Shape,metal abundance,chemistry, and origin of chondrules in the Renazzo (CR) chondrite

Abstract— We used synchrotron X‐ray microtomography to image in 3‐dimensions (3D) eight whole chondrules in a ?1 cm³piece of the Renazzo (CR) chondrite at ?17 μm per volume element (voxel) edge. We report the first volumetric (3D) measurement of metal/silicate ratios in chondrules and quantify indices of chondrule sphericity. Volumetric metal abundances in whole chondrules range from 1 to 37 volume % in 8 measured chondrules and by inspection in tomography data. We show that metal abundances and metal grain locations in individual chondrules cannot be reliably obtained from single random 2D sections. Samples were physically cut to intersect representative chondrules multiple times and to verify 3D data. Detailed 2D chemical analysis combined with 3D data yield highly variable whole‐chondrule Mg/Si ratios with a supra‐chondritic mean value, yet the chemically diverse, independently formed chondrules are mutually complementary in preserving chondritic (solar) Fe/Si ratios in the aggregate CR chondrite. These results are consistent with localized chondrule formation and rapid accretion resulting in chondrule + matrix aggregates (meteorite parent bodies) that preserve the bulk chondritic composition of source regions.     

A New Interlaboratory Characterisation of Silicon,Rare Earth Elements and Twenty‐Two Other Trace Element Concentrations in the Natural River Water Certified Reference Material SLRS‐6 (NRC‐CNRC)

The natural river water reference material SLRS‐6 (NRC‐CNRC) is the newest batch of a quality control material routinely used in many international environmental laboratories. This work presents a nine‐laboratory compilation of measurements of major and trace element concentrations and their related uncertainties, unavailable in the NRC‐CNRC certificate (B, Cs, Li, Ga, Ge, Hf, Nb, P, Rb, Rh, Re, S, Sc, Se, Si, Sn, Th, Ti, Tl, W, Y, Y, Zr and REEs). Measurements were mostly made using inductively coupled plasma‐mass spectrometry. The results are compared with equivalent data for the last batch of the material, SLRS‐5, measured simultaneously with SLRS‐6 in this study. In general, very low concentrations, close to the quantification limits, were found in the new batch. The Sr isotopic ratio is also reported.     

Earliest human remains in Eurasia: New 40Ar/39Ar dating of the Dmanisi hominid-bearing levels,Georgia

Several hominid remains have been discovered in the open-air site of Dmanisi (Georgia), the oldest prehistoric site in Eurasia. Two major arguments prove that this site is close in age to the Plio-Pleistocene boundary: a Villafranchian fauna and the morphological characteristics of hominid remains recently ascribed to Homo georgicus. Direct dating of the lower hominid-bearing level was carried out on volcanic glass and minerals using the ⁴⁰Ar/³⁹Ar method. The concordant results from two different sampled locations allow the determination of the age of the earliest human presence in Eurasia. This radioisotopic result strengthens the argument that the first dispersal of hominids outside Africa occurred at least 1.8 Ma ago.     

New Constraints on the Composition of Jupiter from Galileo Measurements and Interior Models

Using the helium abundance measured by Galileo in the atmosphere of Jupiter and interior models reproducing the observed external gravitational field, we derive new constraints on the composition and structure of the planet. We conclude that, except for helium which must be more abundant in the metallic interior than in the molecular envelope, Jupiter could be homogeneous (no core) or could have a central dense core up to 12M_⊕. The mass fraction of heavy elements is less than 7.5 times the solar value in the metallic envelope and between 1 and 7.2 times solar in the molecular envelope. The total amount of elements other than hydrogen and helium in the planet is between 11 and 45M_⊕.     

CO2 abatement goals for international shipping

The Paris Agreement, which entered into force in 2016, sets the ambitious climate change mitigation goal of limiting the global temperature increase to below 2°C and ideally 1.5°C. This puts a severe constraint on the remaining global GHG emissions budget. While international shipping is also a contributor to anthropogenic GHG emissions, and CO₂ in particular, it is not included in the Paris Agreement. This article discusses how a share of a global CO₂ budget over the twenty-first century could be apportioned to international shipping, and, using a range of future trade scenarios, explores the requisite cuts to the CO₂ intensity of shipping. The results demonstrate that, under a wide range of assumptions, existing short-term levers of efficiency must be urgently exploited to achieve mitigation commensurate with that required from the rest of the economy, with virtually full decarbonization of international shipping required as early as before mid-century.

Key policy insights

• Regulatory action is key to ensuring the international shipping sector’s long-term sustainability.

• For the shipping industry to deliver mitigation in line with the Paris Agreement, virtually full decarbonization needs to be achieved.

• In the near term, immediate and rapid exploitation of available mitigation measures is of critical importance.

• Any delay in the transition will increase the risk of stranded assets, or diminish the chances of meeting the Paris Agreement's temperature commitments.

     

Assessing the ‘usability’ of climate change research for decision-making: A case study of the Canadian International Polar Year

The creation of ‘usable science’ is widely promoted by many environmental change focused research programs. Few studies however, have examined the relationship between research conducted as part of such programs and the decision-making outcomes that the work is supposed to advance, and is constrained by limited methodological development on how to empirically assess the ‘usability’ of science. Herein, this paper develops a conceptual model and assessment rubric to quantitatively and systematically evaluate the usability of climate change research for informing decision-making. We focus on the process through which data is collected, analyzed and reported and examine the extent to which key principles of usable science are integrated into project design, using grant proposals as our data source. The approach is applied to analyze climate change research conducted as part of the International Polar Year in Canada, with 23 projects identified as having explicit goals to inform decision-making.While the creation of usable science was promoted by funded projects in the International Polar Year, this was not generally reflected in research design: fewer than half determined objectives with input of decision makers, decision context was not widely considered, and knowledge users were not widely reported to be engaged in assessing the quality of data or in resolving conflict in evidence. The importance of science communication was widely emphasized, although only 8/23 projects discussed tailoring specific results for end user needs. Thus while International Polar Year research has made significant advances in understanding the human dimensions of Arctic climate change, key attributes necessary for determining success in linking science to decision-making (pertinence, quality, timeliness) were not captured by many projects. Integrating these attributes into research design from the outset is essential for creating usable science, and needs to be at the forefront of future research programs which aim to advance societal outcomes. The framework for assessing usability here, while developed and tested in an Arctic climate change context, has broader applicability in the general environmental change field.     

New data on the composition and age of basement rocks of the Tagil paleo-island arc system

The Tagil paleo-island arc terrane is composed of Late Ordovician-Devonian intrusive, volcanic, and volcano-sedimentary complexes. The western margin of the terrane is comprised of dunite-clinopyroxenite-gabbro massifs of the Ural platinum-bearing belt, which are fringed by rock strata of widely different metamorphic grades. Work on isotope systematics of olivine gabbros enabled us to infer a Vendian age (550–540 Ma) of homogenization of the Sm-Nd isotopic system of the Kytlym and Knyaspa massifs within the Ural platinum-bearing belt. The Sm-Nd ages for metamorphic rocks of the Belaya Gora complex surrounding the studied massifs also agree with a Vendian age (573–574 Ma). Our results suggest that metamorphites of the Belaya Gora complex (amphibolites, plagiogneisses, two-mica and biotite gneisses, schists containing garnet, cordierite, staurolite, gedrite, and sillimanite) and dunite-clinopyroxenite-gabbro intrusions of the proto-platinum-bearing belt may have been formed in a convergence setting above a mantle plume, most likely in a back-arc (?) extension region. Reactivation of this plume during the late Precambrian resulted in the opening of the Ural paleo-ocean. The Late Ordovician-Early Devonian times were marked by metamorphic reworking and tectonic transport of pre-Paleozoic complexes into an accretionary prism setting of the Tagil paleo-arc that was accompanied by generation of gabbroid and granitoid magmas. Based on the obtained results, the Tagil terrane can be now considered as part of the Paleozoic paleo-island arc system developed on a heterogeneous Proterozoic basement.     

A Lagrangian approach to nonlinear modeling of anti-roll tanks

This paper presents two novel nonlinear models of u-shaped anti-roll tanks for ships, and their linearizations. In addition, a third simplified nonlinear model is presented. The models are derived using Lagrangian mechanics. This formulation not only simplifies the modeling process, but also allows one to obtain models that satisfy energy-related physical properties. The proposed nonlinear models and their linearizations are validated using model-scale experimental data. Unlike other models in the literature, the nonlinear models in this paper are valid for large roll amplitudes. Even at moderate roll angles, the nonlinear models have three orders of magnitude lower mean square error relative to experimental data than the linear models.