Colluvial deposits in northwest Deccan,India: their significance in the interpretation of Late Quaternary history

The Deccan Trap region exhibits an erosional landscape over a relatively ancient and stable Deccan shield. The Quaternary history of the area has been reconstructed on the basis of evidence from alluvial deposits occurring along the major rivers. However, recent investigations have revealed that evidence for geo-environmental change during the Quaternary Period is also contained in the colluvial deposits that occur in the foothill zones. The colluvial deposits, ranging in thickness from 1 to 10 m, invariably occupy gently inclined pediment slopes. The sediments are presently deeply dissected by gullies, and the process of colluviation has almost ceased. These deposits are best preserved in the semi-arid parts of the region. Detailed textural, geochemical and stratigraphical studies at four different sites reveal similar input processes, the slight variations being attributed to local environmental factors. Scanning electron microscopy studies of some grains indicate marginal contribution of aeolian processes at the time of deposition. Mesolithic artefacts and a few U/Th dates indicate that the colluviation took place during the Late Quaternary. The properties of the deposits suggest relatively high energy conditions as well as a remarkable variability in the intensity of hillslope processes. These properties are indicative of semi-arid conditions during which the regolith was stripped from devegetated hillslopes and was deposited on the pediments. A variety of evidence indicates that the period of colluviation coincided with arid conditions during the Last Glacial Maximum. The geomorphological and archaeological evidence also indicates that incision by gully systems was initiated during the early Holocene humid phase. The environmental conditions deduced for the study area are similar to those reported for other parts of the intertropical zone. © 1997 John Wiley & Sons, Ltd.     

Holocene lateral expansion, peat growth and carbon accumulation on Haukkasuo, a raised bog in southeastern Finland

Paludification intensity and peat deposition on Haukkasuo bog in southeastern Finland were studied with peat stratigraphic investigations by taking 79 samples for ¹⁴C carbon dating and 164 volumetric samples. Peat formation of Haukkasuo, a concentric raised bog, began about 10 400 cal. BP. Lateral expansion has been largely controlled by the flat clayey floor, which has favoured rapid growth of the bog. During the first 400 years of its existence the bog covered one-fifth, and in the following 2000 years one-half, of its present extent. The long-term carbon accumulation rate averages 22.3 g C/m²/yr in the central part of Haukkasuo and 16.7 g C/m²/yr in its margins. The highest rates of carbon accumulation over 500-year periods were recorded in the central part of the bog in 6500–5500, 3500–2500 and 1500–0 cal. BP. The rate of vertical peat increment was higher than average in these periods, and the peat was mainly slightly humified and, when close to the surface, un compacted. The rate of carbon accumulation was lowest in 5500–3500 and 2500–2000 cal. BP, when the rate of vertical growth was lower than average and the peat was more humified than average. The formation of peat, the rate of vertical peat increment and the succession of peat types in Haukkasuo have mainly been controlled by hydrological changes caused by local factors, although climatic factors might also be important. In particular, the formation of slightly humified peat in 3300–2700 cal. BP and during the last 1300 years can be related to humid climate.     

Late Paleozoic geology of the Queensland Plateau (offshore northeastern Australia)

The southwestern Pacific region consists of segmented and translated continental fragments of the Gondwanan margin. Tectonic reconstructions of this region are challenged by the fact that many fragmented continental blocks are submerged and/or concealed under younger sedimentary cover. The Queensland Plateau (offshore northeastern Australia) is one such submerged continental block. We present detrital zircon geochronological and morphological data, complemented by petrographic observations, from samples obtained from the only two drill cores that penetrated the Paleozoic metasedimentary strata of the Queensland Plateau (Ocean Drilling Program leg 133, sites 824 and 825). Results provide maximum age constraints of 319.4 ± 3.5 and 298.9 ± 2.5 Ma for the time of deposition, which in conjunction with evidence for deformation, indicate that the metasedimentary successions are most likely upper Carboniferous to lower Permian. A comparison of our results with a larger dataset of detrital zircon ages from the Tasmanides suggests that the Paleozoic successions of the Queensland Plateau formed in a backarc basin that was part of the northern continuation of the New England Orogen and/or the East Australian Rift System. However, unlike most of the New England Orogen, a distinctive component of the detrital zircon age spectra of the Mossman Orogen is also recognised, suggesting the existence of a late Paleozoic drainage system that crossed the northern Tasmanides en route from the North Australian Craton. A distinctive shift from abraded zircon grains to grains with well-preserved morphology at ca 305 Ma reflects a direct drainage of first-cycle sediments, most likely from an outboard arc and/or backarc magmatism.     

Magnetic thermodynamics as proxy for chemical inhomogeneity in hemo-ilmenite solid solutions

In this study, we present ac susceptibility measurements for a synthetic and a natural hemo-ilmenite (HI) solid solution (x)FeTiO₃–(1 − x)Fe₂O₃ with compositions x = 0.87(1) and 0.88(8), respectively. The focus of the investigation is the magnetic ordering at the Curie temperature T _C and the spin-glass-like freezing at the freezing temperature T _f. The sharpness of T _C for the synthetic solid solution with well-defined structure indicates the chemical homogeneity of the solution, whereas the disperse magnetic ordering of the natural solid solution reveals inhomogeneities described as spin glass system ofvariations in composition x. The frequency dispersion of T _f was determined between 10 Hz and 10 kHz and was found to obey a dynamic scaling power law. The relaxation rates deviate by five orders of magnitude where the synthetic solid solution exhibits ω₀ = 3(1) × 10⁴ Hz and the natural one 5.5 × 10⁹ Hz. The strong deviation is attributed to the difference in the ordered state above T _f. These findings provide an insight into the cooling-rate effects of natural solid solutions and how magnetic thermodynamics can be used to probe the chemical homogeneity of such systems.     

Monitoring Koyulhisar landslide using rapid static GPS: a strategy to remove biases from vertical velocities

GPS is frequently used in the monitoring of natural hazards and other geophysical phenomena. Landslide monitoring is one such area in which various GPS methods are tested and various systematic error sources are introduced. In previous studies, one error source introduced on rapid static GPS was the effect of large height differences in GPS positions. In this study, we further investigate how GPS velocities/slip rates are affected by large station height differences when rapid static surveying is used. In order to demonstrate the influences, we used static GPS measurements from the Koyulhisar landslide in central Turkey. Comparison of rapid static GPS solutions with static GPS solutions using BERNESE 5.0 indicates that systematic biases occur in the estimated rapid static GPS deformation rates when the station height difference is large between baseline points. The effect is more significant on the vertical component, whereas it is negligible on the horizontal components. When reducing the height difference between the reference station and the rover stations, rapid static solutions from 15-min sessions show high correlation and similar deformation rates with static positioning solutions.     

Seasonal variation in bacterial heavy metal biosorption in water samples from Eziama river near soap and brewery industries and the environmental health implications

Seasonal variation in bacterial heavy metals biosorption from soap and brewery industrial effluent samples from Eziama River in Abia State were analyzed for Pb, Hg, Fe, Zn, As, and Mn, using atomic absorption spectrophotometry. Bioaccumulation of the metals by bacteria showed the following trend > Fe >Zn >As > Pb > Mn (Rainy Season) and Zn > Fe > Mn > As > Hg > Pb (Dry season). Statistical analysis using of variance (ANOVA) showed significant differences in concentrations of Pb, Hg, Fe, Zn, As, and Mn level between the sampling zones at Eziama River. Seasonal changes in heavy metal concentrations, showed increases in Pb, Fe, and As from 1.32 x 10⁵ mg/L in the rainy season to 1.42 x 10⁵ mg/L in the dry season. Fe increased from 40.35 x 10⁵ mg/L to 42.1 x 10⁵ mg/L, while As increased from 2.32 to 2.48 x 10⁵ mg/L with a net increases of+56 and + 69 x 10⁵ mg/L respectively. However, Hg, Zn, and Mn concentrations decreased in the rainy season from 40.54 x 10⁵ mg/L to 39.24 x 10⁵ mg/L, 1.65 to 0.62 x 10⁵ mg/L respectively.     

Systematic errors in the medium range prediction of the Asian summer monsoon circulation

The present study describes an analysis of Asian summer monsoon forecasts with an operational general circulation model (GCM) of the European Centre for Medium Range Weather Forecasts (ECMWF), U.K. An attempt is made to examine the influence of improved treatment of physical processes on the reduction of systematic errors. As some of the major changes in the parameterization of physical processes, such as modification to the infrared radiation scheme, deep cumulus convection scheme, introduction of the shallow convection scheme etc., were introduced during 1985–88, a thorough systematic error analysis of the ECMWF monsoon forecasts is carried out for a period prior to the incorporation of such changes i.e. summer monsoon season (June–August) of 1984, and for the corresponding period after relevant changes were implemented (summer monsoon season of 1988). Monsoon forecasts of the ECMWF demonstrate an increasing trend of forecast skill after the implementation of the major changes in parameterizations of radiation, convection and land-surface processes. Further, the upper level flow is found to be more predictable than that of the lower level and wind forecasts display a better skill than temperature. Apart from this, a notable increase in the magnitudes of persistence error statistics indicates that the monsoon circulation in the analysed fields became more intense with the introduction of changes in the operational forecasting system. Although, considerable reduction in systematic errors of the Asian summer monsoon forecasts is observed (up to day-5) with the introduction of major changes in the treatment of physical processes, the nature of errors remain unchanged (by day-10). The forecast errors of temperature and moisture in the middle troposphere are also reduced due to the changes in treatment of longwave radiation. Moreover, the introduction of shallow convection helped it further by enhancing the vertical transports of heat and moisture from the lower troposphere. Though, the hydrological cycle in the operational forecasts appears to have enhanced with the major modifications and improvements to the physical parameterization schemes, certain regional peculiarities have developed in the simulated rainfall distribution over the monsoon region. Hence, this study suggests further attempts to improve the formulations of physical processes for further reduction of systematic forecast errors.     

Isotope evidence for ijolite formation by fenitization: Sr−Nd data of ijolites from the type locality Iivaara,Finland

Ijolites from the type locality at Iivaara, Finland, form a continuous series of magmatic rocks ranging from urtites to melteigites. Both Ni and Cr, but also the large ion lithophile light-rare-earth elements, Zr, Hf, Nb, Rb, Sr and Ba are low in concentration. The Nd contents equal those of the neighboring fenites, Sr is distinctly less abundant, and there is no significant Eu anomaly. The ¹⁴³Nd/¹⁴⁴Nd and ⁸⁷Sr/⁸⁶Sr of the ijolites demonstrate a systematic covariation between the data of carbonaties from the Kola Alkaline Province (_Sr – 13.8, _Nd + 5.6) and those of the fenites at Iivaara (_Sr + 132.9, _Nd – 24.7) with _Sr varying from +0.3 to +23.9 and _Nd varying from-9.2 to-19.3. The trace element abundances and the isotopic data give evidence for a crystallization of the rocks from a liquid generated by melting (rheomorphism) of high-grade fenitized country rocks rather than from a primary mantle-derived magma which was contaminated at crustal levels. The fenitization of wall rocks preceding the ijolite magma formation was clement selective. Mixing of elements during the fenitization process between the designated components carbonatite (or derivative fenitizing fluid) and wall rock should have been dynamical depending on the stability of the wall rock mineral assemblages in contact with the fenitizing fluids, the migration velocity of these fluids, and their capacity of the respective elements. Such dynamical mixing explains best the variation of the isotope ratios withont systematic covariation of the respective element concentrations.