Environmental discrimination based on quartz grain surface textures: a statistical investigation

ABSTRACT The relative abundance of thirty-two surface features identified on the surfaces of quartz sand grains from eight coded samples was noted independently by five scanning electron microscopists. These data (reduced to binary form) were the subject of canonical variate analyses which discriminated clearly between all samples. Thirteen variables were important in distinguishing between the eight samples. This indicates that there are no single key surface features which, on their own, would allow rapid environmental discrimination. The contention that a multiplicity of surface features should be recorded for the purpose of environmental discrimination is, therefore, upheld.
Operator variance, although considerable in the recognition of individual surface features, is negligible in discrimination of samples based on binary data. The SEM technique of analysis of quartz grain surface textures is a reliable and statistically valid means of discriminating between samples from different environments.     

Methane-derived high-Mg calcite submarine cement in Holocene nodules from the Fraser Delta, British Columbia, Canada

Carbonate nodules and slabs in late Holocene shelly terrigenous deposits of the modern Fraser River delta (～49°N) are formed close to the seafloor by precipitation from saline pore waters of mainly fibrous to bladed crystals of high-Mg (～ 10–20 mol% MgCO₃) calcite cement as coalescing isopachous crusts on grains. Previous reports that the cement is low-Mg calcite are not supported by this study. Highly negative δ¹³C values of ? 7 to ? 59‰ for the cements indicate that the bulk of their carbonate carbon was derived from the microbiological degradation of organic matter in the deltaic deposits during shallow burial. In particular, the production of biogenic methane (CH₄) by anaerobic bacterial fermentation, its upward migration, chemical or biological oxidation to CO₂ and neutralization in the near-surface sediment, and diffusion to microenvironments relatively enriched in organic components, are a possible set of conditions influencing the process and sites of carbonate cementation. Methane-derived Mg-calcite appears also to be the major submarine cement in several other modern occurrences of lithified shallow-water terrigenous sands and muds at non-tropical latitudes.     

Practical aspects of frequency-domain identification of dynamic models of marine structures from hydrodynamic data

The motion response of marine structures in waves can be studied using finite-dimensional linear-time-invariant approximating models. These models, obtained using system identification with data computed by hydrodynamic codes, find application in offshore training simulators, hardware-in-the-loop simulators for positioning control testing, and also in initial designs of wave-energy conversion devices. Different proposals have appeared in the literature to address the identification problem in both time and frequency domains, and recent work has highlighted the superiority of the frequency-domain methods. This paper summarises practical frequency-domain estimation algorithms that use constraints on model structure and parameters to refine the search of approximating parametric models. Practical issues associated with the identification are discussed, including the influence of radiation model accuracy in force-to-motion models, which are usually the ultimate modelling objective. The illustration examples in the paper are obtained using a freely available MATLAB toolbox developed by the authors, which implements the estimation algorithms described.     

The 2011 expedition to the El'gygytgyn impact structure,Northeast Russia: Toward a new geological map for the crater area

El'gygytgyn is a 3.6 Ma, 18 km diameter, impact crater formed in an approximately 88 Ma old volcanic target in Northeast Siberia. The structure has been the subject of a recent ICDP drilling project. In parallel to those efforts, a Russian‐German expedition was undertaken in summer 2011 to investigate the permafrost soil, lake terraces, and the volcanic rocks of the southern and eastern crater rim. This provided the unique opportunity for mapping and sampling of the volcanic target rocks around a large part of this complex impact structure. Samples from 43 outcrops were collected and analyzed petrographically and geochemically. The results were combined with earlier mapping outcomes to create a new geological map of this impact structure and its immediate environs, at the scale of 1:50,000. Compositions of our rock suites are compared with the lithologies of the 2009 ICDP drill core. The ignimbrite described as lower bedrock in the ICDP drill core shows petrographically and chemically strong similarities to the rhyolitic and rhyodacitic ignimbrites observed on surface. The suevite sequence exposed in the ICDP drill core is a mixture of all observed target rocks at their respective proportions in the area. In contrast to previous studies, the calculated average target composition of El'gygytgyn takes the contribution of the basic target rocks into consideration: mafic and intermediate rocks approximately 7.5%, and felsic rocks approximately 92.5%.     

Mineral equilibria constraints on open‐system melting in metamafic compositions

The recent development of activity–composition relations for mineral and melt phases in high‐grade metamafic rocks allows mineral equilibria tools to be used to further aid our understanding of partial melting and the mineralogical consequences of melt segregation in these rocks. We show that bulk compositional data from natural amphibolites cover a wide compositional range, with particular variability in the content and ratios of Ca, Na and K indicating that low‐grade metasomatic alteration can substantially alter the igneous protolith chemistry and potentially affect the volume and composition of melt generated. Mineral equilibria calculations for five samples that span the compositional variability in our data set indicate that melting occurs primarily via the fluid‐absent breakdown of amphibole+quartz to produce a pressure‐sensitive peritectic assemblage of augite, orthopyroxene and/or garnet. The introduction of orthopyroxene at the onset of the amphibolite‐to‐granulite‐facies transition at lower pressure results in an increased rate of melt production until quartz is typically exhausted, and this is similarly seen for the introduction of garnet at higher pressure. Calculated melt compositions are dependent on the protolith composition, but initial solidus melting and biotite breakdown produce 1–3 mol.% of K‐rich granitic melts. As hornblende melting proceeds, 15–20 vol.% of either more granodioritic‐to‐tonalitic or granodioritic‐to‐trondhjemitic melt is produced. Once quartz is exhausted, intermediate to mafic melt compositions are produced at ultrahigh‐temperature conditions. Quartz‐rich lithologies with high Ca coupled to low Na and K are the most fertile under orogenic conditions, yielding up to 25 mol.% of sub‐alkalic granitic melt by 850°C. Such rocks did not experience significant subsolidus alteration. Altered compositions with low Ca and elevated Na and K are not as fertile, yielding less than 15 mol.% of alkalic granitic melt by 850°C. These melt volumes are enough to be segregated, and can make a contribution to granite magmatism and intracrustal differentiation that should not be overlooked.     

Spatial and Temporal Validation of In-Situ and Satellite Weather Data for the South West Agricultural Region of Australia

Seasonal variations in weather have significant impacts on crop yields. The accuracy of weather data is an import-ant consideration for crop yield models. This ...