys Himalaya, and two country-rock gneisses were investigated by UPb dating of zircon fractions and single grains, and fractions of monazite. Additionally, ThU concentrations in whole rock powders and isotopic compositions of Pb in leached K-feldspars were determined. Monazites yield ages of 16.8 ± 0.6 m.y. for the Nialam migmatite-granite, 15.1 ± 0.5 m.y. for the Lhagoi Kangri granite, 14.3 ± 0.6 m.y. for a granite from Mt. Everest, and 9.8 ± 0.7 m.y. and 9.2 ± 0.9 m.y. for two varieties of the Maja granite. These data, together with monazite ages of 21.9 ± 0.2 and 24.0 ± 0.4 m.y., determined earlier on the Makalu granite [1], substantiate a period of intracontinental granite emplacements from 24 to 9 m.y. ago, i.e. from uppermost Oligocene to late Miocene times. Such a period of plutonic activity is consistent with the view that all these granites result from intracrustal melting following the collision of India with Eurasia. Furthermore, the individual ages, together with structural relationships between granites and country rocks suggest that granite formation and tectono-metamorphism occurred as alternating and strongly related processes with a periodicity of 7 to 9 m.y. Inherited lead components, present in all granite zircons point to large proportions of Precambrian material in the magma source regions, up to 2200 m.y. old.ThU systematics between monazite and country rocks indicate that U has been leached from most of the granites after crystallisation of monazite.Zircon dating of the Kangmar granite gneiss, which occurs in a window through the Tethys Himalayan sediments, shows that this pluton, transformed to a gneiss during the Alpine orogeny, crystallised in lowermost Palaeozoic times 562 ± 4 m.y. ago.     

A parameterization of the nocturnal ozone reduction in the residual layer by verticla downward mixing during summer smog situations using sodar data

The reduction of ozone in the nocturnal residual layer by vertical mixing to the surface was investigated for several summer smog episodes on the Swiss plateau in the years 1990 and 1991. Using a limited data set of SODAR measurements and surface ozone concentrations, a parameterization of the ozone depletion in the nocturnal residual layer due to vertical mixing to the ground is proposed. This model is not intended to be physically complete but is rather simple with limited input information required. The nocturnal ozone reduction within the whole planetary boundary layer (nocturnal boundary layer plus residual layer) over the complex terrain of the Swiss plateau for the days investigated is between 20 and 50%.     

Chemical and geochemical studies of Lake Biel

The mixing and transport processes in Lake Biel have been studied using the heat and excess Rn-222 as natural tracers. The mixing parameters were established in terms of coefficients of eddy diffusion in a two-dimensional box model. To account for observed transient Rn-222 distribution, transport by advection had to be included in the model calculations. Part I: Peter W. Santschi and Paul W. Schindler: A mass balance for Lake Biel and its implications for the rates of erosion of the drainage area. Schweiz. Z. Hydrol.39, 182–200 (1977).