Seasonal variability of oxygen and hydrogen isotopes in a wetland system of the Yunnan-Guizhou Plateau,southwest China: a quantitative assessment of groundwater inflow fluxes

The Caohai Wetland serves as an important ecosystem on the Yunnan–Guizhou Plateau and as a nationally important nature reserve for migratory birds in China. In this study, surface water, groundwater and wetland water were collected for the measurement of environmental isotopes to reveal the seasonal variability of oxygen and hydrogen isotopes (δ¹⁸O, δD), sources of water, and groundwater inflow fluxes. Results showed that surface water and groundwater are of meteoric origin. The isotopes in samples of wetland water were well mixed vertically in seasons of both high-flow (September) and low-flow (April); however, marked seasonal and spatial variations were observed. During the high-flow season, the isotopic composition in surface wetland water varied from ?97.13 to ?41.73‰ for δD and from ?13.17 to ?4.70‰ for δ¹⁸O. The composition of stable isotopes in the eastern region of this wetland was lower than in the western region. These may have been influenced by uneven evaporation caused by the distribution of aquatic vegetation. During the low-flow season, δD and δ¹⁸O in the more open water with dead aquatic vegetation ranged from ?37.11 to ?11.77‰, and from ?4.25 to ?0.08‰, respectively. This may result from high evaporation rates in this season with the lowest atmospheric humidity. Groundwater fluxes were calculated by mass transfer and isotope mass balance approaches, suggesting that the water sources of the Caohai Wetland were mainly from groundwater in the high-flow season, while the groundwater has a smaller contribution to wetland water during the low-flow season.     

Stable isotope-guided analysis of biomagnification profiles of arsenic species in a tropical mangrove ecosystem

We performed stable carbon and nitrogen-guided analyses of biomagnification profiles of arsenic (As) species, including total As, lipid-soluble As, eight water-soluble As compounds (arsenobetaine (AB), arsenocholine (AC), tetramethylarsonium ion (TETRA), trimethylarsine oxide (TMAO), dimethylarsinic acid (DMA), monomethylarsonic acid (MMA), arsenate (As[V]), and arsenite (As[III])), and non-extracted As in a tropical mangrove ecosystem in the Ba Ria Vung Tau, South Vietnam. Arsenobetaine was the predominant As species (65-96% of water-soluble As). Simple linear regression slopes of log-transformed concentrations of total As, As fractions or individual As compounds on stable nitrogen isotopic ratio (δ15N) values are regarded as indices of biomagnification. In this ecosystem, lipid-soluble As (slope, 0.130) and AB (slope, 0.108) were significantly biomagnified through the food web; total As and other water-soluble As compounds were not. To our knowledge, this is one of the first reports on biomagnification profiles of As compounds from a tropical mangrove ecosystem.     

<Emphasis Type="Italic">In-situ</Emphasis> trace element analyses and Pb-Pb dating of zircons in granulite from Huangtuling,Dabieshan by LAM-ICP-MS

It is revealed by CL images that there are multi-stage growth internal structures of zircons in the Huangtuling granulite, including the inherited zircons, protolith zircons, sector and planar zone zircons and retrograde zircons. In-situ trace element compositions and Pb-Pb ages have been analyzed by LAM-ICP-MS. The sector and the planar zone domains show typical trace element characteristics of granulite zircon (low Th, U, Th/U, total REEs, clear negative Eu anomalies, relatively depleted HREE and small differential degree between MREE and HREE, etc.), indicating that they formed during granulite-facies metamorphism. The protolith zircons have trace element characteristics of crustal zircon (high Th, U, Th/U, total REEs and enriched HREEs, etc.). 12 analyzed spots on granulite-facies domains give a weighted mean ²⁰⁷Pb/²⁰⁶Pb age of (2154±26) Ma (MSWD = 3.8), which is the best estimated age of granulite-facies metamorphism of this sample. The weighted mean ²⁰⁷Pb/²⁰⁶Pb age of 5 analyzed spots on protolith zircon domains is (2714 ± 22) Ma (MSWD = 1.4), which represents the protolith forming time. The discovery of ca. 3.4 Ga inherited zircon indicates that there are Palaeoarchean continental materials in this area. The interpretation of formation conditions and the ages of zircons can be constrained by simultaneous in-situ analysis of trace elements and ages.     

天线相位中心偏差变化及改正模型对精密单点定位精度的影响

利用精密单点定位程序对IGS站的实测数据进行计算,结果表明:平面方向,天线相位中心偏差和变化对精密单点定位精度影响较小;高程方向,天线相位中心偏差可造成厘米级的影响,天线相位中心变化的影响约5 mm;相比相对天线相位中心改正模型,使用绝对相位改正模型具有更多优点,尤其用于高精度GPS授时其精度明显提高.     

龙永煤田童子岩组顶部鲕粒的矿物学特征及岩相意义

通过对龙永煤田童子岩组煤系顶部鲕状带"鲕粒"赋存规律及其矿物学特征、宏观特征、围岩特征的野外研究及镜下观察,分析了"鲕粒"的成因及其岩相意义,为龙永煤田童子岩组顶部地层提供了对比依据.     

多窗谱分析方法及其在全球变暖研究中的应用

多窗谱分析方法是一种低方差、高分辨的谱分析方法 ,尤其适合于非线性气候系统中高噪声背景下弱信号、时频演变信号的诊断分析。文中简要地介绍了多窗谱分析方法的基本原理 ,并将其用于近 1 5 0 a来全球及南、北半球温度变化的研究。结果表明 :(1 )在温度呈线性变暖的背景趋势下 ,北半球、全球年平均温度还具有显著的 40～ 70 a的准周期低频振荡 ,它们与变暖过程中的波动性密切相关 ;(2 )年代际振荡信号在北半球温度序列中也相当明显 ,南半球则存在多种低于 5 a尺度的显著振荡周期 ,半球或全球 ENSO振荡分量、QBO周期信号的振幅都具有缓变包络的特性 ;(3 )与传统功率谱估计、最大熵谱估计结果的对比表明 ,多窗谱分析方法方法得到的谱估计分辨力高 ,稳定性强。     

Quantitative Assessment of Impacts of Regional Climate and Human Activities on Saline-alkali Land Changes： A Case Study of Qian＇an County, Jilin Province

Interdecadal and interannual variations of saline-alkali land area in Qian’an County, Jilin Province, China were comprehensively analyzed in this paper by means of satellite remote sensing interpretation, field flux observations and regional climate diagnosis. The results show that on the interannual scale, the impact of climate factors accounts for 71.6% of the total variation of the saline-alkali land area, and that of human activities accounts for 28.4%. Therefore the impact of climate factors is obviously greater than that of human activities. On the interdecadal scale, the impact of climate factors on the increase of the saline-alkali land area accounts for 43.2%, and that of human activities accounts for 56.8%. The impact of human activities on the variation of saline-alkali land area is very clear on the interdecadal scale, and the negative impact of human activities on the environment should not be negligible. Besides, changes in the area of heavy saline-alkali land have some indication for development of saline-alkali land in Qian’an County.     

The metallogenic mechanism of the sandstone-type copper deposits in the Chuxiong Basin,Yunnan Province

The sandstone-type Cu deposits in the Chuxiong Basin occur in the Cretaceous Gaofengsi Formation and the Maotoushan Formation and the orebodies are stratoid and lenticular in form, structurally controlled by their stratigraphical position. Ore structures are dominated by impregnated and striped ones. In addition, it has been observed that copper mineralization is controlled by water-discharge and deformation structures. Orebodies are commonly seen on the gently inclined limbs of the anticline, with the involution front. Copper mineralization shows a distinct zonation. S, Pb isotope and REE data suggest that the copper would stem from the country rocks and the sulfur largely from the lower strata. During diagenesis oxidized Cu-bearing brines derived from the upper parts and reduced brines from the lower parts are involved in metallogenetic reactions in the stress neutral plane, which is the key to the formation of copper deposits in the Chuxiong Basin.

     

Analysis of the coupled relationship between grain yields and agricultural labor changes in China

In this paper we establish a model that expresses the coupled relationship between grain yield and agricultural labor changes in China, and present a preliminary discussion of the coupled processes involved in changes in these factors at the county level. Thus, we develop two coefficients on the basis of county-level statistical data for grain yield and agricultural labor for the years 1991, 2000, and 2010, namely, the grain-labor elasticity coefficient (GLEC) and the agricultural labor-transfer effect coefficient (ALTEC). The results of this study show that during the transformation process of agricultural development in China, different kinds of coupled relationships between grain yield and agricultural labor changes co-existed at the same time. For example, between 1991 and 2010, counties characterized by three different coupled modes (i.e., increasing grain yield and decreasing agricultural labor, increasing grain yield and agricultural labor, and decreasing grain yield and agricultural labor) account for 48.85%, 29.11%, and 19.74% of the total across the study area, respectively. Interestingly, a coupled relationship between increasing grain yield and decreasing agricultural labor is mainly concentrated in the traditional farming areas of China, while a coupled relationship between increasing grain yield and agricultural labor is primarily concentrated in pastoral areas and agro-pastoral ecotones in underdeveloped western China. At the same time, a coupled relationship between decreasing grain yield and agricultural labor is concentrated in areas that have experienced a rapid development transition in agriculture, especially the developed southeastern coast of China. The results of this study also show that between 1991 and 2010, 1961 counties experienced a decline in the proportion of agricultural labor; of these, 1452 are also characterized by increasing grain yield, 72.38% of the total. This coupled relationship between grain yield and changes in the proportion of agricultural labor shows a stepped fluctuation and has continually strengthened over time. Data show that mean values for the GLEC and ALTEC increased from–0.25 and–2.93 between 1991 and 2000 to–0.16 and–1.78 between 2000 and 2010, respectively. These changes in GLEC and ALTEC illustrate that the influence of agricultural labor changes on increasing grain yields has gradually diminished. Finally, the results of this study reveal that the ‘Hu Huanyong Line’ is a significant boundary sub-dividing this coupled relationship between grain yield and changes in agricultural labor.     

北塘口近岸海域水环境质量时空变化分析及预测

通过分析2005年-2010年北塘口及其邻近海域水环境现场调查资料,同时结合历史数据进行对比,结果表明:(1)北塘口河口水体中COD和BOD5超标严重,整体污染态势以2008年为界呈现先降低后升高的趋势;邻近海域水体中无机氮为最主要污染物,其中硝酸盐是无机氮中最主要组成部分,但丰水期时亚硝酸盐氮和枯水期时铵盐氮所占比例逐年升高,说明区域水体氧化还原环境的潜在变化;N/P比值远高于正常的Redfield 16比值表明,区域水体已处于潜在严重P限制状态,同时,区域严重富营养化状态也极易诱导区域赤潮爆发;(2)丰水期陆源无机氮大量输入,使区域水体大部分时间超该区域功能区划要求的Ⅳ类海水水质标准,但底质沉积物环境相对比较稳定,各监测项目全部符合一类海洋沉积物质量标准要求;(3)丰水期和枯水期时,活性磷酸盐含量1983年-1998年分别增加了16.6倍和17.2倍,1998年-2010年由于监控措施的加强,极大地降低了P排放,丰水期和枯水期时活性磷酸盐含量最大增幅分别降到了5.84倍和2.33倍,无机氮含量增幅也呈现明显减小趋势,1983年-1998年丰水期和枯水期分别增加了8.37倍和13.7倍,而1998年-2010年丰水期和枯水期最大增幅也仅为3.52倍和3.28倍;整体看来水质和底质环境有缓和趋势,但潜在威胁仍然严重.