Geochemical processes controlling the spatial distribution of selenium in soil and water,west central South Dakota,USA

Selenium (Se) is essential in the human diet, but has a low threshold for toxic concentration. It is recommended that nutrients such as Se should be consumed through foods as part of a normal diet. Se concentrations in crops and meat depend on the amount of labile Se in the soil where crops and forage are grown. Therefore, managing agriculture for optimal Se in grain crops and forage requires an understanding of the distribution and mobility of Se. Elevated concentrations of Se occur in waters, soils, and forage 120 km west of Pierre in west central South Dakota, USA. The research site lies in an elevated, dissected plain where soils developed on gently dipping Pierre Shale. Soils were sampled along catena transects and waters collected from soil, ponds, and shallow borings in areas of known elevated forage and crop Se. Soil extracts from saturated-paste extraction and acid (aqua regia and hydrofluoric acid) extraction were analyzed. Selenate was the dominant Se species in both acid and saturated-paste extracts; selenite and organic Se were below detection (<0.2 ppb) in the same soil extracts. On average, 98% of soil Se was not water-soluble. The distribution of total Se shows much less spatial variation than water-soluble Se in the areas sampled. Se shows correlation with organic carbon in soils and waters, suggesting its association with organic carbon. Ca shows some correlation to Se in acid extracts, but not in saturated-paste extracts or in waters. Total Se shows no significant correlation to Na, Mg, and total S in the soils. Se in saturated-paste extracts and water samples shows good correlations with Na, Mg, and SO₄, suggesting that evaporitic Na–Mg–sulfate minerals may temporarily concentrate water-soluble Se in shallow soils. The dissolution and precipitation of these Na–Mg–sulfate salts together with pH and oxidation–reduction conditions apparently control water-soluble Se distribution and mobilization in shallow subsurface environments.     

UBV photometry of RT Persei

Photoelectric and absolute elements of the system RT Per have been determined inU, B, andV filters. It is suggested that the primary star may be surrounded by a gaseous disk.     

Surface sensible heat flux over a deep moist convective region and its interplay with synoptic and mesoscale features

The surface parameters are being evaluated using a methodology which considers the vertical temperature structure of MONTBLEX ’90. For this 30 metre micrometeorological tower data are utilised. In this process, a concept of isolated layers has been introduced. The parameters have been evaluated following two successive iterative processes to give a consistent value both in the flux-profile relation and the related similarity relation. The heat flux obtained using the present methodology, is then utilised to examine its interplay with the synoptic as well as mesoscale features. The existence of such an interplay is observed.     

Comparative ecophysiology of active zoobenthic filter feeding, essence of current knowledge

The present contribution gives an overview of current knowledge of a comprehensive and steadily growing research field. The first section deals with water pumping and particle retention mechanisms in ciliary and muscular filter feeders. The second section examines the biological filter pumps in order to assess adaptation to the environment. Filter-feeding benthic invertebrates have evolved filter pumps to solve common basic problems. This has led to a large degree of similarity between otherwise distant standing species, which makes comparative studies interesting and important. The present review of zoobenthic filter feeding aims at accentuating such recognition.     

Late-Quaternary supply of terrigenous organic matter to the Congo deep-sea fan (ODP site 1075): implications for equatorial African paleoclimate

Late-Quaternary sections (about 1 Ma) from the Congo deep-sea fan (ODP Leg 175, site 1075) were used to reconstruct the terrigenous organic matter supply to the easternmost equatorial Atlantic Ocean. Variations in quantity and quality of the riverine organic matter reflect the interaction between the paleoclimatic development within the continental catchment area and the paleoceanographic conditions in the Congo river plume. To characterize the delivery of organic matter from terrigenous and marine sources, we used elemental and bulk carbon isotopic analyses, Rock-Eval pyrolysis, lignin chemistry, and organic petrology. High-amplitude fluctuations occurring about every 15-25 ka reveal a mainly precessional control on organic sedimentation. Results from Rock-Eval pyrolysis indicate a mixed kerogen type III/II, as would be anticipated in front of a major river. Fluctuations in T_max from Rock-Eval pyrolysis demonstrate pronounced cyclic changes in the delivery of low- and high-mature organic matter. Contribution of the low-mature organic fraction was strongest during warm climates supporting enhanced marine production offshore of the Congo. Organic petrological observations confirm the existence of abundant terrigenous plant tissues, both non-oxidized (vitrinite) and oxidized (inertinite). Charcoal-like organic matter (fusinite) is attributed to periods of increased bush fires in the continental hinterland, and implies more arid climatic conditions. Results from ratios of specific phenolic lignin components suggest that terrigenous organic matter in Late-Quaternary sections of site 1075 mainly derives from non-woody angiosperm tissue, i.e., grasses and leaves. Correlation between the amount of specific lignin phenols and the bulk '¹³C_org signature fosters the conclusion that an appreciable amount of the terrigenous organic fraction derives from C4 plant matter. This may cause an underestimation of the terrigenous proportion of bulk organic matter when assessments are based on bulk carbon isotopic signatures alone.     

Hydrologic and sedimentologic aspects of mining aggregate from the shipsk bank (Baltic sea)

Abstract

Investigations aimed at obtaining knowledge about the environmental effects of mining aggregate from the sea bottom were carried out on the Stupsk Bank. Special attention was given to the magnitude and reach of changes of hydrologic conditions, in that to changes in concentration of matter suspended in sea water, and to dynamics of the sea bottom—change of bottom relief, resulting from both natural causes and from mining of the aggregate.     

Study of a wave energy device for possible application in communication and spacecraft propulsion

A possible scheme for utilizing ocean wave energy to generate a high power laser is examined. Such a laser can be used (i) unguided communication under water or through the atmosphere, and (ii) in spacecraft propulsion. The natural frequencies and the frequency response of the proposed two degree-of-freedom primary energy converter are obtained by using Lagrange's equations. Further, it is shown that the basic principle used in primary energy conversion can be developed into a mechanism for roll stabilization of marine vessels.     

Multistatic estimation of high-frequency radar surface currents in the region of Toulon

Ocean Dynamics - The high-frequency radar coastal network in Toulon operates in multistatic mode for the monitoring of the ocean circulation in the Northwestern Mediterranean Sea. With 2...