构造物理化学的思路、研究和问题

构造物理化学是研究地壳物质受构造作用产生的物理和化学变化相互关联的领域。构造力可以分解为两部分一部分是均应力,指各向相等的应力,它叠加在原有压力之上,并且影响着各种化学反应的平衡,也是成岩、成矿和变质作用的影响因素。另一部分是差应力,固体中受外力作用普遍产生差应力,它引起地壳物质变形,产生各种构造形迹。构造物理化学特别关注构造作用产生或引起的压力、温度及其他的物理化学条件的变化,研究这些构造附加参量对各种化学平衡的影响,逐渐发展成为独立的学科研究领域。     

Oxidation and metal-insertion in molybdenite surfaces: evaluation of charge-transfer mechanisms and dynamics

Molybdenum disulfide (MoS₂), a layered transition-metal dichalcogenide, has been of special importance to the research community of geochemistry, materials and environmental chemistry, and geotechnical engineering. Understanding the oxidation behavior and charge-transfer mechanisms in MoS₂ is important to gain better insight into the degradation of this mineral in the environment. In addition, understanding the insertion of metals into molybdenite and evaluation of charge-transfer mechanism and dynamics is important to utilize these minerals in technological applications. Furthermore, a detailed investigation of thermal oxidation behavior and metal-insertion will provide a basis to further explore and model the mechanism of adsorption of metal ions onto geomedia.     

干旱区陆面过程参数改进对东亚区域气候影响的数值模拟

为了进一步检验裸土参数化的气候模拟性能,本文在文献[1,2]的基础上,利用NCEP再分析资料和Xie等全球降水资料与CCM3模拟结果进行了对比。结果表明：加入裸土参数化方案的CCM3能较好地再现冬季东亚和中国地区区域气候的主要特征,模式较原CCM3能更好地模拟地表温度和东亚及中国西北地区的降水,对东亚季风环流的模拟也较接近实际。同时,该方案在CCM3中的加入改进了青藏高原冬季降雪带及夏季高原东南部降水中心的模拟,提高了模式对高原冬夏季降水的模拟能力,从而再次说明利用观测资料对模式参数修正及参数化方法的改进是提高数值模式模拟能力的一个重要途径。     

不同土壤湿度条件下绿洲边界层特征的敏感性试验

应用NCAR的非静力平衡中尺度数值模式MM5V3．6,设计了三种不同土壤湿度对金塔绿洲边界层的特征影响的敏感性试验。结果表明：土壤灌溉后地表温度和气温升温率较灌溉前有所减小。土壤湿度越大,绿洲温度越低,绿洲的“冷岛效应”越显著。绿洲灌溉后地面感热通量较灌溉前偏低,潜热通量比灌溉前高;土壤湿度越大,这种差异越显著。土壤湿度为0．35时,绿洲能够很好地表现绿洲特性,维持其自身的发展。绿洲边界层高度在灌溉前后有很大的变化。随着土壤湿度的增加,绿洲的边界层高度逐渐降低。这种较低的边界层对绿洲起到了保护作用,它将绿洲的能量与水分保存任较低的边界层中,促进了绿洲的进一步维持和发展。     

Monthly prediction of rainfall over India and its homogeneous zones during monsoon season: a supervised principal component regression approach on general circulation model products

A supervised principal component regression (SPCR) technique has been employed on general circulation model (GCM) products for developing a monthly scale deterministic forecast of summer monsoon rainfall (June–July–August–September) for different homogeneous zones and India as a whole. The time series of the monthly observed rainfall as the predictand variable has been used from India Meteorological Department gridded (1°?×?1°) rainfall data. Lead 0 (forecast initialized in the same month) monthly products from GCMs are used as predictors. The sources of these GCMs are International Research Institute for Climate and Society, Columbia University, National Center for Environmental Prediction, and Japan Agency for Marine Earth Science and Technology. The performance of SPCR technique is judged against simple ensemble mean of GCMs (EM) and it is found that over almost all the zones the SPCR model gives better skill than EM in June, August, and September months of monsoon. The SPCR technique is able to capture the year to year observed rainfall variability in terms of sign as well as the magnitude. The independent forecasts of 2007 and 2008 are also analyzed for different monsoon months (Jun–Sep) in homogeneous zones and country. Here, 1982–2006 have been considered as development year or training period. Results of the study suggest that the SPCR model is able to catch the observational rainfall over India as a whole in June, August, and September in 2007 and June, July, and August in 2008.     

我国油气成藏机理与油气资源评价研究迈上新台阶——第四届油气成藏机理与油气资源评价国际学术研讨会在北京召开

由中国石油学会石油地质专业委员会、中国地质学会石油地质专业委员会、北京石油学会、国家自然科学基金委地学部、国土资源部油气资源战略研究中心和中国石油大学共同主办的“第四届油气成藏机理与油气资源评价国际学术研讨会”,于2006年10月14日-16日在中国北京顺利召开。共有260余位代表参加了这次大会,他们分别来自俄罗斯、加拿大、澳大利亚、英国、挪威、德国、韩国以及国内的18个科研院所和34个油田公司。这次大会提交的会议论文和摘要116篇,其中大会主题报告28篇,分会交流34篇。[第一段]     

High-frequency climatic oscillations during the last deglaciation as revealed by oxygen-isotope records of benthic organisms (Ammersee,southern Germany)

High-resolution oxygen-isotope records of benthic ostracods and molluscs from Ammersee, southern Germany, show high-frequency climatic changes during the last deglaciation and parallel in great detail published faunal and floral variations reconstructed from Norwegian Sea sediments and isotope variations in Greenland ice cores. The marine and the terrestrial records give evidence of a synchronous late glacial climatic development in Greenland, NW- and Mid-Europe. However,¹⁴C-ages of the supraregional climatic events and of two tephra layers in the marine sediments of the northeastern Atlantic Ocean are significantly older than the¹⁴C-ages of the corresponding horizons on land. These differences strongly suggest that major short-term events have affected the exchangeable carbon on earth during the dramatic environmental changes related to the deglaciation and in particular have affected the CO₂-distribution within the ocean and between ocean and atmosphere. Dating methods independent of climatic variations and of the global carbon budget should be given priority to refine the timescales of the marine and atmospheric processes during the last deglaciation.This is the fourth paper in a series of papers published in this issue on high-resolution paleolimnology. These papers were presented at the Sixth International Palaeolimnology Symposium held 19–21 April, 1993 at the Australian National University, Canberra, Australia. Dr. A. F. Lotter and Dr. M. Sturm served as guest editors for these papers.     

济阳坳陷中生代地层剥蚀厚度、原始厚度恢复及原型盆地研究

在采用各种地层剥蚀量的计算方法对济阳坳陷中生代各主要不整合面地层剥蚀厚度恢复的基础上,结合钻井及地震资料,对中生代各主要构造层的原始地层厚度进行了恢复。以此为切入点,对济阳坳陷区中生代盆地原型进行了初步探讨,将其划分为5期盆地原型：早-中三叠世为一大型内陆坳陷盆地;晚三叠世整体挤压抬升剥蚀;早-中侏罗世为弱挤压背景下的山间盆地;晚侏罗世-早白垩世为受正断层控制的断陷盆地;晚白垩世为断陷后的坳陷盆地。     

Mineralogical evidence for the derivation of metaluminous,potassic rocks from peralkaline precursors: The Cordon Syenite Complex (Philippines)

Summary Rocks from the Cordon Syenite Complex, located in the Philippine island arc, correspond to miaskitic (metaluminous) potassic lavas from the Roman Region and the Indonesian arc in terms of bulk rock chemistry. However, the mineral chemistry indicates a complex history of multiple equilibrations with liquids of different nature. T-site (Si + Al) occupancy in some clinopyroxenes and Ca contents of alkali feldspar phenocrysts indicate that these phases crystallized under the temperature-pressure subvolcanic regime from host liquids with progressively decreasing (Na + K)/Al ratio. In contrast to current views on the genesis of potassic rocks, it is suggested that differentiated leucite tephrite suites may be derived from peralkaline liquids by alkali loss. Magmas with affinities to lamproites may occur in the Philippine island arc, but a direct genetic relationship between subduction and alkaline/peralkaline magmatism remains questionable.

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Mineralogische Hinweise auf die Entstehung subalkalischer, K-reicher gesteine aus, peralkalischen Vorläufern: Der Syenit Komplex von Cordon (Philippinen)

Zusammenfassung Die Magmatite des im philippinischen Inselbogen gelegenen Syenitkomplexes von Cordon entsprechen in ihrem Gesamtgesteinschemismus den miaskitischen, K-reichen Vul kaniten der Romanischen Provinz und des indonesischen Inselbogens. Die chemische Zusammensetzung einzelner Mineralphasen deutet auf eine komplexere Genese unter Beteiligung von Magmen unterschiedlicher Alkalinität hin. Die Variation in der Besetzung der T-Position (Si + Al) in Klinopyroxenen und der Ca-Gehalte in Alkalifeldspäten wird dahingehend interpretiert, daß diese Phasen unter subvulkanischen Bedingungen aus Schmelzen mit abnehmenden (Na + K)/Al-Verhältnissen kristallisierten. Im Gegensatz zu gängigen Auffassungen wird daher angenommen, daß differenzierte Leucit-Tephrite aus mild-peralkalischen Magman hervorgehen können. Obwohl die K-reichen Magmatite des Syenitkomplexes von Cordon in einem Inselbogen gebildet wurden, ist ein direkter Zusammenhang mit Anreicherungsvorgängen im Bereich der Subduktionszone fraglich.

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Paper presented at the General Assembly of the International Association of Volcanology and Chemistry of the Earth Interior, Santa Fe, New Mexico, 1989.

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With 6 Figures     

The tropospheric distribution of formaldehyde during TROPOZ II

A series of 149 measurements of the HCHO mixing ratio were made between 0 and 10 km altitude and 70° N to 60° S latitude during TROPOZ II. The data show a vertical decrease of the HCHO mixing ratio with altitude at all latitudes and a broad latitudinal maximum in the HCHO mixing ratio between 30° N and 30° S at all altitudes. The measured mixing ratios of HCHO are considerably higher than those expected from CH₄ oxidation alone, but agree broadly with the average latitude by altitude distribution of HCHO derived by a 2D model including emissions of C₁–C₇ hydrocarbons. A number of the regional scale deviations of the measured HCHO distribution from the average modelled one can be explained in terms of the local wind field.